Acrylic acid butylsulfanylmethyl ester | 62839-35-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Acrylic acid butylsulfanylmethyl ester
• 英文别名: (Butylsulfanyl)methyl prop-2-enoate；butylsulfanylmethyl prop-2-enoate
• CAS: 62839-35-4
• 化学式: C₈H₁₄O₂S
• 分子量: 174.264
• InChiKey: YHLNKBVKTLRMIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• PROCESS FOR PREPARING INERT RAFT POLYMERS
  申请人：Universiteit Gent

  公开号：EP3018151A1

  公开（公告）日：2016-05-11

  This invention provides a process for preparing an inert RAFT polymer, comprising polymerizing a RAFT-polymerizable ethylenically unsaturated monomer in the presence of a thiocarbonylthio compound until the monomer conversion reaches a value between 40% and 90%, and further comprising, when such value has been reached, adding a 5-fold to 100-fold molar excess, with respect to the thiocarbonylthio compound, of a reducing agent capable of performing aminolysis of the thiocarbonylthio end groups of the polymer. This invention further relates to an inert RAFT polymer prepared by such process.

  本发明提供了一种制备惰性 RAFT 聚合物的工艺，包括在硫代羰基硫代化合物存在下聚合可进行 RAFT 聚合的乙烯基不饱和单体，直至单体转化率达到 40% 至 90% 之间的值，还包括在达到该值时，加入相对于硫代羰基硫代化合物摩尔过量 5 倍至 100 倍的还原剂，该还原剂能够对聚合物的硫代羰基硫代端基进行氨解。本发明还涉及一种通过上述工艺制备的惰性 RAFT 聚合物。
• MONODISPERSE POLYMERS CONTAINING (ALKYL)ACRYLIC ACID MOIETIES, PRECURSORS AND METHODS FOR MAKING THEM AND THEIR APPLICATIONS
  申请人：UNIVERSITEIT GENT

  公开号：EP1776399A1

  公开（公告）日：2007-04-25
• Substituted cyclodextrin derivatives and process for their preparation
  申请人：Arcarios B.V.

  公开号：EP2550299A2

  公开（公告）日：2013-01-30
• Monodisperse Polymers Containing (Alkyl)Acrylic Acid Moieties, Precursors and Methods for Making them and their Applications
  申请人：Du Prez Filip

  公开号：US20080262160A1

  公开（公告）日：2008-10-23

  This invention relates to monodisperse or nearly monodisperse (co)polymers containing acrylic or (α-substituted)acrylic acid moieties, polymeric precursors thereof as well as methods for making them by at least partial hydrolysis of said polymeric precursors. The invention also relates to compositions comprising such (co)polymers optionally in combination with polymer processing additives for use in various fields of technology including imaging applications.
• Substituted Cyclodextrin Derivatives Useful As Intermediates For Producing Biologically Active Materials
  申请人：Van Calenbergh Serge

  公开号：US20130046087A1

  公开（公告）日：2013-02-21

  The present invention relates to substituted cyclodextrin derivatives which are particularly useful intermediates for producing well-defined carboxyalkylated cyclodextrins in contrast with the poorly-defined mixtures available through prior art procedures. The present invention also relates to processes for their preparation in a limited number of steps. These well-defined carboxyalkylated cyclodextrins can be polysulfated according to procedures standard in the art and some of these polysulfates, and alkali salts thereof, have been found to exhibit biologically active properties especially for the treatment and/or prophylaxis of degenerative joint diseases (e.g. osteoarthritis) or heparin-induced thrombocytopenia, or for cartilage repair or connective tissue repair.