3'-溴-[1,1'-联苯]-4-胺 | 91394-64-8

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3'-溴-[1,1'-联苯]-4-胺
• 英文名称: 3-bromo-4’-aminobiphenyl
• 英文别名: 4-Amino-3'-brom-biphenyl；3'-bromo-biphenyl-4-ylamine；3'-Brom-biphenyl-4-ylamin；3'-Brom-4-amino-biphenyl；4'-amino-3-bromobiphenyl；4-(3-bromophenyl)aniline
• CAS: 91394-64-8
• 化学式: C₁₂H₁₀BrN
• 分子量: 248.122
• InChiKey: CISCEQDFKRTNBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3'-溴-[1,1'-联苯]-4-胺 在 盐酸 、 sodium nitrite 、 potassium iodide 、 sodium hydrogensulfite 作用下， 以 水 、 氯仿 为溶剂， 反应 5.0h， 以69%的产率得到3-溴-4'-碘-1,1'-联苯
  参考文献：
  名称：

  WO2006/85434

  摘要：

  公开号：
• 作为产物：
  描述：

  1-溴-3-(4-硝基苯基)苯 在 盐酸 、 tin(ll) chloride 作用下， 以 乙醇 为溶剂， 生成 3'-溴-[1,1'-联苯]-4-胺
  参考文献：
  名称：

  420.同构和化学组成。第十一部分。取代的4-对-n-烷氧基苄叉亚氨基联苯的制备和介晶性质

  摘要：

  DOI：

  10.1039/jr9630002246

文献信息

• 신규한 유기발광 화합물 및 이를 포함하는 유기전계발광소자
  申请人：SFC CO., LTD. 에스에프씨 주식회사(120060087061) Corp. No ▼ 135511-0105889BRN ▼134-81-54429

  公开号：KR101565604B1

  公开（公告）日：2015-11-03

  본 발명은 정공수송 또는 정공주입 재료로 채용되는 신규한 유기발광 화합물에 관한 것으로서, 하기 [화학식 1]로 표시되는 것을 특징으로 하며, 본 발명에 따른 유기전계발광 화합물을 유기전계발광소자의 정공수송 또는 정공주입 재료로 채용시 소자의 발광효율 및 수명 특성이 동시에 매우 우수하여 구동 특성이 향상된 유기전계발광소자의 제조가 가능하다. [화학식 1]

  本发明涉及一种新的有机发光化合物，用作有机电致发光器件的正电荷输送或正电荷注入材料，其特征在于表示为[化学式1]，根据本发明采用的有机电致发光化合物作为有机电致发光器件的正电荷输送或正电荷注入材料时，器件的发光效率和寿命特性均非常优越，可以制造出性能提升的有机电致发光器件。 [化学式1]
• STRONGLY POLARIZED MOLECULE, AND SINGLE MOLECULE FIELD EFFECT TRANSISTOR PREPARED THEREFROM
  申请人：Peking University

  公开号：US20210024560A1

  公开（公告）日：2021-01-28

  The application relates to a strongly-polarized molecule of the following general formula: wherein A denotes a group having a polarizability greater than 2 C·m 2 /V; R 1 and R 2 are respectively hydrogen, halogen, a hydroxyl group, an amino group, a cyano group, a nitro group, a carboxyl group, a C 1-12 alkyl group, a C 1-12 alkoxy group, a halogenated C 1-12 alkyl group, a halogenated C 1-12 alkoxy group, a hydroxyl C 1-12 alkyl group, a hydroxyl C 1-12 alkoxy group, or a C 1-12 alkyl amino group; x 1 and x 2 denote 0 or an integer no less than 1, respectively; and y 1 and y 2 denote 0 or an integer no less than 1, respectively. The application further relates to a strongly-polarized molecule-graphene molecule heterojunction, and a single molecule field effect transistor comprising a substrate, a gate, a dielectric layer and the strongly-polarized molecule-graphene molecule heterojunction; and the dielectric layer is located between the gate and the strongly-polarized molecule-graphene molecule heterojuction. The single molecule field effect transistor provided by the application can realize highly-efficient gate modulation.

  该申请涉及以下通式的强极化分子：其中A表示具有极化率大于2 C·m2/V的基团；R1和R2分别表示氢、卤素、羟基、氨基、氰基、硝基、羧基、C1-12烷基、C1-12烷氧基、卤代C1-12烷基、卤代C1-12烷氧基、羟基C1-12烷基、羟基C1-12烷氧基或C1-12烷基氨基；x1和x2分别表示0或不小于1的整数；y1和y2分别表示0或不小于1的整数。该申请还涉及强极化分子-石墨烯分子异质结和单分子场效应晶体管，包括基底、栅、介电层和强极化分子-石墨烯分子异质结；介电层位于栅和强极化分子-石墨烯分子异质结之间。该申请提供的单分子场效应晶体管可以实现高效的栅调制。
• Bisanthracene derivative and organic electroluminescence device using the same
  申请人：Kubota Mineyuki

  公开号：US20060216633A1

  公开（公告）日：2006-09-28

  A bisanthracene derivative having a specific structure and an organic electroluminescence device having an organic thin film layer which has one layer or a plurality of layers including at least a light emitting layer, and is disposed between a cathode and an anode and contains the bisanthracene derivatives singly or as a component of a mixture. The organic electroluminescence device exhibits a great efficiency of light emission in a region including a high luminance region and has a long life, and the bisanthracene derivative realizes the device.

  一种具有特定结构的双蒽衍生物和一种有机电致发光器件，其具有一个包括至少一个发光层的单层或多层有机薄膜层，位于阴极和阳极之间，并含有双蒽衍生物单独或作为混合物组分。该有机电致发光器件在包括高亮度区域的区域内表现出很高的发光效率，并具有长寿命，而双蒽衍生物实现了该器件。
• 2-Biphenyl-carbapenem antibacterial agents
  申请人：MERCK & CO. INC.

  公开号：EP0467434A1

  公开（公告）日：1992-01-22

  Carbapenems of the formula are useful antibacterial agents.

  碳青霉烯类 是有用的抗菌剂。
• BISANTHRACENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1847521A1

  公开（公告）日：2007-10-24

  A bisanthracene derivative having a specific structure and an organic electroluminescence device having an organic thin film layer which has one layer or a plurality of layers including at least a light emitting layer, and is disposed between a cathode and an anode and contains the bisanthracene derivatives singly or as a component of a mixture. The organic electroluminescence device exhibits a great efficiency of light emission in a region including a high luminance region and has a long life, and the bisanthracene derivative realizes the device.

  一种具有特定结构的双蒽衍生物和一种有机电致发光器件，该器件具有一层或多层有机薄膜层，其中至少包括一个发光层，该薄膜层被置于阴极和阳极之间，并含有单个或作为混合物成分的双蒽衍生物。该有机电致发光器件在包括高亮度区域在内的区域内发光效率高，使用寿命长，双蒽衍生物实现了该器件。