(2-Oxochromen-6-yl)methyl-triphenylphosphanium | 721881-26-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-Oxochromen-6-yl)methyl-triphenylphosphanium
• 英文别名: (2-oxochromen-6-yl)methyl-triphenylphosphanium
• CAS: 721881-26-1
• 化学式: C₂₈H₂₂O₂P
• 分子量: 421.455
• InChiKey: AJYZZURKQKAPSE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  苯甲醛 、 (2-Oxochromen-6-yl)methyl-triphenylphosphanium 在 sodium hydroxide 作用下， 以 二氯甲烷 为溶剂， 生成 cis-6-styrylcoumarin 、 trans-6-styrylcoumarin
  参考文献：
  名称：

  Facile Synthesis, Fluorescence, and Photochromism of Novel Helical Pyrones and Chromenes

  摘要：

  [GRAPHICS]Aryl coumaryl ethylenes undergo oxidative photocyclization readily to yield helical pyrone-annulated condensed aromatics. The pyrones are conveniently converted to the corresponding photochromic diphenylpyrans/chromenes. Both pyrones and chromenes exhibit helicity-dependent fluorescence efficiency and persistence, respectively.

  DOI：

  10.1021/ol0619260
• 作为产物：
  描述：

  6-甲基香豆素 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 、 苯 为溶剂， 生成 (2-Oxochromen-6-yl)methyl-triphenylphosphanium
  参考文献：
  名称：

  Facile Synthesis, Fluorescence, and Photochromism of Novel Helical Pyrones and Chromenes

  摘要：

  [GRAPHICS]Aryl coumaryl ethylenes undergo oxidative photocyclization readily to yield helical pyrone-annulated condensed aromatics. The pyrones are conveniently converted to the corresponding photochromic diphenylpyrans/chromenes. Both pyrones and chromenes exhibit helicity-dependent fluorescence efficiency and persistence, respectively.

  DOI：

  10.1021/ol0619260

文献信息

• Facile Synthesis, Fluorescence, and Photochromism of Novel Helical Pyrones and Chromenes
  作者：Jarugu Narasimha Moorthy、Parthasarathy Venkatakrishnan、Sanchita Sengupta、Mahiuddin Baidya

  DOI：10.1021/ol0619260

  日期：2006.10.1

  [GRAPHICS]Aryl coumaryl ethylenes undergo oxidative photocyclization readily to yield helical pyrone-annulated condensed aromatics. The pyrones are conveniently converted to the corresponding photochromic diphenylpyrans/chromenes. Both pyrones and chromenes exhibit helicity-dependent fluorescence efficiency and persistence, respectively.