diisopropyl 2-methylbut-3-enylphosphonate | 1427527-85-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: diisopropyl 2-methylbut-3-enylphosphonate
• 英文别名: 4-Di(propan-2-yloxy)phosphoryl-3-methylbut-1-ene；4-di(propan-2-yloxy)phosphoryl-3-methylbut-1-ene
• CAS: 1427527-85-2
• 化学式: C₁₁H₂₃O₃P
• 分子量: 234.276
• InChiKey: VFVUSIKAABWPOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  diisopropyl iodomethylphosphonate 、 (Z)-crotyltri-n-butylstannane 在 indium(III) chloride 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以63%的产率得到diisopropyl 2-methylbut-3-enylphosphonate
  参考文献：
  名称：

  Indium(III) Halide-Catalyzed UV-Irradiated Radical Coupling of Iodomethylphosphorus Compounds with Various Organostannanes

  摘要：

  The first catalytic radical coupling of iodomethylphosphorus compounds was accomplished with allyl-, alkenyl-, and allenylstannanes under UV Irradiation in the presence of an indium(III) halide catalyst, for which a transmetalated allylic indium species was confirmed lobe an active radical species.

  DOI：

  10.1021/ol4005257

文献信息

• Indium(III) Halide-Catalyzed UV-Irradiated Radical Coupling of Iodomethylphosphorus Compounds with Various Organostannanes
  作者：Itaru Suzuki、Kensuke Kiyokawa、Makoto Yasuda、Akio Baba

  DOI：10.1021/ol4005257

  日期：2013.4.5

  The first catalytic radical coupling of iodomethylphosphorus compounds was accomplished with allyl-, alkenyl-, and allenylstannanes under UV Irradiation in the presence of an indium(III) halide catalyst, for which a transmetalated allylic indium species was confirmed lobe an active radical species.