Triiodogallane;tris(4-methoxyphenyl)arsane | 182921-13-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Triiodogallane;tris(4-methoxyphenyl)arsane
• CAS: 182921-13-7
• 化学式: C₂₁H₂₁AsGaI₃O₃
• 分子量: 846.754
• InChiKey: TZNCELSDXVLWJW-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  氢化镓 、 Diiodo-tris(4-methoxyphenyl)-lambda5-arsane 以 乙醚 为溶剂， 以70%的产率得到Triiodogallane;tris(4-methoxyphenyl)arsane
  参考文献：
  名称：

  The reaction of gallium metal with (p-MeOC₆H₄)₃AsI₂and Et₃AsI₂; isolation of a novel gallium(II) arsine complex with a gallium–gallium bond and the X-ray crystal structures of GaI₃[(p-MeOC₆H₄)₃As] and Ga₂I₄(AsEt₃)₂

  摘要：

  The reactions of (p-MeOC(6)H(4))(3)AsI2 and Et(3)AsI(2) with gallium metal powder produce the metal complexes GaI3[(p-MeOC(6)H(4))(3)As] and Ga2I4(AsEt(3))(2), respectively; the latter represents a unique example of a gallium-tertiary arsine complex containing a gallium-gallium bond, and both structures illustrate the subtle effect of the organic substituent on the arsenic atoms.

  DOI：

  10.1039/cc9960002179

文献信息

• The reaction of gallium metal with (p-MeOC₆H₄)₃AsI₂and Et₃AsI₂; isolation of a novel gallium(<scp>II</scp>) arsine complex with a gallium–gallium bond and the X-ray crystal structures of GaI₃[(p-MeOC₆H₄)₃As] and Ga₂I₄(AsEt₃)₂
  作者：Brian Beagley、Stephen M. Godfrey、Katharine J. Kelly、Sukjit Kungwankunakorn、Charkes A. McAuliffe、Robin G. Pritchard

  DOI：10.1039/cc9960002179

  日期：——

  The reactions of (p-MeOC(6)H(4))(3)AsI2 and Et(3)AsI(2) with gallium metal powder produce the metal complexes GaI3[(p-MeOC(6)H(4))(3)As] and Ga2I4(AsEt(3))(2), respectively; the latter represents a unique example of a gallium-tertiary arsine complex containing a gallium-gallium bond, and both structures illustrate the subtle effect of the organic substituent on the arsenic atoms.