tris(o-dimethylarsinophenyl)arsine | 60593-36-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(o-dimethylarsinophenyl)arsine
• 英文别名: Tris-(o-dimethylarsinophenyl)-arsin；Tris(2-dimethylarsanylphenyl)arsane
• CAS: 60593-36-4
• 化学式: C₂₄H₃₀As₄
• 分子量: 618.189
• InChiKey: YNUVLYYSRFTREL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.09
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tris(o-dimethylarsinophenyl)arsine 以 乙醇 为溶剂， 生成 [Rh(tris(o-dimethylarsinophenyl)arsine)Br2]Br
  参考文献：
  名称：

  Rhodium(III) and iridium(III) complexes of the tetraarsine tris(o-dimethylarsinophenyl)arsine. Crystal structure of [Ir{(o-Me2AsC6H4)3As}(CO)Cl][BF4]2

  摘要：

  The syntheses of the cis octahedral complexes [Rh(tetas)X(2)]BF4 (tetas=As(o-C(6)H(4)AsMe(2))(3); X=Cl, Br or I) and [Ir(tetas)X(2)]X are described. Fac-[Rh{MeC(CH(2)AsMe(2))3}X(3)] and [Ir{MeC(CH(2)AsMe(2))(3)}Cl-3] were also obtained. The complexes were characterised by analysis, UV-Vis and multinuclear NMR (H-1 and Rh-103) spectroscopies. Cyclic voltammetry revealed irreversible reductions to Rh(I) or Ir(I). The reaction of trans-[Ir(CO)(PPh(3))(2)Cl] with tetas, followed by chlorine oxidation gave the Ir(III) carbonyl [Ir(tetas)(CO)Cl][BF4](2) which was characterised by a single crystal X-ray study (Ir-As=2.392( 1)-2.464(1), Ir-Cl=2.425(2), Ir-C(O)=1.934(8) Angstrom).

  DOI：

  10.1016/s0020-1693(96)05148-1

文献信息

• A comparison of cis- and trans-cobalt(III) complexes with phosphorus and arsenic ligands; the effect of stereochemistry on redox and spectroscopic properties
  作者：William Levason、Stephen R. Preece、Christopher S. Frampton

  DOI：10.1016/0277-5387(95)00558-7

  日期：1996.8

  The spectroscopic (UV-vis, 1H, 31P and 59Co NMR) properties of cis- and trans- [Co(LL)2X2]Y [LL = o-C6H4(PMe2)2 or o-C6H4(AsMe2) 2; X = Cl or Br, Y = X pr BF4] and (cis) [Coo-C6H4AsMe2)3}X2]X (X = Cl, Br or I) are compared. Cyclic voltammetry has been used to probe the redox chemistries as a function of metal geometry. The structure of [CoAs(o-C4H4AsMe2)3}Br2]BF4 has been determined [CoAs = 2

  分光（UV-VIS，1个H，31 P和59共同NMR）的性质顺-和反式- [CO（LL）2 X 2 ] Y [LL= ø -C 6 ħ 4（PME 2）2或o -C 6 H 4（AsMe 2）2；X = Cl或Br，Y = X pr BF 4 ]和（顺式）[Co o -C 6 H 4 AsMe 2）3 } X 2比较] X（​​X = Cl，Br或I）。循环伏安法已被用来探测作为金属几何函数的氧化还原化学。已确定[Co As（o -C 4 H 4 AsMe 2）3 } Br 2 ] BF 4的结构[CoAs= 2.242（2）−2.363（2），CoBr= 2.394（2） ，2.435（2）Å]。
• Cationic rhodium(I) complexes. 5. Preparation and reactions of complexes containing tris(o-dimethylarsinophenyl)arsine and 1,1'-bis(dimethylarsino)ferrocene
  作者：Joel T. Mague、Michael O. Nutt

  DOI：10.1021/ic50172a001

  日期：1977.6.1
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Rh: SVol.B3, 5.2.3.2, page 226 - 226
  作者：

  DOI：——

  日期：——
• Rhodium(III) and iridium(III) complexes of the tetraarsine tris(o-dimethylarsinophenyl)arsine. Crystal structure of [Ir{(o-Me2AsC6H4)3As}(CO)Cl][BF4]2
  作者：Angela M. Hill、William Levason、Stephen R. Preece、Christopher S. Frampton

  DOI：10.1016/s0020-1693(96)05148-1

  日期：1997.1

  The syntheses of the cis octahedral complexes [Rh(tetas)X(2)]BF4 (tetas=As(o-C(6)H(4)AsMe(2))(3); X=Cl, Br or I) and [Ir(tetas)X(2)]X are described. Fac-[RhMeC(CH(2)AsMe(2))3}X(3)] and [IrMeC(CH(2)AsMe(2))(3)}Cl-3] were also obtained. The complexes were characterised by analysis, UV-Vis and multinuclear NMR (H-1 and Rh-103) spectroscopies. Cyclic voltammetry revealed irreversible reductions to Rh(I) or Ir(I). The reaction of trans-[Ir(CO)(PPh(3))(2)Cl] with tetas, followed by chlorine oxidation gave the Ir(III) carbonyl [Ir(tetas)(CO)Cl][BF4](2) which was characterised by a single crystal X-ray study (Ir-As=2.392( 1)-2.464(1), Ir-Cl=2.425(2), Ir-C(O)=1.934(8) Angstrom).