6,14,17,25-Tetraoxa-9,10,11,20,21,22-hexazahexacyclo[28.3.1.18,11.120,23.05,33.026,31]hexatriaconta-1(33),2,4,8(36),9,21,23(35),26,28,30-decaene-32,34-dione | 1206876-88-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 6,14,17,25-Tetraoxa-9,10,11,20,21,22-hexazahexacyclo[28.3.1.18,11.120,23.05,33.026,31]hexatriaconta-1(33),2,4,8(36),9,21,23(35),26,28,30-decaene-32,34-dione
• 英文别名: 6,14,17,25-tetraoxa-9,10,11,20,21,22-hexazahexacyclo[28.3.1.18,11.120,23.05,33.026,31]hexatriaconta-1(33),2,4,8(36),9,21,23(35),26,28,30-decaene-32,34-dione
• CAS: 1206876-88-1
• 化学式: C₂₆H₂₄N₆O₆
• 分子量: 516.513
• InChiKey: FLKJDMQPGZAYGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  38
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  133
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1,8-二叠氮基-3,5-二氧杂辛烷 、 1,8-bis(prop-2-ynyloxy)anthracene-9,10-dione 在 copper(l) iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以35%的产率得到6,14,17,25-Tetraoxa-9,10,11,20,21,22-hexazahexacyclo[28.3.1.18,11.120,23.05,33.026,31]hexatriaconta-1(33),2,4,8(36),9,21,23(35),26,28,30-decaene-32,34-dione
  参考文献：
  名称：

  Novel Optical/Electrochemical Selective 1,2,3-Triazole Ring-Appended Chemosensor for the Al³⁺ Ion

  摘要：

  A chemosensor (1) bearing a 1,2,3-triazole ring spacer was synthesized for the selective detection of Al3+ with respect to dual optical and electrochemical changing events. The addition of Al+ ions to 1 induced a significant change in fluorescence intensity, attributable to ICT and CHEF effects from the 1,2,3-triazole ring. The electrochemical behavior of 1 in the presence of the Al3+ ion was significantly altered compared with those of the other metal cations tested.

  DOI：

  10.1021/ol902743s

文献信息

• Novel Optical/Electrochemical Selective 1,2,3-Triazole Ring-Appended Chemosensor for the Al³⁺ Ion
  作者：Sang Hoon Kim、Hong Seok Choi、Joohoon Kim、Suk Joong Lee、Duong Tuan Quang、Jong Seung Kim

  DOI：10.1021/ol902743s

  日期：2010.2.5

  A chemosensor (1) bearing a 1,2,3-triazole ring spacer was synthesized for the selective detection of Al3+ with respect to dual optical and electrochemical changing events. The addition of Al+ ions to 1 induced a significant change in fluorescence intensity, attributable to ICT and CHEF effects from the 1,2,3-triazole ring. The electrochemical behavior of 1 in the presence of the Al3+ ion was significantly altered compared with those of the other metal cations tested.