3,4-二亚甲基噻吩 | 105064-76-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 中文名称: 3,4-二亚甲基噻吩
• 英文名称: 3,4-dimethylenethiophene
• 英文别名: 3,4-Dimethylidenethiophene；3,4-dimethylidenethiophene
• CAS: 105064-76-4
• 化学式: C₆H₆S
• 分子量: 110.18
• InChiKey: KBXBVIIYYVUEPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3,4-二亚甲基噻吩 在 氧气 作用下， 以 二氯甲烷 为溶剂， 生成 1H,4H-thieno[3,4-d][1,2]dioxine
  参考文献：
  名称：

  杂环单峰双自由基反应的绝对速率通过纳秒时间分辨吸收光谱来确定。烯烃和双氧的二聚和环加成

  摘要：

  Singlet biradicals of the 3,4-dimethyleneheterocycle series, where the heterocycle is furan, thiophene, or N-substituted pyrrole, with chromophores in the UV-vis region (560-640 nm), are generated by nanosecond laser flash photolysis of diazene precursors in fluid solution. The rate constants for disappearance of these transients are determined by time-resolved absorption spectroscopy using the long-wavelength band. The rate constants for dimerization are near the encounter-controlled rate. Rates of trapping by alkenes are well described by a frontier orbital model. Oxygen trapping rate constants range between 10(7) and 10(9) M-1 s-1. The ratios of rate constants for trapping of 3,4-dimethylene-N-(p-toluenesulfonyl)pyrrole by pairs of alkenes in preparative competition experiments are in good agreement with those determined by the flash photolytic method. This confirms assignments of the 3,4-dimethyleneheterocycle structure to the chromophore of the biradical transients.

  DOI：

  10.1021/j100152a047
• 作为产物：
  描述：

  1,4-Dihydrothieno<3,4-d>-1,4-dihydropyridazine 以 乙腈 为溶剂， 生成 3,4-二亚甲基噻吩
  参考文献：
  名称：

  Absolute rates of dimerization and cycloaddition of 3,4-dimethylenefuran and 3,4-dimethylenethiophene by nanosecond time-resolved spectroscopy

  摘要：

  DOI：

  10.1021/ja00220a061

文献信息

• Parallel reactivity sequences in cycloadditions of singlet biradicals and Diels-Alder reactions. A common physical basis manifested as entropy control or enthalpy control
  作者：J. C. Scaiano、Veronique Wintgens、Karl Haider、Jerome A. Berson

  DOI：10.1021/ja00205a032

  日期：1989.11

  Reactivite des diradicaux dimethyl-3,4 furanne et dimethyl-3,4 thiophene, generes a partir des diazenes correspondants, vis-a-vis de divers composes vinyliques

  Reactive des diradicaux dimethyl-3,4 furanne et dimethyl-3,4 thiophene，generes a partir des diazenes 通讯员，vis-a-vis de divers composesvinyliques
• Absolute rates of dimerization and cycloaddition of 3,4-dimethylenefuran and 3,4-dimethylenethiophene by nanosecond time-resolved spectroscopy
  作者：J. C. Scaiano、Veronique. Wintgens、Ann. Bedell、Jerome A. Berson

  DOI：10.1021/ja00220a061

  日期：1988.6
• 3,4-Dimethylenefuran and 3,4-dimethylenethiophene, heterocyclic analogs of the disjoint non-Kekule hydrocarbon tetramethyleneethane
  作者：Keith J. Stone、Marc M. Greenberg、Joshua L. Goodman、Kevin S. Peters、Jerome A. Berson

  DOI：10.1021/ja00285a035

  日期：1986.12
• Ground-state multiplicities of 3,4-dimethylenefuran and 3,4-dimethylenethiophene. Experimental tests of ab initio and semiempirical theories of heteroatom-bridged disjoint biradicals
  作者：Marc M. Greenberg、Silas C. Blackstock、Keith J. Stone、Jerome A. Berson

  DOI：10.1021/ja00192a026

  日期：1989.5
• Absolute rates of heterocyclic singlet biradical reactions determined by nanosecond time-resolved absorption spectroscopy. Dimerizations and cycloadditions to alkenes and to dioxygen
  作者：Richard B. Heath、Linda C. Busch、Xu Wu Feng、Jerome A. Berson、J. C. Scaiano、Alain B. Berinstain

  DOI：10.1021/j100152a047

  日期：1993.12

  Singlet biradicals of the 3,4-dimethyleneheterocycle series, where the heterocycle is furan, thiophene, or N-substituted pyrrole, with chromophores in the UV-vis region (560-640 nm), are generated by nanosecond laser flash photolysis of diazene precursors in fluid solution. The rate constants for disappearance of these transients are determined by time-resolved absorption spectroscopy using the long-wavelength band. The rate constants for dimerization are near the encounter-controlled rate. Rates of trapping by alkenes are well described by a frontier orbital model. Oxygen trapping rate constants range between 10(7) and 10(9) M-1 s-1. The ratios of rate constants for trapping of 3,4-dimethylene-N-(p-toluenesulfonyl)pyrrole by pairs of alkenes in preparative competition experiments are in good agreement with those determined by the flash photolytic method. This confirms assignments of the 3,4-dimethyleneheterocycle structure to the chromophore of the biradical transients.