(1R,2R)-N,N'-bis(5-bromothiophen-2-ylmethyl)-1,2-diaminocyclohexane | 347868-84-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (1R,2R)-N,N'-bis(5-bromothiophen-2-ylmethyl)-1,2-diaminocyclohexane
• 英文别名: (1R,2R)-1-N,2-N-bis[(5-bromothiophen-2-yl)methyl]cyclohexane-1,2-diamine
• CAS: 347868-84-2
• 化学式: C₁₆H₂₀Br₂N₂S₂
• 分子量: 464.288
• InChiKey: FINMJTQFWHPUOF-ZIAGYGMSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  80.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (1R,2R)-N,N'-bis(5-bromothiophen-2-ylmethyl)-1,2-diiminocyclohexane 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 以85%的产率得到(1R,2R)-N,N'-bis(5-bromothiophen-2-ylmethyl)-1,2-diaminocyclohexane
  参考文献：
  名称：

  A chiral polymer with alternating conjugated segments and (1 R, 2 R )-1,2-diaminocyclohexane as a unit with C 2 symmetry

  摘要：

  A chiral conjugated polymer was prepared via the palladium catalysed coupling reaction between 1,4-di-ynyl-2,5-dialkoxybenzene and a bis-5-bromothienyl derivative of (1R,2R)-1,2-diaminocyclohexane as a chiral unit with C-2 symmetry and a unit with complexing properties. The resulting chiral polymer of which it's backbone consists of alternating conjugated segments and chiral complexing units, showed intense luminescence properties and was used as a ligand in the rhodium-catalysed hydride transfer reduction. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00387-2
• 作为试剂：
  描述：

  苯乙酮 在 氢氧化钾 chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 1,4-diethynyl-2,5-bis(octoxy)benzene 、 (1R,2R)-N,N'-bis(5-bromothiophen-2-ylmethyl)-1,2-diaminocyclohexane 作用下， 以 四氢呋喃 、 异丙醇 为溶剂， 反应 144.0h， 以46%的产率得到苏合香醇
  参考文献：
  名称：

  A chiral polymer with alternating conjugated segments and (1 R, 2 R )-1,2-diaminocyclohexane as a unit with C 2 symmetry

  摘要：

  A chiral conjugated polymer was prepared via the palladium catalysed coupling reaction between 1,4-di-ynyl-2,5-dialkoxybenzene and a bis-5-bromothienyl derivative of (1R,2R)-1,2-diaminocyclohexane as a chiral unit with C-2 symmetry and a unit with complexing properties. The resulting chiral polymer of which it's backbone consists of alternating conjugated segments and chiral complexing units, showed intense luminescence properties and was used as a ligand in the rhodium-catalysed hydride transfer reduction. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00387-2

文献信息

• A chiral polymer with alternating conjugated segments and (1 R, 2 R )-1,2-diaminocyclohexane as a unit with C 2 symmetry
  作者：Jean-Pierre Lère-Porte、Joël J.E Moreau、Françoise Serein-Spirau、Salem Wakim

  DOI：10.1016/s0040-4039(01)00387-2

  日期：2001.4

  A chiral conjugated polymer was prepared via the palladium catalysed coupling reaction between 1,4-di-ynyl-2,5-dialkoxybenzene and a bis-5-bromothienyl derivative of (1R,2R)-1,2-diaminocyclohexane as a chiral unit with C-2 symmetry and a unit with complexing properties. The resulting chiral polymer of which it's backbone consists of alternating conjugated segments and chiral complexing units, showed intense luminescence properties and was used as a ligand in the rhodium-catalysed hydride transfer reduction. (C) 2001 Elsevier Science Ltd. All rights reserved.