3,3,4,4,5,5,6,6,7,7,7-十一氟庚-1-烯 | 84100-13-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 3,3,4,4,5,5,6,6,7,7,7-十一氟庚-1-烯
• 英文名称: 3,3,4,4,5,5,6,6,7,7,7-Undecafluorohept-1-ene
• CAS: 84100-13-0
• 化学式: C₇H₃F₁₁
• 分子量: 296.083
• InChiKey: QAFBNSWDAGQWLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  N-叔丁基-α-苯基硝酮 、 3,3,4,4,5,5,6,6,7,7,7-十一氟庚-1-烯 在 dipotassium hydrogenphosphate 、 silver hexafluoroantimonate 、 六氟磷酸银 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 16.0h， 以93%的产率得到
  参考文献：
  名称：

  通过Ru（II）催化硝基的CH活化并与全氟烷基烯烃偶联，对融合的异恶唑烷进行区域和非对映选择性反应

  摘要：

  氟化异恶唑烷在双环环境中的合成已通过Ru（II）催化的全氟烷基取代的烯烃作为偶联伙伴的芳基硝酮的C–H活化。该反应通过初始螯合辅助的C（芳基）-H烯丙基化反应进行，然后在硝基导向基团和烯烃单元之间进行区域和非对映选择性分子内偶极加成。

  DOI：

  10.1021/acs.orglett.7b03775

文献信息

• METHOD FOR PREPARING THIOCARBOXYLIC ACID S-(FLUOROALKYL) ESTER
  申请人：Sumitomo Chemical Company Limited

  公开号：EP2684870A1

  公开（公告）日：2014-01-15

  It is provided that a method for producing a thiocarboxylic acid S-(fluoroalkyl) ester represented by formula (III) [wherein R1 represents a methyl group, an ethyl group or a phenyl group, and R2 represents a C1-C5 fluoroalkyl group] by reacting a thiocarboxylic acid represented by formula (I) [wherein R1 has the same meaning as defined above] with a fluoroolefin represented by formula (II) [wherein R2 has the same meaning as defined above] in the presence of a radical generator.

  根据所提供的方法，通过在自由基发生剂存在下，将公式（I）表示的硫代羧酸（其中R1代表甲基、乙基或苯基，R2代表C1-C5氟烷基）与公式（II）表示的氟烯烃（其中R2具有上述定义的相同含义）反应，可以生产一种由公式（III）表示的硫代羧酸S-(氟烷基)酯。
• Fluorine-containing copolymer and curable composition containing the same
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0483750A1

  公开（公告）日：1992-05-06

  A fluorine-containing copolymer comprising: 30 to 85 % by mole of structural units (a): 1 to 30 % by mole of structural units (b): and 3 to 60 % by mole of structural units (c): and a curable composition containing the same. The copolymer is excellent in compatibility with curing agents and the obtained film therefrom is excellent in appearance, gloss, durability, and the like.

  含氟共聚物，包括30% 至 85% （以摩尔计）的结构单元 (a)： 1 至 30%（摩尔）的结构单元（b）： 和 3%至 60%（以摩尔计）的结构单元（c）： 的共聚物，以及含有这种共聚物的可固化组合物。该共聚物与固化剂的相容性极佳，由此获得的薄膜在外观、光泽度、耐久性等方面也非常出色。
• POLYMER MATERIAL
  申请人：Daikin Industries, Ltd.

  公开号：EP3505572A1

  公开（公告）日：2019-07-03

  An object of the present invention is to provide a macromolecular material that exhibits excellent elongation. The first macromolecular material of the present invention contains the first polymer containing the first structural unit and the second polymer containing the second structural unit. The first structural unit has a guest group in its side chain, and the second structural unit has a host group in its side chain. At least one of the first and the second polymers contains at least one fluorine group. The second macromolecular material of the present invention contains the first structural unit having a guest group in its side chain, the second structural unit having a host group in its side chain, and the third structural unit other than the first and second structural units. At least one of the first, the second, and the third structural units contains at least one fluorine group.

  本发明的目的是提供一种具有优异伸长率的高分子材料。本发明的第一种高分子材料包含含有第一结构单元的第一聚合物和含有第二结构单元的第二聚合物。第一结构单元的侧链中含有客体基团，第二结构单元的侧链中含有宿主基团。第一和第二聚合物中至少有一种含有至少一个氟基团。本发明的第二种高分子材料包含侧链中含有客体基团的第一结构单元、侧链中含有宿主基团的第二结构单元以及第一和第二结构单元以外的第三结构单元。第一、第二和第三结构单元中至少有一个含有至少一个氟基团。
• Polymer material
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：US11198749B2

  公开（公告）日：2021-12-14

  An object of the present invention is to provide a macromolecular material that exhibits excellent elongation. The first macromolecular material of the present invention contains the first polymer containing the first structural unit and the second polymer containing the second structural unit. The first structural unit has a guest group in its side chain, and the second structural unit has a host group in its side chain. At least one of the first and the second polymers contains at least one fluorine group. The second macromolecular material of the present invention contains the first structural unit having a guest group in its side chain, the second structural unit having a host group in its side chain, and the third structural unit other than the first and second structural units. At least one of the first, the second, and the third structural units contains at least one fluorine group.

  本发明的目的是提供一种具有优异伸长率的高分子材料。本发明的第一种高分子材料包含含有第一结构单元的第一聚合物和含有第二结构单元的第二聚合物。第一结构单元的侧链中含有客体基团，第二结构单元的侧链中含有宿主基团。第一和第二聚合物中至少有一种含有至少一个氟基团。本发明的第二种高分子材料包含侧链中含有客体基团的第一结构单元、侧链中含有宿主基团的第二结构单元以及第一和第二结构单元以外的第三结构单元。第一、第二和第三结构单元中至少有一个含有至少一个氟基团。
• POLYMER, ELECTROLYTE, AND LITHIUM-ION BATTERY EMPLOYING THE SAME
  申请人：INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

  公开号：US20220216511A1

  公开（公告）日：2022-07-07

  A polymer, an electrolyte, and a lithium-ion battery employing the same are provided. The polymer is a product of a composition via a polymerization. The composition includes a first monomer and a second monomer. The first monomer has a structure represented by Formula (I) and the second monomer is fluorine-containing acrylate, fluorine-containing alkene, fluorine-containing epoxide, or a combination thereof. Particularly, n, m, and l are independently 1, 2, 3, 4, 5, or 6; and, R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are as defined in the specification.