2-苯基硫烷基-庚酸 | 101267-65-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-苯基硫烷基-庚酸
• 英文名称: 2-phenylsulfanyl-heptanoic acid
• 英文别名: 2-Phenylmercapto-heptansaeure；2-Phenylsulfanylheptanoic acid
• CAS: 101267-65-6
• 化学式: C₁₃H₁₈O₂S
• 分子量: 238.351
• InChiKey: SOCVTAHOHCINDZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  62.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  苯基乙烯基硫醚 在 正丁基锂 、 乙醚 作用下， 生成 2-苯基硫烷基-庚酸
  参考文献：
  名称：

  The Reaction of Vinyl Sulfides and Alkyl Sulfides with Butyllithium¹

  摘要：

  DOI：

  10.1021/ja01518a032

文献信息

• New polyhydroxyalkanoate copolymer, resin composition, molded product, toner, image forming method and image forming apparatus
  申请人：Yano Tetsuya

  公开号：US20060040196A1

  公开（公告）日：2006-02-23

  A polyhydroxyalkanoate copolymer comprises one kind of unit of —[OCH((CH 2 ) x —SOC 6 H 5 R)CH 2 CO]— (n= 1 - 7 )   ( 1 ) (wherein R is any one of H, halogen, CN, NO 2 , COOR′, SO 2 R″ (R′ is any one of H, Na, K, CH 3 and C 2 H 5 ; R″ is any one of OH, ONa, OK, halogen, OCH 3 and OC 2 H 5 ), CH 3 , C 2 H 5 , C 3 H 7 , (CH 3 ) 2 —CH and (CH 3 ) 3 —C) and —[OCH((CH 2 ) x —SO 2 C 6 H 5 R)CH 2 CO]— (n= 1 - 7 )   ( 2 ) (wherein R is any one of H, halogen, CN, NO 2 , COO R′, SO 2 R″ (R′ is any one of H, Na, K, CH 3 and C 2 H 5 ; R″ is any one of OH, ONa, OK, halogen, OCH 3 and OC 2 H 5 ), CH 3 , C 2 H 5 , C 3 H 7 , (CH 3 ) 2 —CH and (CH 3 ) 3 —C) and at least one unit of chemical formulae ( 3 ) to ( 6 ): —[OCH((CH 2 ) m —Rz)CH 2 CO]— (n= 1 - 8 )   ( 3 ) (wherein Rz comprises a residue having either a phenyl structure or a thienyl structure), —[OCH((CH 2 ) k —C 6 H 11 Ra)CH 2 CO]— (n= 1 - 8 )   ( 4 ) (wherein R a is any one of H, CN, NO 2 , halogen, CH 3 , C 2 H 5 , C 3 H 7 , CF 3 , C 2 F 5 and C 3 F 7 ) —[OCH((CH 2 ) n —CH═CH 2 )CH 2 CO]— (n= 1 - 8 )   ( 5 ), and —[OCH((CH 2 ) n —COORb)CH 2 CO]— (n= 1 - 8 )   ( 6 ) (wherein R b is any one of H, Na and K).

  聚羟基烷酸酯共聚物由以下一种单元组成 -[OCH((CH 2 ) x -SOC 6 H 5 R)CH 2 CO]- (n= 1 - 7 ) ( 1 ) (其中 R 是 H、卤素、CN、NO 2 、COOR′、SO 2 R″（R′是 H、Na、K、CH 3 和 C 2 H 5 R″是 OH、ONa、OK、卤素、OCH 3 和 OC 2 H 5 ）、CH 3 , C 2 H 5 , C 3 H 7 , (CH 3 ) 2 -CH和(CH 3 ) 3 -C）和 -[OCH((CH 2 ) x -SO 2 C 6 H 5 R)CH 2 CO]- (n= 1 - 7 ) ( 2 ) (其中 R 是 H、卤素、CN、NO 2 、COO R′、SO 2 R″（R′是 H、Na、K、CH 3 和 C 2 H 5 R″是 OH、ONa、OK、卤素、OCH 3 和 OC 2 H 5 ）、CH 3 , C 2 H 5 , C 3 H 7 , (CH 3 ) 2 -CH和(CH 3 ) 3 -C）和至少一个化学式单位 ( 3 )至( 6 ): -[OCH((CH 2 ) m -Rz)CH 2 CO]- (n= 1 - 8 ) ( 3 ) (其中 Rz 包括具有苯基结构或噻吩基结构的残基）、 -[OCH((CH 2 ) k -C 6 H 11 Ra)CH 2 CO]- (n= 1 - 8 ) ( 4 ) (其中 R a 是 H、CN、NO 2 卤素、CH 3 , C 2 H 5 , C 3 H 7 , CF 3 , C 2 F 5 和 C 3 F 7 ) -[OCH((CH 2 ) n -CH═CH 2 ) CH 2 CO]- (n= 1 - 8 ) ( 5 和 -[OCH((CH 2 ) n -COORb)CH 2 CO]- (n= 1 - 8 ) ( 6 ) (其中 R b 是 H、Na 和 K 中的任意一种）。
• IONIC TAGS FOR SYNTHESIS OF OLIGORIBONUCLEOTIDES
  申请人：The Royal Institution for the Advancement of Learning / McGill University

  公开号：EP2748176A1

  公开（公告）日：2014-07-02
• US7452960B2
  申请人：——

  公开号：US7452960B2

  公开（公告）日：2008-11-18
• [EN] NEW POLYHYDROXYALKANOATE COPOLYMER, RESIN COMPOSITION, MOLDED PRODUCT, TONER, IMAGE FORMING METHOD AND IMAGE FORMING APPARATUS<br/>[FR] COPOLYMERE DE POLYHYDROXYALKANOATE, COMPOSITION DE RESINE, PRODUIT MOULE, TONER, PROCEDE ET APPAREIL DE FORMATION D'IMAGES
  申请人：CANON KK

  公开号：WO2004041905A1

  公开（公告）日：2004-05-21

  A polyhydroxyalkanoate copolymer comprises one kind of unit of -[OCH((CH2)x-SOC6H5R)CH2CO]- (n=1-7) (1) (wherein R is any one of H, halogen, CN, NO2, COOR’, SO2R’’ (R’ is any one of H, Na, K, CH3 and C2H5; R’’ is any one of OH, ONa, OK, halogen, OCH3 and OC2H5), CH3, C2H5, C3H7, (CH3)2-CH and (CH3)3-C) and-[OCH((CH2)x-SO2C6H5R)CH2CO]- (x=1-7) (2) (wherein R is any one of H, halogen, CN, NO2, COOR’, SO2R’’ (R’ is any one of H, Na, K, CH3 and C2H5; R’’ is any one of OH, ONa, OK, halogen, OCH3 and OC2H5), CH3, C2H5, C3H7, (CH3)2-CH and (CH3)3-C)and at least one unit of chemical formulae (3) to (6): -[OCH((CH2)m-Rz)CH2CO]- (m=1-8) (3)(wherein Rz comprises a residue having either phenyl structure or a thienyl structure), -OCH((CH2)k-C6H11Ra)CH2CO]- (k=0-7) (4) (wherein Ra is any one of H, CN, NO2, halogen, CH3, C2H5, C3H7, CF3, C2F5 and C3F7)-[OCH((CH2)n-CH=CH2)CH2CO]- (n=1-8) (5), and-[OCH((CH2)n-COORb)CH2CO]- (n=1-8) (6) (wherein Rb is any one of H, Na and K).
• [EN] IONIC TAGS FOR SYNTHESIS OF OLIGORIBONUCLEOTIDES<br/>[FR] MARQUEURS IONIQUES POUR LA SYNTHÈSE D'OLIGORIBONUCLÉOTIDES
  申请人：UNIV MCGILL

  公开号：WO2013026142A1

  公开（公告）日：2013-02-28

  The invention relates to the chemical synthesis of oligonucleotides, e.g., oligoribonucleotides. In another aspect, the invention relates to compounds of formula (II) processes for making these compounds, and the use thereof in the chemical synthesis of oligonucleotides, e.g., oligoribonucleotides. The invention also relates to methods of synthesis of oligomers, including but not limited to oligopeptides, oligosaccharides and oligonucleotides, particularly oligoribonucleotides and also oligodeoxyribonucleotides, in solution systems, and ionic tag linkers for use in methods provided herein.