C-2'-(2-methyl-1-propenyl)phenyl N-4-chlorophenylsulfonyloxaziridine | 250250-44-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: C-2'-(2-methyl-1-propenyl)phenyl N-4-chlorophenylsulfonyloxaziridine
• 英文别名: 2-(4-Chlorophenyl)sulfonyl-3-[2-(2-methylprop-1-enyl)phenyl]oxaziridine；2-(4-chlorophenyl)sulfonyl-3-[2-(2-methylprop-1-enyl)phenyl]oxaziridine
• CAS: 250250-44-3
• 化学式: C₁₇H₁₆ClNO₃S
• 分子量: 349.838
• InChiKey: CEPPHEGUEZQRSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  58.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  C-2'-(2-methyl-1-propenyl)phenyl N-4-chlorophenylsulfonyloxaziridine 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  The Endocyclic Restriction Test:  Oxygen Transfer from N-Sulfonyl Oxaziridines to Alkenes

  摘要：

  [GRAPHICS]The transition state for the transfer of oxygen from N-sulfonyl oxaziridines to alkenes has been investigated experimentally using the endocyclic restriction test. Molecules containing oxaziridines and alkenes were prepared and the ability of each system to intramolecularly transfer oxygen was evaluated, The results are consistent with a transition state in which N-O bond cleavage is more advanced than C-O bond cleavage.

  DOI：

  10.1021/ol990969w
• 作为产物：
  描述：

  2-(2'-methyl-1'-propenyl)benzaldehyde diethyl acetal 在 potassium carbonate 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 3.25h， 生成 C-2'-(2-methyl-1-propenyl)phenyl N-4-chlorophenylsulfonyloxaziridine
  参考文献：
  名称：

  The Endocyclic Restriction Test:  Oxygen Transfer from N-Sulfonyl Oxaziridines to Alkenes

  摘要：

  [GRAPHICS]The transition state for the transfer of oxygen from N-sulfonyl oxaziridines to alkenes has been investigated experimentally using the endocyclic restriction test. Molecules containing oxaziridines and alkenes were prepared and the ability of each system to intramolecularly transfer oxygen was evaluated, The results are consistent with a transition state in which N-O bond cleavage is more advanced than C-O bond cleavage.

  DOI：

  10.1021/ol990969w

文献信息

• The Endocyclic Restriction Test:  Oxygen Transfer from <i>N</i>-Sulfonyl Oxaziridines to Alkenes
  作者：David R. Anderson、Keith W. Woods、Peter Beak

  DOI：10.1021/ol990969w

  日期：1999.11.1

  [GRAPHICS]The transition state for the transfer of oxygen from N-sulfonyl oxaziridines to alkenes has been investigated experimentally using the endocyclic restriction test. Molecules containing oxaziridines and alkenes were prepared and the ability of each system to intramolecularly transfer oxygen was evaluated, The results are consistent with a transition state in which N-O bond cleavage is more advanced than C-O bond cleavage.