4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine | 10198-78-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine
• 英文别名: 4,6-dichloro-5-phenyl-2-pyridin-2-yl-pyrimidine；Pyrimidine, 4,6-dichloro-5-phenyl-2-(2-pyridinyl)-；4,6-dichloro-5-phenyl-2-pyridin-2-ylpyrimidine
• CAS: 10198-78-4
• 化学式: C₁₅H₉Cl₂N₃
• 分子量: 302.163
• InChiKey: ARQMRNKGOQCCDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 trans-bis((diphenylthio)ethane)dichlororuthenium(II) 、 4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine 以 not given 为溶剂， 以89%的产率得到[Ru(II)((diphenylthio)ethane)(4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine)](PF6)2
  参考文献：
  名称：

  摘要：

  The complexation reaction of trans-[RuCl2(Dpte)(2)] (Dpte - (diphenylthio)ethane) with mixed diimine ligands 2,2'-bipyridine, pyridylquinoline, 4,6-dichloro-2-(2-pyridyl)pyrimidine, 4,6-dichloro-5-methyl-2-(2-pyridyl)pyrimidine, and 4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine produces new Ru(II) mixed-ligand complexes. These complexes exhibit maximum photo- and chemical stability and high absorptivity. The above complexes have been characterized using IR, H-1 and C-13 NMR, electronic absorption spectroscopy, and elemental analysis.

  DOI：

  10.1023/a:1021158931775

文献信息

• Synthesis, physical and photophysical properties of Ru(II) pyridyl-pyrimidine and pyridyl-pyrimidinone complexes: effect of substituents on the pyrimidine ring
  作者：Wen-Mei Xue、W.J. Perez、D.Paul Rillema

  DOI：10.1016/s0020-1693(99)00321-7

  日期：1999.12
• ——
  作者：K. Q. Shawakfeh、N. A. F. Al-Rawashdeh、S. Khader

  DOI：10.1023/a:1021158931775

  日期：——

  The complexation reaction of trans-[RuCl2(Dpte)(2)] (Dpte - (diphenylthio)ethane) with mixed diimine ligands 2,2'-bipyridine, pyridylquinoline, 4,6-dichloro-2-(2-pyridyl)pyrimidine, 4,6-dichloro-5-methyl-2-(2-pyridyl)pyrimidine, and 4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine produces new Ru(II) mixed-ligand complexes. These complexes exhibit maximum photo- and chemical stability and high absorptivity. The above complexes have been characterized using IR, H-1 and C-13 NMR, electronic absorption spectroscopy, and elemental analysis.