[Rh(tris(o-dimethylarsinophenyl)arsine)Br2]Br | 186082-83-7

• 英文名称: [Rh(tris(o-dimethylarsinophenyl)arsine)Br2]Br
• CAS: 186082-83-7
• 化学式: Br*C₂₄H₃₀As₄Br₂Rh
• 分子量: 960.806
• InChiKey: FTDORHNUIAPXNK-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(o-dimethylarsinophenyl)arsine 以 乙醇 为溶剂， 生成 [Rh(tris(o-dimethylarsinophenyl)arsine)Br2]Br
  参考文献：
  名称：

  Rhodium(III) and iridium(III) complexes of the tetraarsine tris(o-dimethylarsinophenyl)arsine. Crystal structure of [Ir{(o-Me2AsC6H4)3As}(CO)Cl][BF4]2

  摘要：

  The syntheses of the cis octahedral complexes [Rh(tetas)X(2)]BF4 (tetas=As(o-C(6)H(4)AsMe(2))(3); X=Cl, Br or I) and [Ir(tetas)X(2)]X are described. Fac-[Rh{MeC(CH(2)AsMe(2))3}X(3)] and [Ir{MeC(CH(2)AsMe(2))(3)}Cl-3] were also obtained. The complexes were characterised by analysis, UV-Vis and multinuclear NMR (H-1 and Rh-103) spectroscopies. Cyclic voltammetry revealed irreversible reductions to Rh(I) or Ir(I). The reaction of trans-[Ir(CO)(PPh(3))(2)Cl] with tetas, followed by chlorine oxidation gave the Ir(III) carbonyl [Ir(tetas)(CO)Cl][BF4](2) which was characterised by a single crystal X-ray study (Ir-As=2.392( 1)-2.464(1), Ir-Cl=2.425(2), Ir-C(O)=1.934(8) Angstrom).

  DOI：

  10.1016/s0020-1693(96)05148-1