butyl 2-methyl-4,4,4-trichlorobut-2-enoate | 97993-74-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: butyl 2-methyl-4,4,4-trichlorobut-2-enoate
• 英文别名: butyl (E)-4,4,4-trichloro-2-methylbut-2-enoate
• CAS: 97993-74-3
• 化学式: C₉H₁₃Cl₃O₂
• 分子量: 259.56
• InChiKey: YKQFRTQUUWZPEP-VOTSOKGWSA-N

物化性质

• 沸点：
  288.1±40.0 °C(Predicted)
• 密度：
  1.246±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Process for preparing poly alpha olefins
  申请人：UNIROYAL CHEMICAL COMPANY, Inc.

  公开号：EP0134079A2

  公开（公告）日：1985-03-13

  A compound having the formula YmXnCC(R1)=C(R2)R3 where Y is hydrogen, cyano or C2-C19 carbalkoxy; X is chlorine or bromine; R1 is hydrogen, chlorine, bromine or -COOR4; wherein R4 is C1-C18 alkyl, C3-C18 alkanyl, C5-C6 cycloalkyl, C7-C9 aralkyl or C1-C18 linear or branched alkyl, provided that R1 ist not chlorine or bromine if R2 is chlorine or bromine and if R1 and R2 are hydrogen they must be in the trans configuration; or R1 and R2 together is C3-C10 alkylene; R3 is an electron withdrawing group; n is 1, 2 or 3 and m is 3-n and the making said compound is disclosed. An intermediate compound, useful in the manufacture of the above compound, having the formula YmXnCCHR1-CR2R3X1 where Y, X, R', R2, R3, n and m have the meanings given for the compound of this invention and where X' is chlorine or bromine with the limitation that when n ist 3, R1 is hydrogen, X and X' are chlorine, if R2 is methyl then R3 is not methoxycarbonyl and if R2 is hydrogen then R3 is not methylcarbonyl, and a process for making said intermediate is described. A composition incorporating the compound, YmXnCC(R1)=C(R2)R3, with a vanadium catalyst, useful as a catalytic agent, i also disclosed. A process for preparing poly(alpha-olefins) employing a compound of the above formula as a catalyst without any of the restrictions relating to the meaning of R1 and R2 is also taught.

  具有式 YmXnCC(R1)=C(R2)R3 的化合物 其中 Y 是氢、氰基或 C2-C19 碳烷氧基；X 是氯或溴；R1 是氢、氯、溴或-COOR4；其中 R4 是 C1-C18 烷基、C3-C18 烷炔基、C5-C6 环烷基、C7-C9 芳烷基或 C1-C18 直链或支链烷基，条件是 R1 不是氯或溴，如果 R2 是氯或溴，如果 R1 和 R2 是氢，它们必须是反式构型；或者 R1 和 R2 一起是 C3-C10 亚烷基；R3 是取电子基团；n 是 1、2 或 3，m 是 3-n，并公开了上述化合物的制造方法。 描述了一种用于制造上述化合物的中间体化合物，其式为 YmXnCCHR1-CR2R3X1，其中 Y、X、R'、R2、R3、n 和 m 具有本发明化合物的含义，X'为氯或溴，限制条件是当 nt 为 3 时，R1 为氢，X 和 X'为氯，如果 R2 为甲基，则 R3 不是甲氧基羰基，如果 R2 为氢，则 R3 不是甲基羰基，并描述了制造上述中间体的工艺。 还公开了一种将化合物 YmXnCC(R1)=C(R2)R3 与钒催化剂结合在一起的组合物，可用作催化剂。 此外，还介绍了一种制备聚（α-烯烃）的工艺，该工艺采用上式化合物作为催化剂，而不受有关 R1 和 R2 意义的任何限制。
• Process for producing copolymer
  申请人：Kawashima Jun

  公开号：US20050014914A1

  公开（公告）日：2005-01-20

  There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those monomers in a polymerization reactor by feeding the following components (A), (B), (C1) and (D) to the polymerization reactor: (A) a transition metal complex, (B) an organic aluminum compound, (C1) a halogen-containing compound, and (D) a Lewis base, wherein those components are fed to the polymerization reactor without a preliminary contact of (1) the component (A) with the component (B), (2) the component (A) with the component (C1), (3) the component (B) with the component (C1), and (4) the component (B) with the component (D); and (II) a process for producing said copolymer, which comprises the step of copolymerizing those monomers in a polymerization reactor (i) by feeding to the polymerization reactor the components (A), (B), (D), (C2) a halogen-containing compound, which is a derivative of an aryl group-containing carboxylic acid, and (C3) a halogen-containing compound, which is not a derivative of a carboxylic acid, or (ii) by feeding thereto the components (A), (B), (D), (C3), and (C4) a halogen-containing compound, which is a derivative of a carboxylic acid containing an unsaturated bond-carrying linear organic group.

  提供了(I)一种生产乙烯、具有 3 至 20 个碳原子的α-烯烃和任选的一种聚烯的共聚物的工艺，该工艺包括在聚合反应器中通过向聚合反应器加入下列组分(A)、(B)、(C1)和(D)使这些单体共聚的步骤：(A)过渡金属络合物，(B)有机铝化合物，(C1)含卤素化合物，和(D)路易斯碱，其中这些组分在送入聚合反应器时不需要(1)组分(A)与组分(B)，(2)组分(A)与组分(C1)，(3)组分(B)与组分(C1)，和(4)组分(B)与组分(D)的初步接触；和(II) 生产所述共聚物的工艺，该工艺包括在聚合反应器(i)中通过向聚合反应器加入组分(A)、(B)、(D)、(C2)含卤素化合物（含芳基羧酸的衍生物）来共聚这些单体的步骤、和 (C3) 含卤化合物，它不是羧酸的衍生物，或 (ii) 向反应器中加入组分 (A)、(B)、(D)、(C3) 和 (C4) 含卤化合物，它是含有不饱和键载线性有机基团的羧酸的衍生物。
• POLYMERIZATION CATALYST PROMOTER
  申请人：UNIROYAL CHEMICAL COMPANY, Inc.

  公开号：EP0901457A1

  公开（公告）日：1999-03-17
• PROCESS FOR THE PREPARATION AND USES OF DERIVATIVES OF ESTERS OF ALPHA-METHYLENE- BETA-HYDROXY ACIDS
  申请人：Uniroyal Chemical Company, Inc.

  公开号：EP1124786A1

  公开（公告）日：2001-08-22
• SPONGE POLYMER WITH CONTROLLED LONG CHAIN BRANCHING AND BROAD MOLECULAR WEIGHT DISTRIBUTION
  申请人：Lion Copolymer Geismar, LLC

  公开号：EP2906605B1

  公开（公告）日：2018-03-28