1-Chlorosulfonyloxy-4-phenylbenzene | 35374-27-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Chlorosulfonyloxy-4-phenylbenzene
• CAS: 35374-27-7
• 化学式: C₁₂H₉ClO₃S
• 分子量: 268.721
• InChiKey: NMBFUIHJNMDFON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-Chlorosulfonyloxy-4-phenylbenzene 在 sodium azide 、 cobalt(II) 5,10,15,20-tetraphenylporphyrin 作用下， 以 氯苯 、 乙腈 为溶剂， 反应 36.0h， 生成 C₂₀H₁₇NO₃S
  参考文献：
  名称：

  Room temperature activation of aryloxysulfonyl azides by [Co(II)(TPP)] for selective radical aziridination of alkenes via metalloradical catalysis

  摘要：

  Aryloxysulfonyl azides can be effectively activated by commercially available cobalt(II) complex of meso-tetraphenylporphyrin ([Co(TPP)]) at room temperature under neutral and nonoxidative conditions for selective radical aziridination of alkenes via metalloradical catalysis. The [Co(TPP)]-catalyzed radical aziridination system is suitable for different combinations of olefin substrates and aryloxysulfonyl azides, producing various N-aryloxysulfonyl aziridine derivatives in good to excellent yields. In addition to generating the environmentally benign N-2 as the only byproduct, this Co(II)-based metalloradical aziridination process features mild reaction conditions and operational simplicity. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2015.01.186
• 作为产物：
  描述：

  对羟基联苯 在 吡啶 、 磺酰氯 作用下， 以 二氯甲烷 为溶剂， 反应 5.0h， 生成 1-Chlorosulfonyloxy-4-phenylbenzene
  参考文献：
  名称：

  Room temperature activation of aryloxysulfonyl azides by [Co(II)(TPP)] for selective radical aziridination of alkenes via metalloradical catalysis

  摘要：

  Aryloxysulfonyl azides can be effectively activated by commercially available cobalt(II) complex of meso-tetraphenylporphyrin ([Co(TPP)]) at room temperature under neutral and nonoxidative conditions for selective radical aziridination of alkenes via metalloradical catalysis. The [Co(TPP)]-catalyzed radical aziridination system is suitable for different combinations of olefin substrates and aryloxysulfonyl azides, producing various N-aryloxysulfonyl aziridine derivatives in good to excellent yields. In addition to generating the environmentally benign N-2 as the only byproduct, this Co(II)-based metalloradical aziridination process features mild reaction conditions and operational simplicity. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2015.01.186

文献信息

• Hedayatullah, Mir; Hugueny, Jean Claude, Synthetic Communications, 1981, vol. 11, # 8, p. 643 - 646
  作者：Hedayatullah, Mir、Hugueny, Jean Claude

  DOI：——

  日期：——
• NEPLYUEV, V. M.;BAZAVOVA, I. M., ZH. ORGAN. XIMII, 1981, 17, N 10, 2231-2232
  作者：NEPLYUEV, V. M.、BAZAVOVA, I. M.

  DOI：——

  日期：——
• Room temperature activation of aryloxysulfonyl azides by [Co(II)(TPP)] for selective radical aziridination of alkenes via metalloradical catalysis
  作者：Velusamy Subbarayan、Li-Mei Jin、Xin Cui、X.Peter Zhang

  DOI：10.1016/j.tetlet.2015.01.186

  日期：2015.6

  Aryloxysulfonyl azides can be effectively activated by commercially available cobalt(II) complex of meso-tetraphenylporphyrin ([Co(TPP)]) at room temperature under neutral and nonoxidative conditions for selective radical aziridination of alkenes via metalloradical catalysis. The [Co(TPP)]-catalyzed radical aziridination system is suitable for different combinations of olefin substrates and aryloxysulfonyl azides, producing various N-aryloxysulfonyl aziridine derivatives in good to excellent yields. In addition to generating the environmentally benign N-2 as the only byproduct, this Co(II)-based metalloradical aziridination process features mild reaction conditions and operational simplicity. (C) 2015 Elsevier Ltd. All rights reserved.