N,N'-bis-(4-methoxycarbonylbenzoyl)-1,2-ethanediamine | 7060-10-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis-(4-methoxycarbonylbenzoyl)-1,2-ethanediamine
• 英文别名: Bis-(p-carbomethoxybenzoyl)ethylendiamin；N,N'-Di(4-carbomethoxybenzoyl)ethylenediamine；N,N'-bis(p-carbomethoxybenzoyl)ethylene diamine；Dimethyl 4,4'-(ethane-1,2-diyldicarbamoyl)dibenzoate；methyl 4-[2-[(4-methoxycarbonylbenzoyl)amino]ethylcarbamoyl]benzoate
• CAS: 7060-10-8
• 化学式: C₂₀H₂₀N₂O₆
• 分子量: 384.389
• InChiKey: ZVJNDEOCNHLFIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  28
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  111
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-bis-(4-methoxycarbonylbenzoyl)-1,2-ethanediamine 生成 4-[2-[(4-Carbonochloridoylbenzoyl)amino]ethylcarbamoyl]benzoyl chloride
  参考文献：
  名称：

  DE2216592

  摘要：

  公开号：
• 作为产物：
  描述：

  对苯二甲酸单甲酯 在 4-二甲氨基吡啶 、 三乙胺 、 N,N'-二环己基碳二亚胺 作用下， 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 N,N'-bis-(4-methoxycarbonylbenzoyl)-1,2-ethanediamine
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES

  摘要：

  A practical and efficient protocol to obtain bis- and tris-(4-carboxybenzoyl)alkaneamines based on monoprotected 1,4-benzenedicarboxylic acid is reported here. N-(4-methoxycarbonylbenzoyloxy)succinimide was treated with aliphatic diamines and triamines to form aliphatic hydrocarbon-linked bis- and tris-amides 4a-4e. The yields ranged from good to very good and showed that choosing the right acylating agent is a key point in this synthesis. All the compounds were characterized by elemental analysis, FTIR, and H-1 NMR.

  DOI：

  10.4067/s0717-97072012000300023

文献信息

• Structured liquid detergent compositions containing amido and imido peroxy acids
  申请人：UNILEVER PLC

  公开号：EP0564250A2

  公开（公告）日：1993-10-06

  An aqueous cleaning composition is provided which includes an amido or imido organic peroxyacid having water solubility of less than 1 x 10⁻⁴M, a structuring surfactant and a pH-adjusting system for maintaining pH from 3.5 to 8.5 during storage and, upon dilution with a wash water, causing pH to rise by at least 0.5 pH units.

  本发明提供了一种水基清洁组合物，其中包括一种水溶性小于 1 x 10-⁴M 的氨基或亚氨基有机过氧酸、一种结构表面活性剂和一种 pH 值调节系统，用于在储存期间将 pH 值保持在 3.5 至 8.5 之间，并在用洗涤水稀释时使 pH 值上升至少 0.5 个 pH 单位。
• Amido peroxycarboxylic acids
  申请人：UNILEVER PLC

  公开号：EP0564251A2

  公开（公告）日：1993-10-06

  An amido peroxyacid compound is provided having the formula : wherein : R is selected from the group consisting of C1-C12 alkylene, C5-C12 cycloalkylene, C6-C12 arylene and radical combinations thereof ; R1 and R2 are independently selected from the group consisting of H, C1-C16alkyl and C6-C12 aryl radicals and a radical that can form a C3-C12 ring together with R3 and both nitrogens ; R3 is selected from the group consisting of C1-C12 alkylene, C5-C12 cycloalkylene and C6-C12 arylene radicals, and provided when R3 is arylene and when n' and m' are each zero, R is other than C5 alkylene ; n and n' each are an integer chosen such that the sum thereof is 1 ; m and m' each are an integer chosen such that the sum thereof is 1 ; and M is selected from the group consisting of H, alkali metal, alkaline earth metal, ammonium, alkanolammonium cations and radicals and combinations thereof. The amido peroxyacid compound is useful for bleaching substrates such as stained laundry.

  提供了一种酰胺基过氧酸化合物，其化学式为： 其中： R 选自由 C1-C12 亚烷基、C5-C12 环亚烷基、C6-C12 芳基及其自由基组合组成的组； R1 和 R2 独立地选自由 H、C1-C16 烷基、C6-C12 芳基以及能与 R3 和两个硝基一起形成 C3-C12 环的基组成的组； R3 选自 C1-C12 亚烷基、C5-C12 环亚烷基和 C6-C12 芳烯基组成的组，并且当 R3 为芳烯基，且 n' 和 m' 均为零时，R 不是 C5 亚烷基； n和n'各自为整数，其和为1； m和m'各自为整数，取其和为1；以及 M 选自 H、碱金属、碱土金属、铵、烷铵阳离子和自由基及其组合组成的组。 氨基过氧酸化合物可用于漂白染色衣物等基质。
• Process for making a modified thermoplastic polyester
  申请人：Agarwal Uday

  公开号：US20050175783A1

  公开（公告）日：2005-08-11

  The invention relates to a process for making a modified thermoplastic polyester by reacting a thermoplastic polyester with a nitrogen-containing compound, wherein the thermoplastic polyester is first contacted in the solid state with an Inert gas atmosphere containing at least one amino-compound of formula H 2 N—R—(X) n , wherein n is an integer≧0, R=a linear, branched or cyclo-aliphatic or aromatic residue comprising 1-24 C-atoms and optionally containing hetero atoms, X═—NH 2 or another functional group reactive with the polyester, at a temperature T(a) between room temperature and the melting point T m of the polyester, during at least 1 s; and then heated to a temperature T(b) between T(a) and T m , during up to 10 hours; and thereafter solid state polymerised at a temperature T(c) between (T m −50) and T m , during up to 100 hours, where T(a)

  本发明涉及一种通过使热塑性聚酯与含氮化合物反应来制造改性热塑性聚酯的工艺，其中热塑性聚酯首先在固态下与惰性气体环境接触，惰性气体环境中至少含有一种式 H 2 N-R-(X) n 其中 n 为整数≧0，R=线性、支链或环脂肪族或芳香族残基，由 1-24 个 C 原子组成，可选含有杂原子，X═-NH 2 或与聚酯反应的其他官能团，温度 T(a) 介于室温和熔点 T m 之间的温度 T(a)，持续至少 1 秒；然后加热至介于 T(a) 和 T(m)之间的温度 T(b) m 之间的温度 T(c)进行固态聚合。 m -50）和 T m 之间的温度 T(c)进行固态聚合，时间不超过 100 小时，其中 T(a)
• AMIDO PEROXYCARBOXYLIC ACIDS FOR BLEACHING
  申请人：UNILEVER PLC

  公开号：EP0724568B1

  公开（公告）日：1998-11-04
• Aromatic amide groups-containing diamines and polymers in which these diamines are incorporated
  申请人：AKZO N.V.

  公开号：EP0277376B1

  公开（公告）日：1991-02-27