| 1169882-15-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1169882-15-8
• 化学式: C₁₃H₁₃PPd
• 分子量: 306.64
• InChiKey: PYXJCEZZWNYNBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.75
• 重原子数：
  15.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  {Pd(η-allyl)Cl(PPh2Me)} 以 四氢呋喃 、 乙醚 为溶剂， 生成 、 Pd2(μ-C3H5)2(PPh2Me)2
  参考文献：
  名称：

  Hayashi, Yoshihito; Matsumoto, Keiji; Nakamura, Yukio, Journal of the Chemical Society, Dalton Transactions, 1989, p. 1519 - 1526

  摘要：

  DOI：

文献信息

• Fluoride-induced reduction of palladium(II) and platinum(II) phosphine complexes
  作者：M. R. Mason、J. G. Verkade

  DOI：10.1021/om00042a040

  日期：1992.6

  A novel redox reaction involving fluoride and phosphine complexes of palladium(II) is reported. The scope of this reaction has been investigated using the ligands PPh3, Ph2P(CH2)nPPh2 (n = 1-4), Ph2PCH2C(CH3)2CH2PPh2, Ph2PCH3, and P(CH2CH2CN)3; several solvents including DMSO, pyridine, acetonitrile, and THF; and either n-Bu4NF.3H2O or KF/18-crown-6 as the fluoride source. The reduction products are palladium(0) phosphine complexes for which this reaction offers a convenient synthetic route. P-31 and F-19 NMR spectra permitted identification of the initial oxidation products as difluorophosphoranes (R3PF2), which subsequently hydrolyzed, forming phosphine oxides if a hydrated fluoride source is used. Results implicating a fluoride-induced redox reaction in the thermal decomposition of [(Ph3P)3PdCl]BF4 to yield [Pd3Cl(PPh2)2(PPh3)3] BF4 are also presented. Preliminary results indicate that platinum complexes also undergo this reaction, but nickel complexes yield NiF2. The X-ray parameters for Pd(dppp)2 (dppp = 1,3-bis(diphenyphosphino)propane) are: monoclinic, space group C2/c (No. 15), a = 18.396 (2) angstrom, b = 13.290 (1) angstrom, c = 20.186 (2) angstrom, beta = 109.383 (5)-degrees, and Z = 4.
• Hayashi, Yoshihito; Matsumoto, Keiji; Nakamura, Yukio, Journal of the Chemical Society, Dalton Transactions, 1989, p. 1519 - 1526
  作者：Hayashi, Yoshihito、Matsumoto, Keiji、Nakamura, Yukio、Isobe, Kiyoshi

  DOI：——

  日期：——