1-Methoxy-2-(2-methylcyclopentyl)benzene | 55631-68-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-Methoxy-2-(2-methylcyclopentyl)benzene
• 英文别名: 1-methoxy-2-(2-methylcyclopentyl)benzene
• CAS: 55631-68-0
• 化学式: C₁₃H₁₈O
• 分子量: 190.28
• InChiKey: AVRJCTYGCQEWFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• PRODUCTION METHOD OF POLAR GROUP-CONTAINING OLEFIN POLYMERS
  申请人：THE UNIVERSITY OF TOKYO

  公开号：US20150368376A1

  公开（公告）日：2015-12-24

  The present invention relates to a method for producing a homopolymer of olefin represented by formula (1): CH 2 ═CHR 1 (R 1 is a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms) or a copolymer of two or more thereof or a method for producing a copolymer of olefin represented by formula (1) with olefin containing a polar group represented by formula (2): CH 2 ═CHR 2 R 3 (R 2 is a hydrogen atom or methyl group, R 3 is —COOR 12 , —CN, —OCOR 12 , —OR 12 , —CH 2 —OCOR 12 , —CH 2 OH, —CH 2 —N(R 13 ) 2 or —CH 2 -Hal (R 12 , R 13 and Hal have the same meanings as stated in the description), using as a catalyst a metal complex of group 10 elements in the periodic system typified by the structure represented by formula 1 (“Men” represents a menthyl group and “Me” represents a methyl group). The present invention enables the production of high molecular weight polymers of the polar group-containing monomers such as polar group-containing allyl compounds.

  本发明涉及一种制备一种由式(1)表示的烯烃的同聚物的方法：CH2═CHR1(R1是氢原子或具有1到20个碳原子的烃基)，或两种或更多烯烃的共聚物，或者一种由式(1)表示的烯烃与含有极性基团的烯烃的共聚物的方法，该极性基团由式(2)表示： ═CHR2R3(R2是氢原子或甲基基团，R3是—COOR12、—CN、—OCOR12、—OR12、— —OCOR12、— OH、— —N(R13)2或— -Hal(R12、R13和Hal的含义与说明中所述相同)，使用一种以1号周期表的10族元素的金属配合物为催化剂，以式1所表示的结构为代表的金属配合物(“Men”表示薄荷基团，“Me”表示甲基基团)。本发明能够生产具有高分子量的极性基团含量的单体，例如极性基团含有烷基化合物的聚合物。
• METHOD FOR PRODUCING POLAR GROUP-CONTAINING OLEFIN POLYMER
  申请人：THE UNIVERSITY OF TOKYO

  公开号：US20170313792A1

  公开（公告）日：2017-11-02

  The present invention relates to a method for producing a copolymer of ethylene and a polar group-containing olefin using as a catalyst a metal complex of group 10 elements having a structure represented by formula (C4) and (C5) (in the formula, “Men” represents a menthyl group and “Me” represents a methyl group). The method of the present invention makes it possible to produce a polar group-containing olefin polymer available for various applications, as being a high molecular weight body, which has been difficult to produce, and to produce the polymer in a molecular weight range such that the polymer has good moldability.
• US9499644B2
  申请人：——

  公开号：US9499644B2

  公开（公告）日：2016-11-22