2,2,3,3-Tetramethylcyclopropylmethyl m-(phenoxy)benzyl ether | 64930-75-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2,3,3-Tetramethylcyclopropylmethyl m-(phenoxy)benzyl ether
• 英文别名: 3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropylmethyl ether；1-Phenoxy-3-[(2,2,3,3-tetramethylcyclopropyl)methoxymethyl]benzene
• CAS: 64930-75-2
• 化学式: C₂₁H₂₆O₂
• 分子量: 310.436
• InChiKey: QJVNPOKBVJFQMX-UHFFFAOYSA-N

物化性质

• 沸点：
  381.7±25.0 °C(Predicted)
• 密度：
  1.016±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  间苯氧基溴化苄 、 1-(hydroxymethyl)-2,2,3,3-tetramethylcyclopropane 在 氢氧化钾 、 四丁基碘化铵 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以74%的产率得到2,2,3,3-Tetramethylcyclopropylmethyl m-(phenoxy)benzyl ether
  参考文献：
  名称：

  Synthesis of ethophenprox analogs

  摘要：

  The synthesis of ethophenprox analogs was performed by condensation of alcohols with benzyl halides under conditions of the phase transfer catalysis. The ultrasonic irradiation was shown to accelerate the reaction and to increase the yield of ethers. The trends in fragmentation of new generation pyrethroids under the electron impact were established. Insecticidal activity of the compounds obtained was evaluated.

  DOI：

  10.1007/bf02757439

文献信息

• Insecticidal resin coating film
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0257415A1

  公开（公告）日：1988-03-02

  An insecticidal resin coating film comprising a combination of an acrylonitrile and/or methacrylonitrile copolymer resin and an insecticidal component selected from the group consisting of specified compounds exhibits an insecticidal effect, since the compound is kept on the surface of the coating film in a state capable of exhibiting its insecticidal effect for a long period of time.

  杀虫树脂涂膜由丙烯腈和/或甲基丙烯腈共聚物树脂和从特定化合物组成的组中选出的杀虫成分组合而成，具有杀虫效果，因为化合物在涂膜表面保持的状态能够长时间显示其杀虫效果。
• US4818525A
  申请人：——

  公开号：US4818525A

  公开（公告）日：1989-04-04
• US4997650A
  申请人：——

  公开号：US4997650A

  公开（公告）日：1991-03-05
• Synthesis of ethophenprox analogs
  作者：F. Z. Galin、R. G. Rakhimov、E. M. Vyrypaev、M. P. Bogdanov、D. V. Amirkhanov、I. I. Furlei、G. A. Tolstikov

  DOI：10.1007/bf02757439

  日期：2000.6

  The synthesis of ethophenprox analogs was performed by condensation of alcohols with benzyl halides under conditions of the phase transfer catalysis. The ultrasonic irradiation was shown to accelerate the reaction and to increase the yield of ethers. The trends in fragmentation of new generation pyrethroids under the electron impact were established. Insecticidal activity of the compounds obtained was evaluated.