1,3-bis[(3-ethyloxetane-3-yl)methoxy]benzene | 111090-66-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,3-bis[(3-ethyloxetane-3-yl)methoxy]benzene
• 英文别名: 1,3-bis(3-ethyl-3-oxetanylmethyloxy)benzene；1,3-bis[(3-ethyl-3-oxetanyl)methoxy]benzene；1,3-bis[(3-ethyloxetan-3-yl)methoxy]benzene；1,3-bis[(3-ethyloxetan-3-yl)methoxy]benzen；Oxetane, 3,3'-[1,3-phenylenebis(oxymethylene)]bis[3-ethyl-；3-ethyl-3-[[3-[(3-ethyloxetan-3-yl)methoxy]phenoxy]methyl]oxetane
• CAS: 111090-66-5
• 化学式: C₁₈H₂₆O₄
• 分子量: 306.402
• InChiKey: FHFOJGCIXOUQMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD OF PRODUCING EPOXY COMPOUND, AND REACTIVE DILUENT
  申请人：JXTG NIPPON OIL & ENERGY CORPORATION

  公开号：US20190071409A1

  公开（公告）日：2019-03-07

  The present invention discloses a monoepoxy compound represented by the following Formula (1), a curable composition containing the same, a cured product therefrom, a method of producing the monoepoxy compound, and a reactive diluent containing the monoepoxy compound. The monoepoxy compound represented by the Formula (1) is useful in that it is capable of reducing the viscosity of a curable composition containing the monoepoxy compound, while preventing a reduction in the heat resistance of the curable composition as well as a reduction in the weight of the curable composition upon curing. (In the Formula (1), R 1 to R 6 are each independently selected from the group consisting of a hydrogen atom, an alkyl group, and an alkoxy group.)

  本发明揭示了一种由以下式（1）表示的单环氧化合物，包含该化合物的可固化组合物，由此固化产物，制备单环氧化合物的方法以及含有单环氧化合物的反应性稀释剂。式（1）表示的单环氧化合物有用之处在于，它能够减少含有单环氧化合物的可固化组合物的粘度，同时防止可固化组合物的耐热性和固化后的重量降低。（在式（1）中，R1至R6各自独立地选自氢原子、烷基和烷氧基组成的群）
• EPOXY COMPOUND, CURABLE COMPOSITION CONTAINING THE SAME, AND CURED PRODUCT OBTAINED BY CURING CURABLE COMPOSITION
  申请人：JXTG NIPPON OIL & ENERGY CORPORATION

  公开号：US20190161494A1

  公开（公告）日：2019-05-30

  The present invention discloses a composition comprising at least one or more stereoisomers of a compound represented by the following Formula (1), wherein, in a gas chromatogram obtained by analyzing the composition by gas chromatography, the ratio of the area of the maximum peak with respect to the total area of peaks derived from the stereoisomers is 60% or more; and wherein the maximum peak is present within the range of retention time of from 27.6 to 28.0 minutes. The present invention also discloses: a curable composition comprising the above described composition, and one selected from the group consisting of a thermal cationic polymerization initiator, an acid anhydride-based curing agent and a curing accelerator, and a photo-cationic polymerization initiator; as well as a cured product therefrom. The above described curable composition is useful in that it allows for the production of a cured product having a high heat resistance. (In the Formula (1), R 1 to R 18 are each independently selected from the group consisting of a hydrogen atom, an alkyl group and an alkoxy group.)

  本发明公开了一种组合物，包括由以下式（1）表示的化合物的至少一种立体异构体，其中，在通过气相色谱分析组合物获得的气相色谱图中，立体异构体所得峰的总面积比之下最大峰的面积比为60％或更高；而且最大峰存在于保留时间范围为27.6至28.0分钟之间。本发明还公开了：包括上述组合物和选自热固性阳离子聚合引发剂、酸酐基固化剂和固化促进剂以及光引发的阳离子聚合引发剂的固化组合物；以及由此固化产生的固化产品。上述固化组合物的用处在于它允许生产具有高耐热性的固化产品。（在式（1）中，R1到R18各自独立地选自氢原子、烷基和烷氧基的群体。）
• CATIONICALLY PHOTOPOLYMERIZABLE RESIN COMPOSITION AND OPTICAL DISK SURFACE PROTECTION MATERIAL
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1630189A1

  公开（公告）日：2006-03-01

  The invention provides a cation polymerizable resin composition excellent in curing properties and corrosion resistance with less resin coloration and less cure shrinkage, which is a material suitable as a surface protective material for optical disk. Specifically, the cation polymerizable resin composition comprises an epoxy compound (A) as an essential ingredient represented by formula 1 wherein R1 and R2 each represent a saturated or unsaturated carbon atom, and R3 represents a hydrogen atom or a saturated or unsaturated carbon atom, a cation polymerizable compound (B) other than the epoxy compound represented by formula 1, a photo cation polymerization initiator (C) and a photo radical polymerization initiator (D).

  本发明提供了一种固化性能和耐腐蚀性能优异、树脂着色少、固化收缩小的阳离子可聚合树脂组合物，它是一种适用于光盘表面保护材料的材料。具体地说，阳离子可聚合树脂组合物包括作为基本成分的环氧化合物（A）（由式 1 表示，其中 R1 和 R2 分别代表饱和或不饱和碳原子，R3 代表氢原子或饱和或不饱和碳原子）、除式 1 所示环氧化合物以外的阳离子可聚合化合物（B）、光阳离子聚合引发剂（C）和光自由基聚合引发剂（D）。
• CATIONICALLY POLYMERIZABLE RESIN COMPOSITION
  申请人：MITSUI TAKEDA CHEMICALS, INC.

  公开号：EP1705202A1

  公开（公告）日：2006-09-27

  It has been discovered that an initiation reaction is efficiently progressed to a propagation reaction by adding a compound that potentially or directly generates a carbocation to the polymerization system of a cationic ring-opening polymerizable compound, and thus the activation of polymerization is rendered. Namely, the present invention relates to a cationic polymerizable resin composition which is characterized by comprising (A) a compound having at least one functional group capable of cationic ring-opening polymerization in one molecular chain, (B) a cationic polymerization initiator, and (C) a compound to generate a carbocation by the action of active species generated from (B) the cationic polymerization initiator by electromagnetic wave or particle beam. According to the present invention, it has been discovered that the initiation reaction is efficiently progressed to the propagation reaction by adding the compound that potentially or directly generates a carbocation to the polymerization system of the cationic ring-opening polymerizable compound, and thus the activation of polymerization is rendered.

  现已发现，通过向阳离子开环聚合化合物的聚合体系中添加一种可能或直接生成碳位的化合物，可有效地将引发反应推进到扩散反应，从而实现聚合活化。也就是说，本发明涉及一种阳离子可聚合树脂组合物，其特征在于该组合物包括：(A) 在一个分子链中具有至少一个能够进行阳离子开环聚合的官能团的化合物；(B) 阳离子聚合引发剂；(C) 通过电磁波或粒子束从(B)阳离子聚合引发剂中产生的活性物质的作用而产生碳位的化合物。根据本发明，发现通过向阳离子开环可聚合化合物的聚合体系中添加可能或直接生成碳位的化合物，可有效地将引发反应推进到传播反应，从而实现聚合活化。
• COATING SOLUTION FOR ANTI-FOGGING TREATMENT AND FOG-RESISTANT PRODUCT
  申请人：SDC Technologies-Asia Ltd.

  公开号：EP1862514A1

  公开（公告）日：2007-12-05

  An anti-fogging coating solution comprising a homopolymer of a repeating unit derived from an ethylenic monomer having a hydroxyl group in the side chain or a copolymer of the above repeating unit and a repeating unit derived from an ethylenic monomer having an epoxy group, alkoxycarbonyl group, carboxyl group, amido group or amino group in the side chain as a resin component. A film formed from the coating solution of the present invention has excellent scratch resistance, initial anti-fogging property and anti-fogging retainability.

  一种防雾涂层溶液，其树脂成分包括由乙烯基单体衍生的重复单元的均聚物，该重复单元的侧链中含有羟基，或上述重复单元与由乙烯基单体衍生的重复单元的共聚物，该重复单元的侧链中含有环氧基、烷氧基羰基、羧基、氨基或氨基。由本发明的涂层溶液形成的薄膜具有优异的抗划伤性、初始防雾性和防雾保持性。