5-(5-norbonene-2,3-dicarboximide) isophthalicacid | 62385-62-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(5-norbonene-2,3-dicarboximide) isophthalicacid
• 英文别名: 5-(5-norbonene-2,3-dicarboximide)isophthalic acid；5-(1,3-dioxo-1,3,3a,4,7,7a-hexahydro-2H-4,7-methanoisoindol-2-yl)benzene-1,3-dicarboxylic acid；5-(3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl)benzene-1,3-dicarboxylic acid
• CAS: 62385-62-0
• 化学式: C₁₇H₁₃NO₆
• mdl: MFCD00385432
• 分子量: 327.293
• InChiKey: JOQBGFKVMFUNCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  112
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5-(5-norbonene-2,3-dicarboximide) isophthalicacid 、 zinc diacetate 、 水 以 N,N-二甲基甲酰胺 为溶剂， 反应 72.0h， 以65%的产率得到
  参考文献：
  名称：

  Lanthanide(Tb3+, Eu3+)-functionalized a new one dimensional Zn-MOF composite as luminescent probe for highly selectively sensing Fe3+

  摘要：

  A new one dimensional zinc metal organic framework {[Zn(NDIC)center dot 2H(2)O]center dot 2H(2)O}(n) (NDIC = 5-(5-Norbonene-2,3-dicarboximide)Isophthalic acid) has been synthesized under an hydrothermal condition and chosen as a parent framework to sensitize via encapsulating Tb3+ and Eu3+ cations in Zn-MOF. The obtained composite Tb(3+)@Zn-MOF shows excellent luminescence which performs a remarkable quenching effect in the luminescence emission of Tb(3+)upon the introduction of Fe3+. Subsequently, Tb(3+)@Zn-MOF as a highly selective and sensitive sensor for Fe3+. Most importantly, the luminescence probe of Fe - shows a low detection limit (7.5 x 10(-6) M), a broad linear range (2.5 x 10(-6) -7.5 x 10(-5) ). A paper strip coated with Tb(3+)@Zn-MOF material was also shown to be highly selective for Fe3+ and under the irradiation of UV light of 254 nm by the naked eyes. This is first example for detecting metal ions based on a lanthanide functionalized a new Zn metal-organic framework. (C) 2018 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2018.04.013
• 作为产物：
  描述：

  纳迪克酸酐 、 5-氨基间苯二甲酸 在 溶剂黄146 作用下， 反应 2.0h， 生成 5-(5-norbonene-2,3-dicarboximide) isophthalicacid
  参考文献：
  名称：

  一种新型的Tb（iii）功能化层状Cd MOF作为发光探针，用于高选择性地检测Cr 3+ †

  摘要：

  溶剂热法合成了一种新的层状金属有机骨架{[Cd 4（NDIC）4 ·5DMF·H 2 O] DMF} n（NDIC = 5-（5-降冰片烯-2,3-二苯甲酰亚胺）间苯二甲酸）方法。它被用作母体框架将Tb 3+阳离子封装在Cd-MOF中。引入Cr 3+后，所得复合材料Tb（3 +）@ Cd-MOF表现出优异的发光性能，并在Tb 3+的发光发射中产生了显着的猝灭效果。随后，开发了Tb（3 +）@ Cd-MOF作为检测Cr 3+的高选择性和灵敏探针。尤其是Cr 3+发光探针的检出限低（7.5×10-8 M），较宽的线性范围（1×10 -7 –5×10 -6 M）。还显示了用Tb（3 +）@ Cd-MOF涂覆的纸条在裸眼在254 nm紫外线的照射下对Cr 3+具有高度选择性。这是基于镧系元素官能化的新型金属-有机骨架（MOF）检测金属离子的第一个示例。

  DOI：

  10.1039/c7ce01795b

文献信息

• A new Tb(<scp>iii</scp>)-functionalized layer-like Cd MOF as luminescent probe for high-selectively sensing of Cr³⁺
  作者：Yi Wang、Huan Yang、Gang Cheng、Yunying Wu、Shaomin Lin

  DOI：10.1039/c7ce01795b

  日期：——

  developed as a highly selective and sensitive probe for detection of Cr3+. In particular, the luminescence probe of Cr3+ had a low detection limit (7.5 × 10−8 M), a broad linear range (1 × 10−7–5 × 10−6 M). A paper strip coated with Tb(3+)@Cd-MOF was also shown to be highly selective to Cr3+ under the irradiation of 254 nm UV light of by the naked eyes. This is the first example for detecting metal ions

  溶剂热法合成了一种新的层状金属有机骨架[Cd 4（NDIC）4 ·5DMF·H 2 O] DMF} n（NDIC = 5-（5-降冰片烯-2,3-二苯甲酰亚胺）间苯二甲酸）方法。它被用作母体框架将Tb 3+阳离子封装在Cd-MOF中。引入Cr 3+后，所得复合材料Tb（3 +）@ Cd-MOF表现出优异的发光性能，并在Tb 3+的发光发射中产生了显着的猝灭效果。随后，开发了Tb（3 +）@ Cd-MOF作为检测Cr 3+的高选择性和灵敏探针。尤其是Cr 3+发光探针的检出限低（7.5×10-8 M），较宽的线性范围（1×10 -7 –5×10 -6 M）。还显示了用Tb（3 +）@ Cd-MOF涂覆的纸条在裸眼在254 nm紫外线的照射下对Cr 3+具有高度选择性。这是基于镧系元素官能化的新型金属-有机骨架（MOF）检测金属离子的第一个示例。
• Fused cyclic succinimide compounds and analogs thereof, modulators of nuclear hormone receptor function
  申请人：——

  公开号：US20040087548A1

  公开（公告）日：2004-05-06

  Fused cyclic compounds, methods of using such compounds in the treatment of nuclear hormone receptor-associated conditions such as cancer and immune disorders, and pharmaceutical compositions containing such compounds.

  融合的环状化合物，使用这种化合物治疗与核激素受体相关的疾病，如癌症和免疫紊乱的方法，以及包含这种化合物的制药组合物。
• THERMOSETTING OLIGOMER OR POLYMER, THERMOSETTING RESIN COMPOSITION INCLUDING THE OLIGOMER OR POLYMER, AND PRINTED CIRCUIT BOARD USING THE COMPOSITION
  申请人：LEE Jae Jun

  公开号：US20100155120A1

  公开（公告）日：2010-06-24

  A thermosetting oligomer or thermosetting polymer is provided. The thermosetting oligomer or thermosetting polymer contains repeating units, each of which has at least one thermosetting functional group in the side chain and is represented by Formula 1: where repeating units include X 1 , A 1 , and Y 1 subunits, sidechain units include linking unit L and thermosetting functional group Z, and n is an integer from 1 to 4. The thermosetting oligomer or thermosetting polymer has a low coefficient of thermal expansion and high or no glass transition temperature, stiffness, processability, heat resistance and mechanical properties. The thermosetting oligomer or thermosetting polymer is highly soluble, wettable and dimensionally stable and is suitable for use in films, prepregs and printed circuit boards. Further provided are a thermosetting resin composition including the thermosetting oligomer or thermosetting polymer and a printed circuit board using the composition.
• US7655688B2
  申请人：——

  公开号：US7655688B2

  公开（公告）日：2010-02-02
• US8986846B2
  申请人：——

  公开号：US8986846B2

  公开（公告）日：2015-03-24