2-hydroxy-butyric acid allyl ester | 857592-91-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-hydroxy-butyric acid allyl ester
• 英文别名: 2-Hydroxy-buttersaeure-allylester；Prop-2-enyl 2-hydroxybutanoate
• CAS: 857592-91-7
• 化学式: C₇H₁₂O₃
• 分子量: 144.17
• InChiKey: DSOHDBZCBFQXSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  吡啶 、 光气 、 2-hydroxy-butyric acid allyl ester 、 苯 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Unsaturated esters and polymers thereof

  摘要：

  公开号：

  US02384120A1
• 作为产物：
  描述：

  丁炔二醇 生成 2-hydroxy-butyric acid allyl ester
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1955, vol. 596, p. 65

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING AN ALKYL 3-HYDROXYBUTYRATE
  申请人：Eastman Chemical Company

  公开号：US20150038734A1

  公开（公告）日：2015-02-05

  A method for making an alkyl 3-hydroxybutyrate is provided. The method can include reacting an alkyl alcohol with diketene to form an alkyl acetoacetate and then hydrogenating the alkyl acetoacetate to form the alkyl 3-hydroxybutyrate. The method of the present invention may also include separating one or more impurities an alkyl acetoacetate stream and subjecting the purified acetoacetate mixture to hydrogenation to form the alkyl 3-hydroxybutyrate. Methods of the present invention can be carried out on a lab, pilot, or commercial scale.

  提供了一种制备烷基3-羟基丁酸酯的方法。该方法可以包括将烷基醇与二羰基乙烯反应以形成烷基乙酰乙酸酯，然后加氢烷基乙酰乙酸酯以形成烷基3-羟基丁酸酯。本发明的方法还可以包括从烷基乙酰乙酸酯流中分离一种或多种杂质，并将纯化后的乙酰乙酸酯混合物进行加氢以形成烷基3-羟基丁酸酯。本发明的方法可以在实验室、中试或商业规模上进行。
• Thermosetting powdery coating composition
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0301557A1

  公开（公告）日：1989-02-01

  The thermosetting powdery coating composition of the invention comprises (A) from 40 to 98 parts by weight of a fluorinecontaining copolymer, which is a copolymer of a fluoroolefin and a comonomer having a crosslinkable reactive group, e.g., hydroxy, carboxyl, amino and glycidyl groups, containing at least 10% by weight of fluorine and having an intrinsic viscosity of 0.05-2 dl/g (30 °C, tetrahydrofuran) and a glass transition temperature of 30-120 °C and (B) from 60 to 2 parts by weight of a curing agent capable of forming crosslinks by reacting with the crosslinkable reactive groups in (A). The powdery coating composition of the invention is excellent in the dispersibility of pigments and efficiency in the coating works therewith and capable of giving a coating film having improved adhesion to the substrate surface, surface luster, impact resistance and insusceptibility to stain.

  本发明的热固性粉状涂料组合物包括 (A) 40 至 98 份（按重量计）的含氟共聚物，它是氟烯烃和具有可交联反应基团（如羟基、羧基、氨基和缩水甘油基）的共聚物，含氟量至少为 10%（按重量计），固有粘度为 0.05-2 dl/g（30℃，四氢呋喃）、(B) 60 至 2 份（按重量计）能与（A）中的可交联反应基团反应形成交联的固化剂。本发明的粉末涂料组合物在颜料的分散性和涂布效率方面都非常出色，能使涂膜与基材表面的附着力、表面光泽、抗冲击性和抗污性得到改善。
• Alpha-hydroxyketone derivatives, liquid crystal compositions containing said derivatives, and liquid crystal devices using said compositions
  申请人：Chisso Corporation

  公开号：EP0409234A2

  公开（公告）日：1991-01-23

  α-hydroxyketone derivatives represented by the general formula (I) which are novel optically active compounds; liquid crystal compositions, such as chiral smectic or chiral nematic compositions, containing the derivatives; and liquid crystal devices using the compositions. General Formula (I) wherein A and B are independently a radical represented by the general formula (II): wherein R2 is an aliphatic hydrocarbon having 1 to 16 carbon atoms, which may contain -0- and may be substituted by a cyano group and/or a halogen atom, are independently a single bond, etc., X and Y are independently a single bond, or -CH2CH2-, etc., or an aliphatic hydrocarbon having 1 to 16 carbon atoms; R1 is an alkyl group, a phenyl group, or a cyclohexyl group; n is 0 or 1; and the asterisk (*) indicates an asymmetric carbon atom.

  由通式（I）代表的α-羟基酮衍生物，是新型光学活性化合物；含有该衍生物的液晶组合物，如手性硅胶组合物或手性向列型组合物；以及使用该组合物的液晶器件。通式 (I) 其中 A 和 B 独立地为通式 (II) 所代表的基团： 其中 R2 是具有 1 至 16 个碳原子的脂肪族烃，可含有 -0- 并可被氰基和/或卤素原子取代、 独立地为单键、 等，X 和 Y 独立地为单键或-CH2CH2-等，或为具有 1 至 16 个碳原子的脂肪烃；R1 为烷基、苯基或环己基；n 为 0 或 1；星号（*）表示不对称碳原子。
• CURABLE URETHANE COMPOSITION, CURED PRODUCT THEREOF, KIT AND CURRED PRODUCT PRODUCTION METHOD
  申请人：Mie University

  公开号：EP2636692A1

  公开（公告）日：2013-09-11

  [Problem] To provide a curable urethane composition of superior safety and environmental tolerance while also increasing the curing rate thereof. [Solution] Present inventions relate a curable urethane composition, a cured product and a kit thereof, which contain (A) an isocyanate group-containing compound, (B) a polyol, and as curing catalysts, (C) a titanium alkoxide and (D) an alpha-hydroxycarboxylic acid ester or beta-hydroxycarboxylic acid ester.

  问题 提供一种安全性和环境耐受性优异的可固化聚氨酯组合物，同时提高其固化率。 [解决方案］ 本发明涉及一种可固化聚氨酯组合物、固化产品及其成套工具，其中包含 (A) 含异氰酸酯基化合物、(B) 多元醇和固化催化剂、(C) 钛烷氧基化合物和 (D) α-羟基羧酸酯或β-羟基羧酸酯。
• FLUORINE-CONTAINING POLYMER FOR METAL-CLAD LAMINATED SHEET, COMPOSITION FOR METAL-CLAD LAMINATED SHEET, CURABLE COMPOSITION, METAL-CLAD LAMINATED SHEET AND PRINTED SUBSTRATE
  申请人：Daikin Industries, Ltd.

  公开号：EP3998297A1

  公开（公告）日：2022-05-18

  The disclosure provides a fluorine-containing polymer for a metal-clad laminated sheet excellent in compatibility with epoxy resins. Provided is a fluorine-containing polymer for a metal-clad laminated sheet, containing: a polymerized unit based on a fluorine-containing vinyl monomer; and a polymerized unit based on a vinyl ester monomer other than the fluorine-containing vinyl monomer, the fluorine-containing polymer comprising not more than 1 mol% in total of a polymerized unit based on a monomer containing a hydroxy group and a polymerized unit based on a monomer containing a carboxy group, of all polymerized units.

  本公开提供了一种用于金属覆层板的含氟聚合物，与环氧树脂的相容性极佳。本发明提供了一种用于金属包覆层压板的含氟聚合物，它包含：基于含氟乙烯基单体的聚合单元；以及基于除含氟乙烯基单体之外的乙烯基酯单体的聚合单元，该含氟聚合物包含的基于含羟基单体的聚合单元和基于含羧基单体的聚合单元的总和不超过所有聚合单元的 1 摩尔%。