terephthalic acid monovinyl ester | 116532-09-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: terephthalic acid monovinyl ester
• 英文别名: Terephthalsaeure-monovinylester；ethylene terephthalate；4-(Vinyloxycarbonyl) benzoic acid；4-ethenoxycarbonylbenzoic acid
• CAS: 116532-09-3
• 化学式: C₁₀H₈O₄
• 分子量: 192.171
• InChiKey: ZVKPGHYZRCHUJO-UHFFFAOYSA-N

物化性质

• 熔点：
  194.0-195.5 °C
• 沸点：
  110-120 °C(Press: 0.05 Torr)
• 密度：
  1.268±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  对苯二甲酸 、 乙炔 在 zinc(II) oxide 作用下， 生成 terephthalic acid monovinyl ester
  参考文献：
  名称：

  Zur kenntnis der aromatischen vinylester

  摘要：

  AbstractDie Darstellung von neuen Vinylestern aromatischer und heterocyclischer Carbonsäuren nach bekannten Methoden wird beschrieben. Im Gegensatz zu den Literaturangaben wurde gefunden, daß auch Divinylestern aus Dicarbonsäuren durch direkte Vinylierung mit Acetylen darstellbar sind.

  DOI：

  10.1002/macp.1956.020180121

文献信息

• Water soluble copolymers prepared from vinyl functional monomers
  申请人：UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

  公开号：EP0506088A2

  公开（公告）日：1992-09-30

  Compositions are disclosed which are useful in coating and ink applications. Such compositions comprise a copolymer of at least one vinyl ester monomer and at least one vinyl functional acid-containing monomer in which the vinyl group is separated by at least two atoms from the acid group, the copolymer more preferably having a number average molecular weight of less than 10,000 and being substantially water soluble in the neutralized state. A particularly useful vinyl functional, carboxylic acid-containing monomer is mono vinyl adipate.

  本文公开了可用于涂料和油墨的组合物。这种组合物包括至少一种乙烯基酯单体和至少一种乙烯基官能团含酸单体的共聚物，其中乙烯基与酸基之间至少有两个原子隔开，共聚物的平均分子量最好小于 10,000 并且在中和状态下基本上可溶于水。一种特别有用的含乙烯基官能团的羧酸单体是己二酸单乙烯酯。
• An oxygen scavenging polyethylene terephthalate based polymer
  申请人：ARTEVA TECHNOLOGIES S.à.r.l.

  公开号：EP1283234A2

  公开（公告）日：2003-02-12

  The present invention improves the effectiveness of the oxygen scavenging composition and maintains an excellent balance in the color properties of the polymer. The present invention relates to an improved oxygen scavenging PET based copolymer comprising from about 10 to about 120 ppm cobalt based on the PET polymer, and from about 15 to about 150 ppm zinc based on the PET polymer. The present invention also comprises a process for preparing a PET based oxygen scavenging copolymer, comprising the steps of: a) polymerizing monomers to produce a PET based polymer; b) adding Zn, Co, and an oxygen scavenging compound during said polymerizing step; c) copolymerizing said oxygen scavenging compound with said PET based polymer to form a copolymer; and optionally d) extruding said copolymer. The present invention also comprises an oxygen barrier container having one or more layers of a PET based oxygen scavenging copolymer having from about 10 to about 120 ppm Co based on said PET polymer, and from about 15 to about 150 ppm Zn based on the PET polymer; and an oxygen scavenging compound wherein said Co and said Zn are catalysts for said oxygen scavenging compound.

  本发明提高了氧清除组合物的效果，并保持了聚合物颜色特性的极佳平衡。本发明涉及一种改进的氧清除 PET 基共聚物，其中包含基于 PET 聚合物的约 10 至约 120 ppm 的钴和基于 PET 聚合物的约 15 至约 150 ppm 的锌。本发明还包括一种制备 PET 基氧清除共聚物的工艺，包括以下步骤： 1： a) 聚合单体以生产 PET 基聚合物； b) 在所述聚合步骤中添加 Zn、Co 和氧清除化合物； c) 将所述氧清除化合物与所述 PET 聚合物共聚形成共聚物；以及 d) 挤压所述共聚物。 本发明还包括一种氧气阻隔容器，该容器具有一层或多层基于 PET 的氧清除共聚物，基于所述 PET 聚合物的 Co 含量约为 10 至 120 ppm，基于所述 PET 聚合物的 Zn 含量约为 15 至 150 ppm；以及氧清除化合物，其中所述 Co 和所述 Zn 是所述氧清除化合物的催化剂。
• SUPERFINE POLYESTER FIBER AND TUBULAR SEAMLESS FABRIC
  申请人：Asahi Kasei Fibers Corporation

  公开号：EP2826894A1

  公开（公告）日：2015-01-21

  Provided is a superfine polyester fiber containing at least 98 wt% of a polyethylene terephthalate component, and characterized by fulfilling the following conditions: (1) the reduced viscosity (ηsp/c) is at least 0.80 dl/g; (2) the total fineness is 7-120 dtex, and the single filament fineness is no more than 0.5 dtex; and (3) the toughness parameter (X) indicated by formula (1) is at least 2.0, the tensile strength is at least 3.5 cN/dtex and the tensile elongation is at least 12%. X=Tensile strength×√tensile elongation/total fineness×single filament fineness

  提供了一种超细聚酯纤维，含有至少 98 wt%的聚对苯二甲酸乙二醇酯组分，其特征在于满足以下条件：（1）还原粘度（ηsp/c）至少为 0.80 dl/g；(2) 总细度为 7-120 dtex，单丝细度不超过 0.5 dtex；(3) 由式（1）表示的韧性参数（X）至少为 2.0，拉伸强度至少为 3.5 cN/dtex，拉伸伸长率至少为 12%。X=拉伸强度×√拉伸伸长率/总细度×单丝细度
• ULTRAFINE POLYESTER FIBER
  申请人：Asahi Kasei Fibers Corporation

  公开号：EP3045574A1

  公开（公告）日：2016-07-20

  Provided is an ultrafine polyester fiber which is useful as a constituent material for a cloth for a stent graft or other medical device that is to be implanted in the body and which can simultaneously solve both a clinical need (diameter reduction) and a clinical challenge (integration of a stent with a stent graft). An ultrafine polyester fiber which has a polyethylene terephthalate content of 98 wt% or more, characterized by: having (1) a reduced viscosity (ηsp/c) of 0.80 dl/g or higher and (2) a total fineness of 7 to 120 dtex and a single-fiber fineness of 0.5 dtex or less; and exhibiting (3) a maximum thermal shrinkage stress of 0.05 cN/dtex or more in a temperature range of 80 to 200°C or (4) a degree of crystallinity of 35% or more in a region spreading from the surface of the fiber to a depth of 0.1 µm.

  本发明提供了一种超细聚酯纤维，它可作为植入体内的支架移植物或其他医疗设备的布料的组成材料，并能同时解决临床需求（直径减小）和临床难题（支架与支架移植物的整合）。一种超细聚酯纤维，其聚对苯二甲酸乙二醇酯含量为 98 wt% 或以上，其特征在于：(1) 降低粘度 (ηsp/c) 为 0.80 dl/g 或以上；(2) 总细度为 7 至 120 dtex，单纤维细度为 0.(3) 在 80 至 200°C 的温度范围内，最大热收缩应力为 0.05 cN/dtex 或以上；或 (4) 在从纤维表面到 0.1 µm 深度的区域内，结晶度为 35% 或以上。
• Combination of substituted cyclodextrin compound and activated carbon
  申请人：Cellresin Technologies, LLC

  公开号：US10323131B2

  公开（公告）日：2019-06-18

  The invention is a composition that can prevent formation in, or scavenge undesirable organic materials from, a polymer matrix. The composition contains cyclodextrin and particles of activated carbon. The composition can scavenge thermal decomposition products that can be produced during melt processing of a polymer, contaminants inherent in a polymer, or other types of impurities from a polymer matrix that otherwise may elute into the air, a water supply, or an ingestible material such as a food, a drug, or a beverage. Other aspects of the invention are blends of the composition with polymeric materials, methods of making blends, articles containing the composition, and methods of making articles containing the composition.

  本发明是一种可防止聚合物基质中形成或清除不良有机物的组合物。该组合物含有环糊精和活性炭颗粒。该组合物可以清除聚合物熔融加工过程中可能产生的热分解产物、聚合物中固有的污染物或聚合物基质中的其他类型杂质，否则这些杂质可能会洗脱到空气、水源或食品、药品或饮料等可食用材料中。本发明的其他方面包括本发明组合物与聚合物材料的混合物、混合物的制造方法、含有本发明组合物的物品以及含有本发明组合物的物品的制造方法。