Allyl-furfuryl-<4-methoxy-phenyl>-amin | 17960-71-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Allyl-furfuryl-<4-methoxy-phenyl>-amin
• 英文别名: N-Allyl-N-(2-furfuryl)-p-anisidin；N-allyl-N-furfuryl-4-methoxy-aniline；N-(furan-2-ylmethyl)-4-methoxy-N-prop-2-enylaniline
• CAS: 17960-71-3
• 化学式: C₁₅H₁₇NO₂
• 分子量: 243.305
• InChiKey: GOFKBRGFGBSLPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  25.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-(呋喃-2-甲基)-4-甲氧基苯胺 、 3-溴丙烯 在 In(OSO₂CF₃)3 作用下， 反应 0.15h， 以90%的产率得到(1S,5S,7S)-3-(4-Methoxy-phenyl)-10-oxa-3-aza-tricyclo[5.2.1.0^1,5]dec-8-ene
  参考文献：
  名称：

  Indium trifluoromethanesulfonate (In(OTf)3). A novel reusable catalyst for intramolecular Diels–Alder reactions

  摘要：

  Indium trifluoromethanesulfonate (In(OTf)(3)) is found to be an effective catalyst for intramolecular Diels-Alder reactions of furans. This novel catalyst, soluble in both aqueous and organic media, is easily recovered from the aqueous layer after the reaction is completed. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)01513-6

文献信息

• Indium trifluoromethanesulfonate (In(OTf)3). A novel reusable catalyst for intramolecular Diels–Alder reactions
  作者：Dipak Prajapati、Dhrubojyoti D Laskar、Jagir S Sandhu

  DOI：10.1016/s0040-4039(00)01513-6

  日期：2000.10

  Indium trifluoromethanesulfonate (In(OTf)(3)) is found to be an effective catalyst for intramolecular Diels-Alder reactions of furans. This novel catalyst, soluble in both aqueous and organic media, is easily recovered from the aqueous layer after the reaction is completed. (C) 2000 Elsevier Science Ltd. All rights reserved.