2-萘硫乙基丙烯酸酯; 2-丙烯酸 2-(2-萘硫基)乙酯 | 897049-32-0

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-萘硫乙基丙烯酸酯; 2-丙烯酸 2-(2-萘硫基)乙酯
• 中文别名: 2-萘硫乙基丙烯酸酯;2-丙烯酸2-(2-萘硫基)乙酯
• 英文名称: 2-naphthylthioethylacrylate
• 英文别名: Naphthalenylthioethyl acrylate；2-naphthalen-2-ylsulfanylethyl prop-2-enoate
• CAS: 897049-32-0
• 化学式: C₁₅H₁₄O₂S
• 分子量: 258.341
• InChiKey: TVQDRZGNLJFEQK-UHFFFAOYSA-N

物化性质

• 沸点：
  412.9±28.0 °C(Predicted)
• 密度：
  1.18

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-萘硫乙基丙烯酸酯; 2-丙烯酸 2-(2-萘硫基)乙酯 、 苯胺 在 silica sulfuric acid 作用下， 反应 2.5h， 以86%的产率得到3-phenylaminopropionic acid 2-(naphthalen-2-ylsulfanyl)-ethyl ester
  参考文献：
  名称：

  二氧化硅硫酸作为非均相和可重复使用的催化剂在无溶剂条件下促进氮杂-迈克尔加成反应。

  摘要：

  使用二氧化硅硫酸（SSA 或 SiO(2)-SO(3)H) 进行胺/硫醇与 α,β-不饱和化合物的化学选择性氮杂-迈克尔加成反应的高效、廉价、可回收、方便和绿色的方案是发达。该方法简单、方便，标题化合物的产率非常好。

  DOI：

  10.3390/molecules14114779
• 作为产物：
  描述：

  2-萘硫醇 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 2-萘硫乙基丙烯酸酯; 2-丙烯酸 2-(2-萘硫基)乙酯
  参考文献：
  名称：

  JP7056141

  摘要：

  公开号：

文献信息

• Curable composition for imprinting
  申请人：DIC Corporation

  公开号：US10295901B2

  公开（公告）日：2019-05-21

  There is provided a curable composition for imprinting containing a polymerizable compound, in which (a) the concentration of a polymerizable group in the polymerizable compound is in the range of 4.3 mmol/g to 7.5 mmol/g, (b) a polymerizable compound X whose Ohnishi parameter is 3.5 or less and ring parameter is 0.35 or greater is contained in the range of 40% by mass to 95% by mass with respect to all the polymerizable compounds, (c) a polymerizable compound C having three or more polymerizable groups is further contained in the range of 5% by mass to 20% by mass with respect to all the polymerizable compounds, and (d) the viscosity of the composition being at 25° C. and in a state of not containing a solvent is in the range of 3 mPa·s to 8,000 mPa·s.

  提供了一种含有可聚合化合物的用于压印的可固化组合物，其中 (a) 可聚合化合物中可聚合基团的浓度范围为 4.3 mmol/g 至 7.5 mmol/g，(b) 大西参数为 3.5 或以下且环参数为 0.35 或更高的可聚合化合物 X，其含量占所有可聚合化合物的质量百分比为 40% 至 95%，(c) 具有三个或更多可聚合基团的可聚合化合物 C，其含量占所有可聚合化合物的质量百分比为 5% 至 20%，(d) 在 25°C、不含溶剂的状态下，组合物的粘度在 3 mPa-s 至 8,000 mPa-s 之间。
• Organic-inorganic hybrid composition, optical member and optical device prepared using the same
  申请人：LMS CO., LTD.

  公开号：US10670796B2

  公开（公告）日：2020-06-02

  Disclosed is an organic-inorganic hybrid composition. The organic-inorganic hybrid composition includes a curable resin and inorganic particles dispersed in the curable resin. The inorganic particle has a core-shell structure composed of a core containing titanium and barium, and a shell containing at least one selected from zirconium, aluminum and chromium. According to this organic-inorganic hybrid composition, a liquid-phase refractive index of the composition can be improved, and as a result, luminance and light transmittance can be improved in an optical member using the same.

  公开了一种有机-无机混合组合物。有机-无机杂化组合物包括可固化树脂和分散在可固化树脂中的无机颗粒。无机颗粒具有核壳结构，由含有钛和钡的核以及含有至少一种选自锆、铝和铬的壳组成。根据这种有机-无机杂化组合物，可以提高组合物的液相折射率，从而提高使用该组合物的光学部件的亮度和透光率。
• COMPOSITIONS FOR BRIGHTNESS ENHANCING FILMS
  申请人：General Electric Company

  公开号：EP1954732A1

  公开（公告）日：2008-08-13
• Compositions for brightness enhancing films
  申请人：Olson Robert Daniel

  公开号：US20060293463A1

  公开（公告）日：2006-12-28

  Disclosed is a brightness enhancing film composition comprising a multifunctional (meth)acrylate, a substituted or unsubstituted naphthyl (meth)acrylate monomer, an arylether (meth)acrylate and an optional polymerization initiator. The composition was found to efficiently cure under typical conditions employed for the rapid, continuous production of cured, coated films. Such cured compositions exhibit excellent relative degree of cure under a variety of processing conditions. Disclosed also are articles comprising the brightness enhancing film composition comprising a multifunctional (meth)acrylate, a substituted or unsubstituted naphthyl (meth)acrylate monomer, an arylether (meth)acrylate and an optional polymerization initiator. The article may be a multilayer article comprising a substrate.
• Polymerizable composition and its uses
  申请人：Yeh Kun-Ming

  公开号：US20110068305A1

  公开（公告）日：2011-03-24

  The present invention provides a polymerizable composition, comprising, based on the total weight of the polymerizable composition: (a) 1-90 wt % of a monomer of a formula (I): wherein X 1 is H or methyl; X 2 is H or C 1 -C 2 alkyl; X is O or S; R 1 is C 1 -C 12 straight or branched alkylene or alkoxylene; and d and n are each independently an integer of 0 to 3; and (b) 0.1-10 wt % of a photo-initiator. The present invention also provides an optical film comprising a coating formed from the above polymerizable composition. The optical film can be used in backlight units for displays as a brightness enhancement film.