4-(Anthracen-9-ylmethyl)-1,7,13-trioxa-4,10,16-triazacyclooctadecane | 496053-44-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4-(Anthracen-9-ylmethyl)-1,7,13-trioxa-4,10,16-triazacyclooctadecane
• CAS: 496053-44-2
• 化学式: C₂₇H₃₇N₃O₃
• 分子量: 451.609
• InChiKey: CJEVEIWHASRGAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  33
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  55
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-(Anthracen-9-ylmethyl)-1,7,13-trioxa-4,10,16-triazacyclooctadecane 在 caesium carbonate 、 三氟乙酸 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Fluororeceptor for zwitterionic form amino acids in aqueous methanol solution

  摘要：

  A fluorescent receptor for underivatized amino acids was developed. The receptor based on triaza-18-crown-6 ether combined with two guanidinium groups could bind several biologically important amino acids in aqueous methanol solution and showed fluorescence enhancement response by a PET (photoinduced electron transfer) mechanism. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01618-0
• 作为产物：
  描述：

  4,10,16-Tris-(toluene-4-sulfonyl)-1,7,13-trioxa-4,10,16-triaza-cyclooctadecane 在 lithium aluminium tetrahydride 、 caesium carbonate 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 生成 4-(Anthracen-9-ylmethyl)-1,7,13-trioxa-4,10,16-triazacyclooctadecane
  参考文献：
  名称：

  Fluororeceptor for zwitterionic form amino acids in aqueous methanol solution

  摘要：

  A fluorescent receptor for underivatized amino acids was developed. The receptor based on triaza-18-crown-6 ether combined with two guanidinium groups could bind several biologically important amino acids in aqueous methanol solution and showed fluorescence enhancement response by a PET (photoinduced electron transfer) mechanism. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01618-0

文献信息

• Fluororeceptor for zwitterionic form amino acids in aqueous methanol solution
  作者：Shin-ichi Sasaki、Akio Hashizume、Daniel Citterio、Eiji Fujii、Koji Suzuki

  DOI：10.1016/s0040-4039(02)01618-0

  日期：2002.9

  A fluorescent receptor for underivatized amino acids was developed. The receptor based on triaza-18-crown-6 ether combined with two guanidinium groups could bind several biologically important amino acids in aqueous methanol solution and showed fluorescence enhancement response by a PET (photoinduced electron transfer) mechanism. (C) 2002 Elsevier Science Ltd. All rights reserved.