O-isopropyl-S-acetonyl-dithiocarbonate | 42573-98-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代缩醛
• 英文名称: O-isopropyl-S-acetonyl-dithiocarbonate
• 英文别名: O-Isopropyl-S-acetonyl-dithiocarbonat；O-propan-2-yl 2-oxopropylsulfanylmethanethioate
• CAS: 42573-98-8
• 化学式: C₇H₁₂O₂S₂
• 分子量: 192.303
• InChiKey: NVTCRVYJQDSMLK-UHFFFAOYSA-N

物化性质

• 沸点：
  260.2±23.0 °C(Predicted)
• 密度：
  1.152±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  83.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  O-isopropyl-S-acetonyl-dithiocarbonate 在 硫酸 作用下， 生成 4-methyl-[1,3]dithiol-2-one
  参考文献：
  名称：

  从 4-methyl-5-tri-n-butylstannyl-1,3-dithiol-2-one 和二氧化硒意外形成三硒化物

  摘要：

  摘要 当试图将 Riley 氧化应用于甲磺酸化前体而不是预期的醛时，获得了无环三硒化物，其中 Se3 链取代了两个前体的 nBu3Sn 取代基。发现该反应是完全可重现的。对含有 Se3 部分的产物进行了全面分析，包括 X 射线结构表征和 77Se 核磁共振，因此可能具有有益的生物活性。

  DOI：

  10.1016/j.inoche.2017.02.005
• 作为产物：
  描述：

  potassium isopropylxanthate 、 一氯丙酮 以 丙酮 为溶剂， 生成 O-isopropyl-S-acetonyl-dithiocarbonate
  参考文献：
  名称：

  General synthesis of 1,3-dithiol-2-ones

  摘要：

  DOI：

  10.1021/jo00915a021

文献信息

• KETONE-CONTAINING CONTROLLED RADICAL INITIATORS FOR POLYMERIZATION REACTIONS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200369820A1

  公开（公告）日：2020-11-26

  Controlled radical initiators that are ketone-containing dithiocarbamate or ketone-containing dithiocarbonate compounds are used to form polymeric materials that have a single polymeric block or multiple polymeric blocks. Reaction mixtures containing controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided.

  含酮的二硫代氨基甲酸盐或含酮的二硫代碳酸盐控制自由基引发剂用于形成具有单一聚合物块或多重聚合物块的聚合物材料。本发明提供了含有控制自由基引发剂和多种乙烯基不饱和单体的反应混合物、由反应混合物形成的聚合物材料、含有聚合物材料的可交联组合物、由可交联组合物形成的交联组合物，以及包含聚合物材料、可交联组合物或交联组合物的物品。
• Ketone-containing controlled radical initiators for polymerization reactions
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10941234B2

  公开（公告）日：2021-03-09

  Controlled radical initiators that are ketone-containing dithiocarbamate or ketone-containing dithiocarbonate compounds are used to form polymeric materials that have a single polymeric block or multiple polymeric blocks. Reaction mixtures containing controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided.

  含酮二硫代氨基甲酸酯或含酮二硫代碳酸酯化合物的受控自由基引发剂可用于形成具有单个或多个聚合物嵌段的聚合物材料。提供了含有受控自由基引发剂和各种乙烯基不饱和单体的反应混合物、由反应混合物形成的聚合材料、含有聚合材料的可交联组合物、由可交联组合物形成的交联组合物以及含有聚合材料、可交联组合物或交联组合物的物品。
• POLYMERIC MATERIALS FORMED USING INITIATORS WITH TWO THIOCARBONYLTHIO-CONTAINING GROUPS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20210095097A1

  公开（公告）日：2021-04-01

  Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, polymeric materials formed from the reaction mixtures, crosslinkable compositions containing the polymeric materials, crosslinked compositions formed from the crosslinkable compositions, and articles containing the polymeric materials, the crosslinkable compositions, or the crosslinked compositions are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds having a single carbon between the two dithiocarbamate or dithiocarbonate groups. Also attached to that single carbon is a ketone group.
• The unexpected formation of a triselenide from 4-methyl-5-tri- n -butylstannyl-1,3-dithiol-2-one and selenium dioxide
  作者：Claudia Schindler、Carola Schulzke

  DOI：10.1016/j.inoche.2017.02.005

  日期：2017.3

  Abstract When attempting to apply a Riley oxidation to a stannylated precursor instead of the expected aldehyde an acyclic triselenide was obtained in which a Se3 chain replaces the nBu3Sn substituents of two precursors. The reaction was found to be fully reproducible. The product bearing the Se3 moiety and, hence, potentially possessing beneficial biological activity was analyzed comprehensively including

  摘要 当试图将 Riley 氧化应用于甲磺酸化前体而不是预期的醛时，获得了无环三硒化物，其中 Se3 链取代了两个前体的 nBu3Sn 取代基。发现该反应是完全可重现的。对含有 Se3 部分的产物进行了全面分析，包括 X 射线结构表征和 77Se 核磁共振，因此可能具有有益的生物活性。
• General synthesis of 1,3-dithiol-2-ones
  作者：Ajit K. Bhattacharya、Alfred G. Hortmann

  DOI：10.1021/jo00915a021

  日期：1974.1