N-(4-methoxybenzyl)-N,N-dimethylanilinium chloride | 104292-44-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(4-methoxybenzyl)-N,N-dimethylanilinium chloride
• 英文别名: N-[(4-Methoxyphenyl)methyl]-N,N-dimethylanilinium chloride；(4-methoxyphenyl)methyl-dimethyl-phenylazanium;chloride
• CAS: 104292-44-6
• 化学式: C₁₆H₂₀NO*Cl
• 分子量: 277.794
• InChiKey: WZSCPWDAPBZNLF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.47
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  sodium tetrakis(pentafluorophenyl)-borate 、 N-(4-methoxybenzyl)-N,N-dimethylanilinium chloride 以 二氯甲烷 、 水 为溶剂， 以85 %的产率得到dimethylphenyl(4-methoxybenzyl)ammonium tetrakis(pentafluorophenyl)boronate salt
  参考文献：
  名称：

  WO2022/220285

  摘要：

  公开号：
• 作为产物：
  描述：

  N,N-二甲基苯胺 、 4-甲氧基氯苄 以 乙腈 为溶剂， 生成 N-(4-methoxybenzyl)-N,N-dimethylanilinium chloride
  参考文献：
  名称：

  N-苄基苯胺六氟锑酸酯的热重排

  摘要：

  我们制备了对-取代的N-苄基苯胺六氟锑酸盐，已知的阳离子引发剂，并检查了它们的热反应。热反应产生2-或4-苄基苯胺盐作为主要产物，这是由于苄基的重排所致。当苄基中的取代基是给电子体时，反应在较低的温度下以较高的产率进行。

  DOI：

  10.1016/s0040-4039(99)01546-4

文献信息

• Method of producing a crosslinked coating in the manufacture of integrated circuits
  申请人：Hessell T. Edward

  公开号：US20050215713A1

  公开（公告）日：2005-09-29

  The present invention is directed to a method of providing a thermally curable coating composition for to provide positive photoresists layers, underlayers for multiple layer resists, antireflective coatings, bottom layer antireflective coatins, dielectric layers, photoresist layers, hard mask etch stops, in the manufacture of integrated circuits. More particularly, the present invention is directed to a method of using a thermally activable latent acid or a thermal acid generator, a N-benzylpyridinium or N-benzylanilinium salt of a strong acid, as a catalyst in a polymerizable composition suitable for preparing such coatings and layers. The present invention is also directed to novel compositions comprising benzylpyridinium and benzylanilinium salts of a strong acid, such as sulfonic acid or disulfonic acid as thermal acid generators.

  本发明涉及一种提供热固性涂层组合物的方法，用于提供正向光刻层、多层光刻底层、抗反射涂层、底层抗反射涂层、介电层、光刻层、硬膜层刻停等，用于集成电路的制造。更具体地，本发明涉及一种使用热活性潜酸或热酸发生剂、强酸的N-苄基吡啶或N-苄基苯胺盐作为催化剂的聚合物组合物的方法，适用于制备这种涂层和层。本发明还涉及一种新型组合物，包括苄基吡啶和苄基苯胺盐，作为热酸发生剂的强酸，如磺酸或二磺酸。
• Rate-equilibrium relationships for reactions of families of carbanion nucleophiles with N-benzyl-N,N-dimethylanilinium cations and with alkyl chlorides, bromides, and iodides
  作者：Frederick G. Bordwell、David L. Hughes

  DOI：10.1021/ja00283a027

  日期：1986.11
• [EN] METHOD OF PRODUCING A CROSSLINKED COATING IN THE MANUFACTURE OF INTEGRATED CIRCUITS<br/>[FR] PROCEDE DE PRODUCTION D'UN REVETEMENT RETICULE DANS LA FABRICATION DE CIRCUITS INTEGRES
  申请人：KING INDUSTRIES INC

  公开号：WO2005097883A2

  公开（公告）日：2005-10-20

  The present invention is directed to a method of providing a thermally curable coating composition for to provide positive photoresists layers, underlayers for multiple layer resists, antireflective coatings, bottom layer antireflective coatins, dielectric layers, photoresist layers, hard mask etch stops, in the manufacture of integrated circuits. More particularly, the present invention is directed to a method of using a thermally activable latent acid or a thermal acid generator, a N-benzylpyridinium or N-benzylanilinium salt of a strong acid, as a catalyst in a polymerizable composition suitable for preparing such coatings and layers. The present invention is also directed to novel compositions comprising benzylpyridinium and benzylanilinium salts of a strong acid, such as sulfonic acid or disulfonic acid as thermal acid generators.
• 酸発生剤、前記酸発生剤を含む硬化性組成物、及びその硬化物
  申请人：[en]SAN-APRO LTD.;[ja]サンアプロ株式会社

  公开号：WO2024042951A1

  公开（公告）日：2024-02-29

  カチオン硬化性化合物への溶解性に優れる酸発生剤を提供する。　本発明の酸発生剤は、下記式（ｃ－１）で表されるカチオンと１価の対アニオンとの塩（１）と、下記式（ｃ－２）で表されるカチオンと１価の対アニオンとの塩（２）を含み、前記塩（２）の含有率が０．００１重量％以上、５重量％未満である。下記式中、Ｒ1、Ｒ2、Ｒ3は同一又は異なって炭素数１～６のアルキル基を示す。ｎは１以上の整数を示す。
• Thermal rearrangement of N-benzylanilinium hexafluoroantimonates
  作者：Jeongkyu Park、Jung-Hyu Shin、Changjin Lee

  DOI：10.1016/s0040-4039(99)01546-4

  日期：1999.10

  N-benzylanilinium hexafluoroantimonates, known cationic initiators, and examined their thermal reaction. The thermal reaction produced 2- or 4-benzylanilinium salts as the major products, which resulted from the rearrangement of the benzyl group. The reaction proceeded at lower temperature with higher yield when the substituent in the benzyl group was electron donating.

  我们制备了对-取代的N-苄基苯胺六氟锑酸盐，已知的阳离子引发剂，并检查了它们的热反应。热反应产生2-或4-苄基苯胺盐作为主要产物，这是由于苄基的重排所致。当苄基中的取代基是给电子体时，反应在较低的温度下以较高的产率进行。