bis-(2,3,5,6-tetrachloro-phenyl)-disulfide | 81081-98-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(2,3,5,6-tetrachloro-phenyl)-disulfide
• 英文别名: Bis-(2,3,5,6-tetrachlor-phenyl)-disulfid；2,2',3,3',5,5',6,6'-Octachlordiphenyldisulfid；1,2,4,5-Tetrachloro-3-[(2,3,5,6-tetrachlorophenyl)disulfanyl]benzene
• CAS: 81081-98-3
• 化学式: C₁₂H₂Cl₈S₂
• 分子量: 493.904
• InChiKey: ZNTWBKFKQSOEPV-UHFFFAOYSA-N

物化性质

• 熔点：
  138-139 °C
• 沸点：
  489.6±45.0 °C(Predicted)
• 密度：
  1.85±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,3,5,6-tetrachlorobenzene-1-sulfonyl chloride 在 氢溴酸 、 溶剂黄146 、 苯酚 作用下， 生成 bis-(2,3,5,6-tetrachloro-phenyl)-disulfide
  参考文献：
  名称：

  Lukaschevitsch, Doklady Akademii Nauk SSSR, 1955, vol. 103, p. 627,629

  摘要：

  DOI：

文献信息

• GOLF BALL
  申请人：TARAO Toshiyuki

  公开号：US20120021853A1

  公开（公告）日：2012-01-26

  An object of the present invention is to provide a golf ball having a high resilience with a high spin rate on the approach shots. The present invention provides a golf ball comprising a constituting member that is formed from a polyurethane composition containing a polyurethane elastomer as a resin component, the polyurethane composition satisfying properties of a rebound resilience of 54% or more and a shear loss modulus G″ of 5.03×10 6 Pa or less when measured at the conditions of the temperature of 0° C., the oscillation frequency of 10 Hz, and in a shear mode using a dynamic viscoelasticity measuring apparatus.

  本发明的目的是提供一种高回弹性并在接近球洞的击球时具有高旋转率的高尔夫球。本发明提供了一种高尔夫球，其包括由聚氨酯弹性体作为树脂成分形成的构成成员，所述聚氨酯组合物在温度为0℃，振动频率为10 Hz，并使用动态粘弹性测量仪以剪切模式测量时，具有反弹回弹性为54%或更高和剪切损失模量G″为5.03×106Pa或更低的性质。
• PRODUCTION OF POLYARYLENE THIOETHER
  申请人：RESEARCH INSTITUTE FOR PRODUCTION DEVELOPMENT

  公开号：EP0402481A1

  公开（公告）日：1990-12-19

  This invention discloses a method for producing polyarylene thioether by the catalytic oxidative coupling polymerization of at least one compound selected from the group consisting of diaryl disulfides of general formula (I) and thiophenols of general formula (11), wherein R1 to R12 are each as defined in the specification, by using oxygen in the presence of an acid. According to the above method, the reaction proceeds under very mild conditions; the procedure can be simplified; and the starting material and catalyst an available at extremely low cost. Thus, this method is advantageous industrially.

  本发明公开了一种生产聚芳基硫醚的方法，该方法是在酸存在下，利用氧催化至少一种选自通式(I)的二芳基二硫化物和通式(11)的噻吩酚（其中 R1 至 R12 各为本说明书中定义的）所组成的组中的化合物的氧化偶联聚合。根据上述方法，反应在非常温和的条件下进行；程序可以简化；起始材料和催化剂成本极低。因此，这种方法在工业上很有优势。
• Golf ball resin composition and golf ball using the same
  申请人：DUNLOP SPORTS CO. LTD.

  公开号：US10005855B2

  公开（公告）日：2018-06-26

  An object of the present invention is to provide a golf ball resin composition that comprises an ionomer resin with an excellent resilience and fluidity. Another object of the present invention is to provide a golf ball excellent in the resilience without lowering the durability significantly in a golf ball using the ionomer resin for the intermediate layer. The present invention provides a golf ball resin composition comprising, 100 parts by mass of (A) an ionomer resin consisting of a metal ion-neutralized product of a ternary copolymer composed of ethylene, α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and α,β-unsaturated carboxylic acid ester, and from 25 parts to 100 parts by mass of (B) a metal salt of a fatty acid having 18 to 30 carbon atoms. The golf ball of the present invention is not limited, as long as it comprises a constituent member formed from the golf ball resin composition of the present invention.

  本发明的一个目的是提供一种高尔夫球树脂组合物，该组合物包括一种具有优异回弹性和流动性的离子聚合物树脂。本发明的另一个目的是提供一种具有优异回弹性的高尔夫球，在使用该离子聚合物树脂作为中间层的高尔夫球中，耐久性不会明显降低。本发明提供了一种高尔夫球树脂组合物，该组合物包括 100 份（按重量计）由乙烯、具有 3 至 8 个碳原子的α，β-不饱和羧酸和α，β-不饱和羧酸酯组成的三元共聚物的金属离子中和产物构成的离子聚合物树脂，以及 25 份至 100 份（按重量计）具有 18 至 30 个碳原子的脂肪酸的金属盐。本发明的高尔夫球不受限制，只要它包括由本发明的高尔夫球树脂组合物形成的构件即可。
• Golf ball
  申请人：DUNLOP SPORTS CO. LTD.

  公开号：US10232226B2

  公开（公告）日：2019-03-19

  A golf ball 2 includes a core 4, a mid layer 6, and a cover 8. A difference DH in hardness between a surface and a central point of the core 4, a thickness Tm and a hardness Hm of the mid layer 6, a thickness Tc and a hardness Hc of the cover 8, and an amount of compressive deformation Sb of the golf ball 2 meet the following mathematical formulas (DH*Hm)/(Hc*Tc)>80 and ((Sb*Tc)/(Hc*Hm*Tm))*1000>0.75. A hardness Hc of the cover 8 is equal to or less than 40. A material of the cover 8 is a resin composition. The resin composition includes a polyurethane (A) and a polyrotaxane (B).

  高尔夫球 2 包括球芯 4、中层 6 和外层 8。球芯 4 的表面和中心点之间的硬度差 DH、中层 6 的厚度 Tm 和硬度 Hm、外层 8 的厚度 Tc 和硬度 Hc 以及高尔夫球 2 的压缩变形量 Sb 符合以下数学公式 (DH*Hm)/(Hc*Tc)>80 且 ((Sb*Tc)/(Hc*Hm*Tm))*1000>0.75 。盖板 8 的硬度 Hc 等于或小于 40。盖板 8 的材料是一种树脂组合物。树脂组合物包括聚氨酯 (A) 和聚碳酸酯 (B)。
• Solid golf ball
  申请人：——

  公开号：US20030114246A1

  公开（公告）日：2003-06-19

  A solid golf ball with a polyurethane cover is provided which is satisfactory in the moldability of the cover and in ball characteristics such as a shot feeling and a flight distance. The solid golf ball of the invention includes a solid center, an intermediate layer, and a polyurethane cover. A material having a flexural modulus of from 150 to 420 MPa is used for the intermediate layer in order for the golf ball to offer satisfactory shot feeling and flight distance. By the use of a vulcanizate of a rubber composition containing a diphenyl disulfide for the solid center, the golf ball can exhibit an increased flight distance. In order to enhance the moldability of the cover a urethane prepolymer having a residual isocyanate monomer content of not more than 0.5% by mass is used.

  本发明提供了一种带有聚氨酯外层的实心高尔夫球，它在外层的成型性以及击球感和飞行距离等球的特性方面都令人满意。本发明的实心高尔夫球包括实心中心、中间层和聚氨酯外层。为了使高尔夫球具有令人满意的击球感和飞行距离，中间层使用了一种弯曲模量为 150 至 420 兆帕的材料。通过使用含有二苯基二硫化物的橡胶硫化组合物作为固体中心，高尔夫球的飞行距离可以增加。为了提高外层的成型性，使用了残留异氰酸酯单体含量不超过 0.5%（质量百分比）的聚氨酯预聚物。