1-cyano-anthra<1,9-bc>pyridine-2,7-dione | 175026-97-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-cyano-anthra<1,9-bc>pyridine-2,7-dione
• 英文别名: 2-hydroxy-7-oxo-7H-naphtho[1,2,3-de]quinoline-1-carbonitrile；2-Hydroxy-7-oxo-7H-naphtho[1,2,3-de]chinolin-1-carbonitril；15-hydroxy-8-oxo-14-azatetracyclo[7.7.1.02,7.013,17]heptadeca-1(16),2,4,6,9(17),10,12,14-octaene-16-carbonitrile
• CAS: 175026-97-8
• 化学式: C₁₇H₈N₂O₂
• mdl: MFCD01532308
• 分子量: 272.263
• InChiKey: MYMLJUOAANBFOS-UHFFFAOYSA-N

物化性质

• 沸点：
  555.0±50.0 °C(Predicted)
• 密度：
  1.49±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-cyano-anthra<1,9-bc>pyridine-2,7-dione 在 对甲苯磺酸甲酯 作用下， 生成 1-Cyano-N-methylanthrapyridon
  参考文献：
  名称：

  DE655651

  摘要：

  公开号：
• 作为产物：
  描述：

  2-氯-N-(9,10-二氧代-9,10-二氢-1-蒽基)乙酰胺 在 三乙胺 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 生成 1-cyano-anthra<1,9-bc>pyridine-2,7-dione
  参考文献：
  名称：

  Berghot; Moawad, Bollettino Chimico Farmaceutico, 1995, vol. 134, # 10, p. 564 - 5568

  摘要：

  DOI：

文献信息

• Colorant compounds
  申请人：Banning H. Jeffrey

  公开号：US20060036095A1

  公开（公告）日：2006-02-16

  Compounds of the formula wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 66 , m, n, p, and G are as defined herein.

  其中R1、R2、R3、R4、R5、R6、R66、m、n、p和G的化合物如下所定义。
• Diaryl ether condensation reactions
  申请人：——

  公开号：US20030088128A1

  公开（公告）日：2003-05-08

  One aspect of the present invention relates to novel reaction conditions that allow the efficient synthesis of diaryl ethers from arenes bearing a leaving group and arenols under relatively mild conditions. Another aspect of the present invention relates to the dramatic effects of acidic activators on Ullmann-type couplings involving electron-poor and/or relatively insoluble substrates.

  本发明的一个方面涉及新颖的反应条件，允许在相对温和的条件下从带有离去基团的芳烃和芳醇中高效合成二芳基醚。本发明的另一个方面涉及酸性活化剂对涉及电子贫乏和/或相对不溶性底物的乌尔曼型偶合反应的显著影响。
• Improved clarity copolyester
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP0854160A2

  公开（公告）日：1998-07-22

  An improved clarity copolyester of a diethylene glycol modified poly(ethylene terephthalate) has a b* value of less than 15, preferably less than 10. The copolyester composition has an inherent viscosity of 0.4 to 1.0 dL/g and comprises (A) 100 mol percent dicarboxylic acid residue component, (B) 100 mol percent diol residue component, (C) catalyst residues and (D) color control agent residues. The dicarboxylic acid residue component comprises at least 75 mol percent of terephthalic acid residues. The diol residue component comprises 10 to 50 mol percent diethylene glycol residue and 50 to 90 mol percent ethylene glycol residue. The catalyst residues comprise 20 to 100 ppm manganese, 50 to 300 ppm antimony, 0 to 100 ppm titanium and 40 to 150 ppm phosphorus, based on the weight of the copolyester. The color control agent residues comprise organic or inorganic toners present in a sufficient amount to reduce the b* color value of the combination of components A, B, and C to less than 15 by the addition of component D. Preferably, the color control agent residues comprises either (i) 40 to 100 ppm cobalt, (ii) 1.5 to 10 ppm of blue compounds of substituted 1,4-bis(2,6-dialylanilino) anthraquinones and 0.5 to 6 ppm of red compounds of anthraquinones and (iii) 0.5 to 10 ppm of 1-cyano-3H-dibenz[f,ij] isoquinoline-2,7-diones, all ppm based on the weight of the copolyester.

  一种二甘醇改性聚对苯二甲酸乙二醇酯的改良透明度共聚物的 b* 值小于 15，最好小于 10。该共聚聚酯组合物的固有粘度为 0.4 至 1.0 dL/g，由以下成分组成：(A) 100% mol%的二羧酸残留物成分；(B) 100% mol%的二元醇残留物成分；(C) 催化剂残留物；(D) 着色控制剂残留物。二羧酸残余物组分包括至少 75 摩尔%的对苯二甲酸残余物。二元醇残渣组分包括 10 至 50 摩尔%的二乙二醇残渣和 50 至 90 摩尔%的乙二醇残渣。催化剂残留物包括 20 至 100 ppm 的锰、50 至 300 ppm 的锑、0 至 100 ppm 的钛和 40 至 150 ppm 的磷，以共聚聚酯的重量为基准。颜色控制剂残留物包括有机或无机调色剂，其含量足以在添加组分 D 后将组分 A、B 和 C 组合的 b* 色值降至 15 以下。5至10ppm的取代1,4-双(2,6-二苯胺基)蒽醌的蓝色化合物和0.5至6ppm的蒽醌的红色化合物，以及(iii)0.5至10ppm的1-氰基-3H-二苯并[f,ij]异喹啉-2,7-二酮，所有ppm均基于共聚聚酯的重量。
• Improved clarity and adjustable shrinkage of shrink films using miscible polyester blends
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP0854175A2

  公开（公告）日：1998-07-22

  A heat-shrinkable film is provided comprising a copolyester blend of: (a) about 1 to about 98.5 percent by weight of a PETG copolyester, (b) about 98.5 to about 1 percent by weight of a DEG modified PET copolyester having a b* value of less than 15, preferably less than 10, (c) about 0.5 to about 3 percent by weight of anti-blocking agent, and optionally, (d) about 5 to about percent by weight of a crystallizable polyester. Component (a) comprises 100 mol percent dicarboxylic acid residue component of at least 95 mol percent terephthalic acid residues and 100 mol percent diol residue component of about 65 to about 80 mol percent ethylene glycol residues and about 35 to about 20 mol percent 1,4-cyclohexanedimethanol residues. Component (b) comprises 100 mol percent dicarboxylic acid residue component, 100 mol percent diol residue component, catalyst residues and color control agent residues. The dicarboxylic acid residue component comprises at least 75 mol percent of terephthalic acid residues. The diol residue component comprises 10 to 50 mol percent diethylene glycol residue and 50 to 90 mol percent ethylene glycol residue. The catalyst residues comprise 20 to 100 ppm manganese, 50 to 300 ppm antimony, 0 to 100 ppm titanium and 40 to 150 ppm phosphorus, based on the weight of the copolyester. The color control agent residues comprises either (i) 40 to 100 ppm cobalt, (ii) 1.5 to 10 ppm of blue compounds of substituted 1,4-bis(2,6-dialylanilino) anthraquinones and 0.5 to 6 ppm of red compounds of anthraquinones and (iii) 0.5 to 10 ppm of 1-cyano-3H-dibenz[f,ij] isoquinoline-2,7-diones, all ppm based on the weight of the copolyester.

  提供了一种热收缩薄膜，该薄膜由以下共聚聚酯混合物组成：(a)约 1%至约 98.5%（按重量计）的 PETG 共聚聚酯；(b)约 98.5%至约 1%（按重量计）的 DEG 改性 PET 共聚聚酯，其 b* 值小于 15，最好小于 10；(c)约 0.5%至约 3%（按重量计）的抗阻塞剂；以及可选的、(d)约 5%至约 5%（按重量计）的可结晶聚酯。组分（a）包括 100% 的二羧酸残余物组分（至少 95% 的对苯二甲酸残余物）和 100% 的二元醇残余物组分（约 65% 至约 80% 的乙二醇残余物和约 35% 至约 20% 的 1,4-环己烷二甲醇残余物）。组分（b）包括 100 摩尔%的二羧酸残留物组分、100 摩尔%的二元醇残留物组分、催化剂残留物和颜色控制剂残留物。二羧酸残渣组分包括至少 75 摩尔%的对苯二甲酸残渣。二元醇残渣组分包括 10 至 50 摩尔%的二乙二醇残渣和 50 至 90 摩尔%的乙二醇残渣。催化剂残留物包括 20 至 100 ppm 的锰、50 至 300 ppm 的锑、0 至 100 ppm 的钛和 40 至 150 ppm 的磷，以共聚聚酯的重量为基准。颜色控制剂残留物包括：(i) 40 至 100 ppm 的钴；(ii) 1.5 至 10 ppm 的取代 1,4-双(2,6-二乙酰苯胺基)蒽醌的蓝色化合物和 0.5 至 6 ppm 的蒽醌红色化合物；(iii) 0.5 至 10 ppm 的 1-氰基-3H-二苯并[f,ij]异喹啉-2,7-二酮，所有 ppm 均以共聚聚酯的重量为基准。
• Phase change inks
  申请人：Xerox Corporation

  公开号：EP1626072A1

  公开（公告）日：2006-02-15

  Phase change inks comprising a phase change ink carrier and a colorant compound of the formula or wherein R1, R2, R3, R4, R5, m, n, and p are as defined herein, R6 is a direct bond, an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R66 is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, G is a hydroxy group, a carboxylic acid group, an alkyl group having at least about 8 carbon atoms, an aryl group, an arylalkyl group having at least about 14 carbon atoms, an alkylaryl group having at least about 14 carbon atoms, a group of the formula a group of the formula a group of the formula or a group of the formula X is -O- or -NR9-, and R7, R8, and R9 are as defined herein.

  相变油墨，包括相变油墨载体和式中的着色剂化合物 或 其中 R1、R2、R3、R4、R5、m、n 和 p 如本文所定义，R6 是直接键、亚烷基、亚芳基、亚芳烷基或亚烷基芳基，R66 是亚烷基、亚芳基、亚芳烷基或亚烷基芳基、G 是羟基、羧酸基、至少具有约 8 个碳原子的烷基、芳基、至少具有约 14 个碳原子的芳烷基、至少具有约 14 个碳原子的烷芳基、式中的一个基团 式中的一个基团 式中的一个基团 或式中的一个基团 X是-O-或-NR9-，R7、R8和R9如本文所定义。