2-methoxy-4-nitro-1-(prop-2-yn-1-yloxy) benzene | 63147-90-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-methoxy-4-nitro-1-(prop-2-yn-1-yloxy) benzene
• 英文别名: 2-Methoxy-4-nitro-1-[(prop-2-yn-1-yl)oxy]benzene；2-methoxy-4-nitro-1-prop-2-ynoxybenzene
• CAS: 63147-90-0
• 化学式: C₁₀H₉NO₄
• 分子量: 207.186
• InChiKey: DFCAXQQRGMZILL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  64.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-methoxy-4-nitro-1-(prop-2-yn-1-yloxy) benzene 以 various solvent(s) 为溶剂， 反应 2.0h， 以46%的产率得到7-Methoxy-2-methyl-5-nitro-benzofuran
  参考文献：
  名称：

  聚乙二醇中芳基炔丙基醚的克莱森重排-显着的取代基和溶剂作用

  摘要：

  在200°C下，聚乙二醇（200）中的芳基炔丙基醚进行克莱森重排，可以提供高收率的产品。含有给电子基团的芳基炔丙基醚产生（2H）-苯并吡喃，而含有吸电子基团的芳基炔丙基醚产生2-甲基苯并呋喃。

  DOI：

  10.1016/s0040-4039(01)99839-9
• 作为产物：
  描述：

  4-硝基愈创木酚 、 3-溴丙炔 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 生成 2-methoxy-4-nitro-1-(prop-2-yn-1-yloxy) benzene
  参考文献：
  名称：

  Appriou,P. et al., Bulletin de la Societe Chimique de France, 1976, p. 2039 - 2046

  摘要：

  DOI：

文献信息

• RAO, U.;BALASUBRAMANIAN, K. K., TETRAHEDRON LETT., 1983, 24, N 45, 5023-5024
  作者：RAO, U.、BALASUBRAMANIAN, K. K.

  DOI：——

  日期：——
• Combination of Novel Nitrification Inhibitors and Biopesticides as Well as Combination of (Thio)Phosphoric Acid Triamides and Biopesticides
  申请人：BASF SE

  公开号：US20170181435A1

  公开（公告）日：2017-06-29

  A composition including (a) at least one (thio)phosphoric acid triamide (T) according to the general formula (Ia) R a1 R a2 N—P(X)(NH 2 ) 2 (Ia) wherein X is oxygen or sulfur; R a1 is a C 1 to C 20 alkyl, C 3 to C 20 cycloalkyl, C 6 to C 20 aryl, or dialkylaminocarbonyl group; R a2 is H, or R a1 and R a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur; and (b) at least one biopesticide.
• US9968092B2
  申请人：——

  公开号：US9968092B2

  公开（公告）日：2018-05-15
• [EN] COMBINATION OF NOVEL NITRIFICATION INHIBITORS AND HERBICIDES AS WELL AS COMBINATION OF (THIO)PHOSPHORIC ACID TRIAMIDES AND HERBICIDES<br/>[FR] COMBINAISON DE NOUVEAUX INHIBITEURS DE NITRIFICATION ET D'HERBICIDES AINSI QU'UNE COMBINAISON DE TRIAMIDES D'ACIDE (THIO)PHOSPHORIQUE ET D'HERBICIDES
  申请人：BASF SE

  公开号：WO2015081349A2

  公开（公告）日：2015-06-04

  A composition comprising c) at least one (thio)phosphoric acid triamide (T) according to the general formula (la) Ra1 Ra2N_p(X)(NH2)2 (|a) wherein X is oxygen or sulfur; Ra1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkyl- aminocarbonyl group; Ra2 is H, or Ra1 and Ra2 together with the nitrogen atom linking them define a 5- or 6- membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and at least one specific herbicide.
• [EN] NOVEL NITRIFICATION INHIBITORS<br/>[FR] INHIBITEURS DE NITRIFICATION D'UN NOUVEAU TYPE
  申请人：BASF SE

  公开号：WO2015158853A1

  公开（公告）日：2015-10-22

  The present invention relates to novel nitrification inhibitors of formula I. Moreover, the invention relates to the use of these novel nitrification inhibitors for reducing nitrification, as well as agrochemical mixtures and compositions comprising the nitrification inhibitors. Further encompassed by the present invention are methods for reducing nitrification comprising the treatment of plants, soil and/or loci with said nitrification inhibitors, and methods for treating a fertilizer or a composition by applying said nitrification inhibitor.