3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟辛基)噻吩 | 96721-82-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 中文名称: 3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟辛基)噻吩
• 英文名称: 3-perfluoro-n-octylthiophene
• 英文别名: 3-(perfluorooctyl)thiophene；Thiophene, 3-(heptadecafluorooctyl)-；3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)thiophene
• CAS: 96721-82-3
• 化学式: C₁₂H₃F₁₇S
• 分子量: 502.195
• InChiKey: HCQJAAKQIMFGKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟辛基)噻吩 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 、 溶剂黄146 为溶剂， 反应 0.08h， 以80%的产率得到2-bromo-4-(perfluorooctyl)thiophene
  参考文献：
  名称：

  Conjugated thiophene compound comprising perfluorinated and alkylated sidechains, conductive organic thin film containing the compound, and field-effect type organic transistor employing the thin film

  摘要：

  一种π共轭化合物，具有由式(I)和式(II)表示的环，在式(I)的环之间插入奇数个环，在式(II)的环之间插入奇数个环：其中R1和R2是氢或取代或未取代的1至20个碳原子的直链、环状或支链烷基，至少一个R1和R2不是氢；而R3和R4是氢或取代或未取代的1至20个碳原子的直链、环状或支链全氟烷基。

  公开号：

  US07462726B2
• 作为产物：
  描述：

  3-碘噻吩 、 全氟辛基碘烷 在 铜 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以60%的产率得到3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟辛基)噻吩
  参考文献：
  名称：

  Conjugated thiophene compound comprising perfluorinated and alkylated sidechains, conductive organic thin film containing the compound, and field-effect type organic transistor employing the thin film

  摘要：

  一种π共轭化合物，具有由式(I)和式(II)表示的环，在式(I)的环之间插入奇数个环，在式(II)的环之间插入奇数个环：其中R1和R2是氢或取代或未取代的1至20个碳原子的直链、环状或支链烷基，至少一个R1和R2不是氢；而R3和R4是氢或取代或未取代的1至20个碳原子的直链、环状或支链全氟烷基。

  公开号：

  US07462726B2

文献信息

• Conjugated thiophene compound, conprising perfluorinated and alkylated sidechains, conductive organic thin film containing the compound, and field-effect type organic transistor employing the thin film
  申请人：Nakamura Shinichi

  公开号：US20060234335A1

  公开（公告）日：2006-10-19

  A π-conjugated compound has rings represented by Formulae (I) and (II), an odd number of rings being interposed between the rings of Formula (I), and an odd number of rings being interposed between the rings of Formula (II): where R 1 and R 2 are hydrogen or a substituted or unsubstituted linear, cyclic, or branched alkyl group of 1 to 20 carbon atoms, at least one of R 1 and R 2 being not hydrogen; and R 3 and R 4 are hydrogen or a substituted or unsubstituted linear, cyclic, or branched perfluoroalkyl group of 1 to 20 carbon atoms.

  一种π-共轭化合物，其环由式（I）和（II）表示，奇数个环被插入在式（I）的环之间，奇数个环被插入在式（II）的环之间：其中R1和R2为氢或取代或未取代的1至20个碳原子的线性、环状或支链烷基，其中至少一个不是氢；R3和R4为氢或取代或未取代的1至20个碳原子的线性、环状或支链全氟烷基。
• Copper-mediated perfluoroalkylation of halogenothiophenes
  作者：J. Leroy、M. Rubinstein、C. Wakselman

  DOI：10.1016/s0022-1139(00)81309-3

  日期：1985.3
• LEROY, J.;RUBINSTEIN, M.;WAKSELMAN, C., J. FLUOR. CHEM., 1985, 27, N 3, 291-298
  作者：LEROY, J.、RUBINSTEIN, M.、WAKSELMAN, C.

  DOI：——

  日期：——
• MATRIX NANOCOMPOSITE SENSING FILM FOR SAW/BAW BASED HYDROGEN SULPHIDE SENSOR AND METHOD FOR MAKING SAME
  申请人：Serban Bogdan-Catalin

  公开号：US20090280593A1

  公开（公告）日：2009-11-12

  A method can be adapted for design and preparation of a matrix nanocomposite sensing film for hydrogen sulphide SAW/BAW detection at room temperature. A matrix nanocomposite can be synthesized by incorporating both single-wall and multi-wall thiolated carbon nanotubes into conductive organic polymers or ceramic nanocrystalline in a properly functionalized manner. A thin organic sensing film can be prepared based on the matrix nanocomposite. The matrix nanocomposite sensing film can be prepared on a surface of a SAW/BAW device by an additive process or a direct printing process. Finally, the sensing film can be consolidated by thermal annealing or laser annealing under ambient conditions in order to obtain the stable sensing film with higher sensitivity and electrical properties for a SAW/BAW based H 2 S sensor.
• SILICON-BASED ENERGY STORAGE DEVICES WITH FUNCTIONAL THIOPHENE COMPOUNDS OR DERIVATIVES OF THIOPHENE CONTAINING ELECTROLYTE ADDITIVES
  申请人：Enevate Corporation

  公开号：US20200388881A1

  公开（公告）日：2020-12-10

  Electrolytes and electrolyte additives for energy storage devices comprising functional thiophene compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from a thiophene compound.