1,3-dimethoxy-1-phenylbutane | 26278-68-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-dimethoxy-1-phenylbutane
• 英文别名: 1,3-dimethoxy-1-phenyl-butane；1,3-Dimethoxy-1-phenyl-butan；1-phenyl-1,3-dimethoxy-n-butane；(1,3-Dimethoxybutyl)benzene；1,3-dimethoxybutylbenzene
• CAS: 26278-68-2
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.274
• InChiKey: XERFTCMOZJAHKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯乙烯 、 二甲氧基乙烷 在 三氟化硼乙醚 作用下， 生成 1,3-dimethoxy-1-phenylbutane
  参考文献：
  名称：

  Addition of acetals and ketals to olefins

  摘要：

  公开号：

  US02768212A1

文献信息

• 9,10-DICYANOANTHRACENE-SENSITIZED TWO-ELECTRON OXIDATION OF PHENYLCYCLOPROPANE AND AROMATIC OLEFINS IN THE PRESENCE OF COPPER(II) ION
  作者：Kazuhiko Mizuno、Katsutoshi Yoshioka、Yoshio Otsuji

  DOI：10.1246/cl.1983.941

  日期：1983.6.5

  The photooxidation of phenylcyclopropane, styrene, and indene using 9,10-dicyanoanthracene-Cu(BF4)2 sensitizer system in acetonitrile-alcohol(3:1) solutions affords the corresponding 1,3-dialkoxy and 1,2-dialkoxy compounds.

  在乙腈-醇 (3:1) 溶液中使用 9,10-二氰基蒽-Cu(BF4)2 敏化剂体系对苯基环丙烷、苯乙烯和茚进行光氧化，得到相应的 1,3-二烷氧基和 1,2-二烷氧基化合物。
• Catalysts for the (co)polymerization of ethylene
  申请人：Montell Technology Company bv

  公开号：EP0719799A1

  公开（公告）日：1996-07-03

  The present invention relates to new catalysts for the polymerization of ethylene and its blends with CH2=CHR olefins, where R is an alkyl, cycloalkyl or aryl radical that has 1-12 carbon atoms, comprising the product of the reaction between: (a) a solid catalytic component comprising a magnesium halide in an active form and a titanium compound containing at least one Ti-halogen bond; (b) an Al-alkyl compound (c) an electron-donor compound selected from the 1,3 diethers that have a particular structural formula. These catalysts make it possible to produce (co)polymers of ethylene with narrow MWD with good polymerization yields.

  本发明涉及乙烯及其与CH2=CHR烯烃（其中R为具有1-12个碳原子的烷基、环烷基或芳基）共混物聚合的新型催化剂，包括以下两种反应的产物： (a) 固体催化组分，包括活性形式的卤化镁和含有至少一个钛卤键的钛化合物； (b) 铝烷基化合物 (c) 选自具有特定结构式的 1,3-二醚的电子供体化合物。 这些催化剂可以生产出具有较窄截留分子量的乙烯（共）聚合物，并具有良好的聚合收率。
• Organic Synthesis by Electrolysis. VI. Anodic Oxidation of Arylcyclopropanes
  作者：T. Shono、Y Matsumura

  DOI：10.1021/jo00837a604

  日期：1970.12
• PHOTOSENSITIZER AND PHOTOVOLTAIC DEVICE
  申请人：Yamanaka Noriyo

  公开号：US20110108117A1

  公开（公告）日：2011-05-12

  Disclosed is a novel photosensitizer that can absorb light in a wide visible light region and in the case of a very thin film form, can enhance a light absorption efficiency by virtue of a large light absorption coefficient. The photosensitizer is used for metal oxide semiconductor electrodes and comprises a metal complex represented by a general formula ML 1 L 2 X 2 , wherein M is a group 8 transition metal of the periodic table, Xs are each independently a halogen atom, a cyano group, a thiocyanate group, an isothiocyanate group, an isocyanate group, an isocyanide group or a hydroxyl group, or a bidentate ligand in the case where Xs are bonded to one another, L 1 and L 2 are each a ligand having an aromatic ring, and either L 1 or L 2 has a functional group having a COOH group or PO(OH) 2 , and when the photosensitizer is adsorbed on a metal oxide semiconductor electrode via ligands L 1 and L 2 , the difference ΔL between the energy levels of ligands L 1 and L 2 in their excited states, calculated in accordance with a GAUSSIAN03 quantum chemistry calculation program is 0.25 eV or more.
• US8471018B2
  申请人：——

  公开号：US8471018B2

  公开（公告）日：2013-06-25