3,6-双(4-苯基苯基)苯-1,2-二胺 | 868770-61-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3,6-双(4-苯基苯基)苯-1,2-二胺
• 英文名称: 3,6-Bis(4-phenylphenyl)benzene-1,2-diamine
• 英文别名: 3,6-bis(4-phenylphenyl)benzene-1,2-diamine
• CAS: 868770-61-0
• 化学式: C₃₀H₂₄N₂
• 分子量: 412.534
• InChiKey: DNYNOKPFBBJGMG-UHFFFAOYSA-N

物化性质

• 沸点：
  675.8±55.0 °C(Predicted)
• 密度：
  1.161±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 、 3,6-双(4-苯基苯基)苯-1,2-二胺 在 三乙胺 作用下， 以 乙醇 为溶剂， 反应 5.0h， 生成 10,13-bis(4-biphenylyl)dipyrido[3,2-a:2',3'-c]phenazine
  参考文献：
  名称：

  Novel 10,13-disubstituted dipyrido[3,2-a:2′,3′-c]phenazines and their platinum(II) complexes: highly luminescent ICT-type fluorophores based on D–A–D structures

  摘要：

  DOI：

  10.1016/j.tetlet.2014.07.069
• 作为产物：
  描述：

  4-双苯硼酸频那醇酯 在 lithium aluminium tetrahydride 、 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 、 乙二醇二甲醚 、 乙醇 、 水 为溶剂， 反应 25.0h， 生成 3,6-双(4-苯基苯基)苯-1,2-二胺
  参考文献：
  名称：

  Novel 10,13-disubstituted dipyrido[3,2-a:2′,3′-c]phenazines and their platinum(II) complexes: highly luminescent ICT-type fluorophores based on D–A–D structures

  摘要：

  DOI：

  10.1016/j.tetlet.2014.07.069

文献信息

• Synthesis, chemical properties, and electrochemical behavior of a Pt(II) complex bearing a benzenediamide-derived ligand
  作者：Take-aki Koizumi、Takuya Teratani、Takakazu Yamamoto

  DOI：10.1016/j.inoche.2010.11.018

  日期：2011.1

  The reaction of [PtCl2(cod)] [(cod = 1,5-cyclooctadiene) with Ph-Ph'-Ph'(2,3-NH2)-Ph'-Ph (LH2) (Ph = phenyl; Ph' = p-phenylene; Ph'(2.3-NH2) = p-phenylene-2,3-diamine) gave a new platinum(II) complex bearing a pi-conjugated Ph-Ph'-Ph'(2,3-NH)-Ph'-Ph (L. Ph'(2,3-NH) = p-phenylene-2,3-diamide) ligand, [Pt(L)(cod)], with the liberation of 2 HCl. The X-ray structure determination of the complex confirmed the coordination of the ligand to the platinum center in an o-benzenediamide form. The cyclic voltammogram of the complex showed reversible two-step [Pt-bda](0)/[Pt-sqdi](+) and [Pt-sqdi](+)/[Pt-bqdi](2+) redox couples (bda = o-benzenediamide, sqdi = o-semiquinone diimine, bqdi = o-benzoquinone diimine). (C) 2010 Elsevier B.V. All rights reserved.
• p-Quinquephenyl diamine, C6H5–p-C6H4–p-C6H2(2,3-NH2)–p-C6H4–C6H5, and its corresponding diimine–Ru(II) complex: Crystal structure and electrochemical and optical properties
  作者：Take-aki Koizumi、Bong-Jin Choi、Takakazu Yamamoto

  DOI：10.1016/j.ica.2007.10.036

  日期：2008.5

  The molecular structure of an o-phenylenediamine unit-containing oligophenylene (1), Ph-Ph'-Ph'(2,3-NH2)-Ph'-Ph (Ph = phenyl; Ph' = p-phenylene; Ph'(2,3-NH2) = 2,3-diamino-p-phenylene), was determined by X-ray crystallography. 1 has a twisted structure, and forms an intermolecular C-H center dot center dot center dot p interaction network. The-NH2 group of 1 was air-oxidized to an imine, =NH, group in the presence of [RuCl2(bpy)(2)] (bpy = 2,2'-bipyridyl) and gave a ruthenium(II)-benzoquinone diimine complex [Ru(2)(bpy)(2)](PF6)(2) (2: Ph-Ph'-Ph'(2,3-imine)-Ph'-Ph). The molecular structure of [Ru(2)(bpy)(2)](PF6)(2) was confirmed by X-ray crystallography. [Ru(2)(bpy)(2)](PF6)(2) underwent two-step electrochemical reduction with E-1/2 = -0.889 V and -1.531 V versus Fc(+)/Fc. The E(1/2,)s were located at higher potentials by 91 mV and 117 mV, respectively, than those of reported [Ru(bqdi)(bpy)(2)](PF6)(2) (bqdi = benzoquinone diimine). Electrochemical oxidation of [Ru(2)(bpy)(2)](PF6)(2) occurred at a lower potential by 180 mV than that of [Ru(bqdi)(bpy)(2)](PF6)(2). Occurrence of the easier reduction and oxidation of [Ru(2)(bpy)(2)](PF6)(2) than those of [Ru(bqdi)(bpy)(2)](PF6)(2) is ascribed to the presence of a large pi-conjugation system in 2. (C) 2007 Elsevier B.V. All rights reserved.