dodecylbutanediperoxoic acid | 87458-70-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: dodecylbutanediperoxoic acid
• 英文别名: Butanediperoxoic acid, dodecyl-；2-dodecylbutanediperoxoic acid
• CAS: 87458-70-6
• 化学式: C₁₆H₃₀O₆
• 分子量: 318.411
• InChiKey: VQNGHUKPEOOZEX-UHFFFAOYSA-N

物化性质

• 沸点：
  449.7±55.0 °C(Predicted)
• 密度：
  1.079±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  22
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N-十二烷基琥珀酸酐 在 双氧水 作用下， 以 (2S)-N-methyl-1-phenylpropan-2-amine hydrate 、 甲烷磺酸 为溶剂， 生成 dodecylbutanediperoxoic acid
  参考文献：
  名称：

  Substituted-butanediperoxoic acids and process for bleaching

  摘要：

  化学式为##STR1##的取代丁二过氧酸，其中R为6到18个碳原子的烷基或苯基，是有用的氧化剂。这些取代丁二过氧酸可用作漂白剂和消毒剂。

  公开号：

  US04435335A1

文献信息

• Controlled release laundry bleach product
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0070066A1

  公开（公告）日：1983-01-19

  A hydrophilic or hydrotropic peroxyacid laundry bleach plus a surfactant bleach release-delaying agent, contained inside a pouch, bag or substrate, provides a controlled bleach release laundry product.

  亲水性或亲水性过氧乙酸洗衣漂白剂加上表面活性剂漂白释放延缓剂，装在小袋、袋子或基材中，可提供一种可控漂白释放的洗衣产品。
• Substituted-butanediperoxoic acid and process for bleaching
  申请人：MONSANTO COMPANY

  公开号：EP0083560A1

  公开（公告）日：1983-07-13

  Substituted-butanediperoxoic acids represented by the formula: wherein R is alkyl of 6 to 18 carbon atoms or phenyl are useful oxidizing agents. These substituted-butanediperoxoic acids are useful as bleaching agents and disinfecting agents.

  式中 R 为 6 至 18 个碳原子的烷基或苯基的取代丁基哌啶氧酸是有用的氧化剂： 其中 R 是 6 至 18 个碳原子的烷基或苯基，是有用的氧化剂。这些取代的丁基哌啶氧酸可用作漂白剂和消毒剂。
• Production of substituted-butanediperoxoic acids
  申请人：Monsanto Company

  公开号：EP0136280A2

  公开（公告）日：1985-04-03

  Substituted-butanediperoxoic acid is produced by reacting substituted succinic anhydride with a mixture of concentrated sulfuric acid and hydrogen peroxide. The substituted-butanediperoxoic acids are particularly useful as bleaching agents.

  取代丁基哌啶氧酸是由取代琥珀酸酐与浓硫酸和过氧化氢的混合物反应生成的。 取代丁基哌啶氧酸特别适用于漂白剂。
• Stabilized compositions containing peroxygen compounds
  申请人：MONSANTO COMPANY

  公开号：EP0384911A2

  公开（公告）日：1990-08-29

  Stabilized bleach compositions are disclosed comprising peroxygen compounds or a precursor thereof and a stabilizing amount of a polyhydroxamic acid or salt thereof wherein a polymer has a plurality of hydroxamato |groups of the formula: where R represents hydrogen or an optionally substituted alkyl group having from 1 to 6 carbon atoms in the alkyl group.

  本发明公开了稳定漂白剂组合物，该组合物包含过氧化合物或其前体，以及稳定量的聚羟肟酸或其盐，其中聚合物具有多个式中的羟酰胺基团： 其中 R 代表氢或烷基中含有 1 至 6 个碳原子的任选取代的烷基。
• Hydroxamate bleach stabilizer
  申请人：MONSANTO COMPANY

  公开号：EP0384912A2

  公开（公告）日：1990-08-29

  There are disclosed compositions comprising peroxygen containing bleach systems containing a bleach stabilizing amount of compound represented by the formula wherein R is selected from the group consisting of optionally substituted straight and branched chained alkyl C₁-₂₁, alkenyl C₁-₂₁, hydrogen, and optionally substituted phenyl groups, and wherein each R˝ is independently selected from groups consisting of hydrogen, alkyl C₁-₂₁ and alkenyl C₁-₂₁, provided that the total number of carbons in both R˝ groups is not greater than 21, each X is independently selected from hydrogen and SO₃ and Z is selected from the group consisting of hydroxy, alkoxy C₁-5 and alkenoxy C₁-₅, -O⁻M⁺, -NR₂‴ wherein each R‴ is independently selected from the group consisting of hydrogen, alkyl C₁-₅ or alkenyl C₁-₅, and R′ is selected from the group consisting of hydrogen, optionally substituted straight and branched chained alkyl C₁-₂₁, alkenyl C₁-₂₁ and an optionally substituted phenyl group, provided only one of R and R′ is hydrogen said stabilizer having a hydrophile-lipophile (HLB) balance within the same range as the HLB of said compounds wherein R is an unsubstituted C₁-₂₁ alkyl group and R′ is hydrogen or an unsubstituted C₁-₆ alkyl group, M is selected from hydrogen and a non-­interfering cation, and further provided that when M⁺ represents hydrogen and the composition contains a detergent active agent, the bleaching agent is selected from an inorganic peroxy compounds and bleach activator combination or an organic peroxy acid.

  本发明公开了由含过氧的漂白剂体系组成的组合物，该体系含有一定量的漂白剂稳定剂，该化合物由式表示 其中 R 选自任选取代的直链和支链烷基 C₁-₂₁、烯基 C₁-₂₁、氢和任选取代的苯基组成的组，以及 其中每个 R˝独立选自由氢、C₁-₂₁烷基和 C₁-₂₁ 烯基组成的基团，条件是两个 R˝ 基团中的碳总数不大于 21，每个 X 独立选自由氢和 SO₃，Z 选自由羟基组成的基团、烷氧基 C₁-5、烯氧基 C₁-₅、-O-M⁺、-NR₂‴，其中每个 R‴ 独立选自由氢组成的组、烷基 C₁-₅或烯基 C₁-₅，且 R′选自由氢、任选取代的直链和支链烷基 C₁-₂₁组成的组、烯基 C₁-₂₁和任选取代的苯基、只要 R 和 R′中只有一个是氢，所述稳定剂具有与所述化合物的 HLB 相同范围内的亲水-亲脂（HLB）平衡，其中 R 是未取代的 C₁-₂₁烷基，R′是氢或未取代的 C₁-₆烷基、M 选自氢和非干扰性阳离子，条件是当 M⁺ 代表氢且组合物含有洗涤活性剂时，漂白剂选自无机过氧化合物和漂白活化剂组合或有机过氧酸。