4,6-decadiyne-1,10-diyl bis-N-(4-dimethylaminophenyl)carbamate | 478404-29-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,6-decadiyne-1,10-diyl bis-N-(4-dimethylaminophenyl)carbamate
• 英文别名: 10-[[4-(dimethylamino)phenyl]carbamoyloxy]deca-4,6-diynyl N-[4-(dimethylamino)phenyl]carbamate
• CAS: 478404-29-4
• 化学式: C₂₈H₃₄N₄O₄
• 分子量: 490.602
• InChiKey: GOOSHLYSFYAPLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  36
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  83.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-二甲氨基苯异氰酸酯 在 copper(l) iodide 四氢吡咯 、 二丁基二异辛酸锡 、 氧气 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 2.67h， 生成 4,6-decadiyne-1,10-diyl bis-N-(4-dimethylaminophenyl)carbamate
  参考文献：
  名称：

  摘要：

  Carbamates of monoacetylene and diacetylene series were synthesized and characterized. A catalytic system CuI-pyrrolidine was applied for the first time to a synthesis of symmetrical diacetylenes by oxidative dimerization of terminal acetylenes. The comparative activity of diynes obtained was studied in the photoinitiated solid-phase topochemical polymerization. Diyne carbamates undergoing thermal polymerization were obtained for the first time.

  DOI：

  10.1023/a:1020326818084

文献信息

• ——
  作者：S. Yu. Vyazmin、S. E. Berezina、L. A. Remizova、I. N. Domnin、R. Gleiter

  DOI：10.1023/a:1020326818084

  日期：——

  Carbamates of monoacetylene and diacetylene series were synthesized and characterized. A catalytic system CuI-pyrrolidine was applied for the first time to a synthesis of symmetrical diacetylenes by oxidative dimerization of terminal acetylenes. The comparative activity of diynes obtained was studied in the photoinitiated solid-phase topochemical polymerization. Diyne carbamates undergoing thermal polymerization were obtained for the first time.