4-Carbamoyl-2,2-dimethyl-butyric acid methyl ester | 193621-17-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-Carbamoyl-2,2-dimethyl-butyric acid methyl ester
• 英文别名: Methyl 5-amino-2,2-dimethyl-5-oxopentanoate；methyl 5-amino-2,2-dimethyl-5-oxopentanoate
• CAS: 193621-17-9
• 化学式: C₈H₁₅NO₃
• 分子量: 173.212
• InChiKey: FWJSLKIKTZUMHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  69.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-甲氧基-1-(三甲基甲硅氧基)-2-甲基-1-丙烯 、 丙烯酰胺 在 lutetium triflate 作用下， 以 乙腈 为溶剂， 生成 4-Carbamoyl-2,2-dimethyl-butyric acid methyl ester
  参考文献：
  名称：

  α,β-不饱和酮的金属离子络合物在乙烯酮甲硅烷基乙缩醛的迈克尔加成反应中作为实际反应物

  摘要：

  β,β-二甲基取代的乙烯酮甲硅烷基缩醛 [Me2C=C(O​​Me)OSiMe3] 与 α,β-不饱和酮的迈克尔加成在高氯酸镁或三氟甲磺酸镥的存在下在 298 K 的乙腈中通过 1 有效发生： 1 α,β-不饱和酮与金属离子形成络合物，其中金属离子的配位增强了α,β-不饱和酮的亲电性，加快了反应速度。

  DOI：

  10.1246/cl.1997.667

文献信息

• A METALLIC NANOPARTICLE DISPERSION
  申请人：Agfa-Gevaert

  公开号：EP3287499A1

  公开（公告）日：2018-02-28

  A metallic nanoparticle dispersion comprising metallic nanoparticles, a liquid carrier and an optional binder, characterized in that the dispersion further comprises a silane compound according to Formula I: wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, an alkoxy group and an aryloxy group with the proviso that at least one of R1 to R3 represents an alkoxy group or an aryloxy group, L1 represents a divalent linking group comprising one to 20 carbon atoms, A represents a thiol, a disulfide or a functional moiety comprising at least one thiol or disulfide, having no more than 10 carbon atoms, and n represents 0 or 1.

  一种金属纳米颗粒分散液，由金属纳米颗粒、液体载体和任选粘合剂组成，其特征在于该分散液还包括一种符合式 I 的硅烷化合物： 其中 R1、R2 和 R3 独立地选自氢、取代或未取代的烷基、取代或未取代的芳基、烷氧基和芳氧基组成的组，但 R1 至 R3 中至少有一个代表烷氧基或芳氧基、 L1 代表由 1 至 20 个碳原子组成的二价连接基团、 A 代表硫醇、二硫化物或包含至少一个硫醇或二硫化物的官能团，其碳原子数不超过 10 个，以及 n 代表 0 或 1。
• CONDUCTIVE INKS
  申请人：Agfa-Gevaert N.V.

  公开号：EP3790934A1

  公开（公告）日：2021-03-17
• A METALLIC NANOPARTICLE DISPERSION
  申请人：AGFA-GEVAERT NV

  公开号：US20190185686A1

  公开（公告）日：2019-06-20

  A metallic nanoparticle dispersion includes metallic nanoparticles, a liquid carrier and an optional binder, and a silane compound according to Formula I: wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, an alkoxy group and an aryloxy group with the proviso that at least one of R1 to R3 represents an alkoxy group or an aryloxy group, L1 represents a divalent linking group including one to 20 carbon atoms, A represents a thiol, a disulfide or a functional moiety comprising at least one thiol or disulfide, having no more than 10 carbon atoms, and n represents 0 or 1.
• [EN] A METALLIC NANOPARTICLE DISPERSION<br/>[FR] DISPERSION DE NANOPARTICULES MÉTALLIQUES
  申请人：AGFA GEVAERT NV

  公开号：WO2018037072A1

  公开（公告）日：2018-03-01

  A metallic nanoparticle dispersion comprising metallic nanoparticles, a liquid carrier and an optional binder, characterized in that the dispersion further comprises a silane compound according to Formula (I) wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, an alkoxy group and an aryloxy group with the proviso that at least one of R1 to R3 represents an alkoxy group or an aryloxy group, L1 represents a divalent linking group comprising one to 20 carbon atoms, A represents a thiol, a disulfide or a functional moiety comprising at least one thiol or disulfide, having no more than 10 carbon atoms, and n represents 0 or 1.
• [EN] CONDUCTIVE INKS<br/>[FR] ENCRES CONDUCTRICES
  申请人：AGFA GEVAERT NV

  公开号：WO2019215068A1

  公开（公告）日：2019-11-14

  A conductive ink comprising metallic nanoparticles, a liquid carrier and an optional binder, characterized in that liquid carrier includes between 0.5 and 7.5 wt% of a solvent selected from water and a compound comprising at least two hydroxyl groups.