2-羟基乙基(E)-丁-2-烯二酸丁基酯 | 3207-09-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-羟基乙基(E)-丁-2-烯二酸丁基酯
• 英文名称: Butyl hydroxyethyl fumarate
• 英文别名: 1-O-butyl 4-O-(2-hydroxyethyl) (E)-but-2-enedioate
• CAS: 3207-09-8
• 化学式: C₁₀H₁₆O₅
• 分子量: 216.23
• InChiKey: PUDIPIBJWKQFNR-SNAWJCMRSA-N

物化性质

• 沸点：
  327.9±22.0 °C(Predicted)
• 密度：
  1.128±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

文献信息

• Radiation curable thiol-ene composition
  申请人：Dias Angelo Athanasius Aylvin Jorge

  公开号：US20070043205A1

  公开（公告）日：2007-02-22

  The invention relates to a curable thiol-ene composition comprising either compound A and compound B, or a compound B further comprising polythiol functionality as defined under (A), wherein (A) a polythiol, (B) a compound having a plurality of cyclic ene groups thereon, wherein said compound (B) comprises a carbonyl group directly attached to at least one cyclic ene group and comprises at least one hydrogen donating group, wherein the distance between at least one of said cyclic ene groups and at least one of said hydrogen donating groups is at least two skeletal bonds, wherein compound (B) does not contain a (meth)acrylate group, and 0-10 wt. % of a (free-radical) photoinitiator. The invention further relates to the use of such composition fiber optical coating, stereolithography resin, medical coating and adhesive.

  本发明涉及一种可固化的硫醇烯组合物，包括化合物A和化合物B，或者进一步包括聚硫醇功能的化合物B，其定义如下：（A）为聚硫醇，（B）为具有多个环烯基团的化合物，其中所述化合物（B）包括直接连接至至少一个环烯基团的羰基基团，并且包括至少一个氢供体基团，其中至少一个所述环烯基团与至少一个所述氢供体基团之间的距离至少为两个骨架键，其中化合物（B）不含（甲基）丙烯酸酯基团，并且0-10重量％为（自由基）光引发剂。本发明还涉及使用这种组合物进行光纤涂层、立体光刻树脂、医疗涂层和粘合剂的方法。
• Paint resin composition
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0238013A1

  公开（公告）日：1987-09-23

  A paint resin composition which does not appreciably attack an old coated film or a substrate to be coated, said composition consisting essentially of (A) a copolymer having a glass transition point of from -30°C to +50°C, a number average molecular weight of from 4,000 to 20,000 and a weight average molecular weight/ number average molecular weight ratio of from 1.8 to 10 and obtained by copolymerizing (a-1) 1 to 50% by weight of a vinyl monomer having a hydroxyl group, (a-2) 0 to 5% by weight of a vinyl monomer having a carboxyl group, (a-3) 0 to 80% by weight of a polyester resin having a copolymerizable unsaturated bond, (a-4) 10 to 80% by weight of a vinyl monomer having a side-chain alkyl group with 4 to 8 carbon atoms, and (a-5) 4 to 49% by weight of another vinyl monomer copolymerizable with the monomers (a-1) to (a-4), the total proportion of these monomers being 100% by weight, in the presence of a radical initiator in a nonpolar organic solvent having an aniline point of 7 to 70°C, (B) a polyisocyanate containing an isocyanurate ring and being soluble in a nonpolar organic solvent having an aniline point to from 7 to 70°C, said polyisocyante being obtained by reacting at least one diisocyanate compound selected from alkylene diisocyanates having 2 to 8 carbon atoms in the alkylene moiety, cyclo-alkylene diisocyanates having 6 to 8 carbon atoms in the cycloalkylene moiety and aralkylene diisocyantes having 7 to 8 carbon atoms in the aralkylene moiety with a diol having 10 to 40 carbon atoms, and (C) a nonpolar organic solvent, the OHINCO equivalent ratio of the copolymer (A) to the polyisocyanate (B) being from 1:0.2 to 1:1.5.

  一种不会明显侵蚀旧涂膜或待涂基材的涂料树脂组合物，所述组合物主要包括 (A) 一种共聚物，其玻璃化转变点为-30°C 至 +50°C，平均分子量为 4000 至 20000，平均分子量/平均分子量比为 1.(a-1) 1 至 50%（重量百分比）具有羟基的乙烯基单体；(a-2) 0 至 5%（重量百分比）具有羧基的乙烯基单体；(a-3) 0 至 80%（重量百分比）具有可共聚不饱和键的聚酯树脂；(a-4) 10 至 80%（重量百分比）具有 4 至 8 个碳原子的侧链烷基的乙烯基单体、(a-5)4-49%（按重量计）可与单体(a-1)至(a-4)共聚的另一种乙烯基单体，这些单体的总比例为 100%（按重量计），在有自由基引发剂存在的情况下，在苯胺点为 7 至 70℃的非极性有机溶剂中进行、 (B) 包含异氰尿酸酯环并可溶于苯胺点为 7 至 70°C 的非极性有机溶剂中的多异氰酸酯，所述多异氰酸酯由至少一种二异氰酸酯化合物反应获得，所述二异氰酸酯化合物选自烷基中含有 2 至 8 个碳原子的亚烷基二异氰酸酯、环亚烷基中含有 6 至 8 个碳原子的环亚烷基二异氰酸酯和芳基中含有 7 至 8 个碳原子的芳基二异氰酸酯与含有 10 至 40 个碳原子的二元醇反应得到的二异氰酸酯化合物，以及 (C) 非极性有机溶剂，共聚物 (A) 与多异氰酸酯 (B) 的 OHINCO 当量比为 1:0.2 至 1:1.5。
• AQUEOUS ORGANIC-INORGANIC HYBRID COMPOSITION
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1956049A1

  公开（公告）日：2008-08-13

  Disclosed is an organic-inorganic hybrid composition containing a metal oxide (A) having a particle diameter of 1-400 nm and a polymer emulsion particle (B) having a particle diameter of 10-800 nm. The polymer emulsion particle (B) is obtained by polymerizing a hydrolysable silicon compound (b1) and a vinyl monomer (b2) having a secondary and/or tertiary amide group in the presence of water and an emulsifying agent.

  本发明公开了一种有机-无机杂化组合物，其中含有颗粒直径为 1-400 纳米的金属氧化物（A）和颗粒直径为 10-800 纳米的聚合物乳液颗粒（B）。聚合物乳液颗粒（B）是在水和乳化剂存在下，通过聚合可水解硅化合物（b1）和具有二级和/或三级酰胺基团的乙烯基单体（b2）而得到的。
• PIGMENT DISPERSING COMPOSITION FOR COLOR FILTERS
  申请人：DIC Corporation

  公开号：EP2209025A1

  公开（公告）日：2010-07-21

  Provided is a pigment dispersing composition for a color filter including a color material, a resin, and an organic solvent which may dissolve the resin, wherein a modified pigment (D) is contained as the color material which includes, on the surface of a pigment (A), a polymer (P) obtained by polymerizing a polymer (B) containing a polymerizable unsaturated group soluble in a non-aqueous solvent and at least one type of polymerizable unsaturated monomer (C) which is soluble in the non-aqueous solvent and becomes either insoluble or poorly soluble following polymerization. Alternatively provided is a pigment dispersing composition for a color filter including a color material, a resin, and an organic solvent which may dissolve the resin, wherein a modified pigment (D) is contained as the color material which is obtained, under the presence of a pigment (A), a non-aqueous solvent, and a polymer (B) containing a polymerizable unsaturated group soluble in the non-aqueous solvent, by polymerizing at least one type of polymerizable unsaturated monomer (C) which is soluble in the non-aqueous solvent and becomes either insoluble or poorly soluble following polymerization.

  本发明提供了一种用于彩色滤光片的颜料分散组合物，该组合物包括颜料、树脂和可溶解树脂的有机溶剂，其中改性颜料（D）作为颜料包含在颜料（A）的表面、聚合物 (P)，通过聚合聚合物 (B)而得，聚合物 (B)含有可溶于非水溶剂的可聚合不饱和基团和至少一种可聚合不饱和单体 (C)，该单体可溶于非水溶剂，聚合后变得不溶或难溶。 另外，还提供了一种用于彩色滤光片的颜料分散组合物，该组合物包括一种颜料、一种树脂和一种可溶解该树脂的有机溶剂，其中含有一种改性颜料 (D)，该改性颜料是在颜料 (A)、一种非水溶剂的存在下获得的、通过聚合至少一种可聚合不饱和单体 (C)，得到含有可聚合不饱和基团且可溶于非水溶剂的聚合物 (B)，该单体可溶于非水溶剂，聚合后变得不溶或难溶。
• ACTIVE ENERGY RAY-CURABLE INK COMPOSITION AND PRINTED MATTER
  申请人：DIC Corporation

  公开号：EP2258778A1

  公开（公告）日：2010-12-08

  Disclosed is an active energy ray-curable ink composition comprising a coloring agent, a binder resin, and a radically polymerizable varnish and/or a radically polymerizable monomer as main components. The coloring agent is a modified pigment wherein the surface of a pigment (A) is provided with a polymer (P) which is obtained by polymerizing a polymer (B), which is soluble in nonaqueous solvents, with at least one polymerizable unsaturated monomer (C), which is originally soluble in nonaqueous solvents but becomes insoluble or poorly soluble after polymerization. Also disclosed is a printed matter which has a coating film obtained by curing and drying the active energy ray-curable ink composition.

  本发明公开了一种活性能量射线固化油墨组合物，其主要成分包括着色剂、粘合剂树脂、可辐射聚合清漆和/或可辐射聚合单体。着色剂是一种改性颜料，其中颜料（A）的表面具有聚合物（P），聚合物（P）是通过将可溶于非水溶剂的聚合物（B）与至少一种可聚合的不饱和单体（C）聚合而得到的，不饱和单体（C）原本可溶于非水溶剂，但在聚合后变得不溶或溶解性很差。还公开了一种印刷品，其涂膜是通过固化和干燥活性能量射线固化油墨组合物获得的。