2,3',4'-Trimethyl-benzophenon | 20002-30-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3',4'-Trimethyl-benzophenon
• 英文别名: (3,4-Dimethylphenyl)(2-methylphenyl)methanone；(3,4-dimethylphenyl)-(2-methylphenyl)methanone
• CAS: 20002-30-6
• 化学式: C₁₆H₁₆O
• mdl: MFCD11211425
• 分子量: 224.302
• InChiKey: VIMFFCXDSCCYQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.187
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,3',4'-Trimethyl-benzophenon 在 (1R,2S)-N-picolinoyl ephedrine 、 三氯硅烷 、 四氯化钛 、 三乙胺 作用下， 以 二氯甲烷 、 1,2-二氯乙烷 为溶剂， 反应 55.0h， 生成 ((3,4-dimethylphenyl)(o-tolyl)methyl)(4-methoxyphenyl)amine
  参考文献：
  名称：

  对映选择性的路易斯碱催化的取代苯甲酮N-芳基亚胺的不对称氢化硅烷化：手性（二芳基甲基）胺的高效合成

  摘要：

  AbstractLewis‐base‐catalyzed asymmetric hydrosilylation of substituted benzophenone N‐aryl imines was investigated. Among various chiral Lewis‐base catalysts, a catalyst derived from L‐Serine was found to be the most favorable one which promote the reaction to afford a series of (diarylmethyl)amines with high yields (up to 97 %) in moderate to good enantioselectivities (up to 97 % ee). The absolute configuration of the product was determined by the X‐ray crystallographic analysis.magnified image

  DOI：

  10.1002/adsc.201400643
• 作为产物：
  描述：

  邻二甲苯 、 邻甲基苯甲酰氯 在 三氯化铝 作用下， 生成 2,3',4'-Trimethyl-benzophenon
  参考文献：
  名称：

  Baker et al., Journal of the Chemical Society, 1945, p. 27,29

  摘要：

  DOI：

文献信息

• YULDASHEV X. YU., DOKL. AN UZSSR, 1977, HO 11, 50-51
  作者：YULDASHEV X. YU.

  DOI：——

  日期：——
• POLYIMIDE-CO-POLYBENZOXAZOLE COPOLYMER, PREPARATION METHOD THEREOF, AND GAS SEPARATION MEMBRANE COMPRISING THE SAME
  申请人：Lee Young Moo

  公开号：US20110065823A1

  公开（公告）日：2011-03-17

  Disclosed herein are a polyimide-polybenzoxazole copolymer, a method for preparing thereof and a gas separation membrane comprising the same. More specifically, provided are a polyimide-polybenzoxazole copolymer simply prepared through thermal-rearrangement performed by thermally treating a polyimide-poly (hydroxyimide) copolymer as a precursor, a method for preparing the same, and a gas separation membrane comprising the same. The copolymer shows superior gas permeability and gas selectivity, thus being suitable for use in gas separation membranes in various forms such as films, fibers or hollow fibers. The gas separation membrane thus prepared can advantageously endure even harsh conditions such as long operation time acidic conditions and high humidity due to the rigid polymer backbone present in the copolymer.
• US8821617B2
  申请人：——

  公开号：US8821617B2

  公开（公告）日：2014-09-02
• Enantioselective Lewis-Base-Catalyzed Asymmetric Hydrosilylation of Substituted Benzophenone<i>N</i>-Aryl Imines: Efficient Synthesis of Chiral (Diarylmethyl)amines
  作者：Xiao-Yan Hu、Min-Min Zhang、Chang Shu、Yong-Hong Zhang、Li-Hua Liao、Wei-Cheng Yuan、Xiao-Mei Zhang

  DOI：10.1002/adsc.201400643

  日期：2014.11.24

  AbstractLewis‐base‐catalyzed asymmetric hydrosilylation of substituted benzophenone N‐aryl imines was investigated. Among various chiral Lewis‐base catalysts, a catalyst derived from L‐Serine was found to be the most favorable one which promote the reaction to afford a series of (diarylmethyl)amines with high yields (up to 97 %) in moderate to good enantioselectivities (up to 97 % ee). The absolute configuration of the product was determined by the X‐ray crystallographic analysis.magnified image
• Baker et al., Journal of the Chemical Society, 1945, p. 27,29
  作者：Baker et al.

  DOI：——

  日期：——