1,1,2,2,3,3,6,6,6-Nonafluorohexyl prop-2-enoate | 91528-57-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,1,2,2,3,3,6,6,6-Nonafluorohexyl prop-2-enoate
• 英文别名: 1,1,2,2,3,3,6,6,6-nonafluorohexyl prop-2-enoate
• CAS: 91528-57-3
• 化学式: C₉H₇F₉O₂
• 分子量: 318.14
• InChiKey: IDLKDJKKLNXPHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  11

文献信息

• Polymerization of acrylic esters
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0291212A1

  公开（公告）日：1988-11-17

  Polymerization process comprising contacting under polymerizing conditions:     (a) at least one acrylic ester monomer of the formula CH₂ =C(Y)C(O)OR wherein Y is -H or -CH₃ and R is a hydrocarbyl radical;     (b) a polymerization initiator comprising a tetracoordinate silicon-containing organic compound having at least one initiating site; and     (c) a catalyst which is a source of fluoride, bifluoride or selected oxyanions, the process characterized in that the initiator is of the formula     (Ra)·(H)fSi(Z³)g wherein the substituents have the meanings given by claim 1.

  聚合工艺，包括在聚合条件下使以下物质接触 (a) 至少一种式 CH₂ =C(Y)C(O)OR 的丙烯酸酯单体，其中 Y 为-H 或-CH₃，R 为烃基； (b) 一种聚合引发剂，包括至少具有一个引发位点的四配位含硅有机化合物； 以及 (c) 催化剂，它是氟化物、双氟化物或选定氧阴离子的来源、 该工艺的特征在于，引发剂的结构式为 (Ra)-(H)fSi(Z³)g 其中取代基具有权利要求 1 所述的含义。
• AN ANTI-FROST COATING AND THE APPLICATION METHOD THEREOF
  申请人：Institute of Chemistry, Chinese Academy of Science

  公开号：EP2236573A1

  公开（公告）日：2010-10-06

  The present invention provides an aoti-frost coating, which forms a coat having a hydrophilic and hydrophobic composite structure after being applied on a substrate, and contains a hydrophobic polymer and a hydrophilic polymer. The application method of the anti-frost coating comprises: dissolving the hydrophilic polymer and the hydrophobic polymer in a solvent to form a homogeneous solution, coating the solution on a substrate to form a film, drying and curing to form an anti-frost coat with a hydrophilic and super-hydrophobic composite structure including a super-hydrophobic surface layer and a hydrophilic inner layer. Water drips can roll off easily and the dust and impurities deposited on the surface can be easily removed. The anti-frost effect is desirable.

  本发明提供了一种防霜冻涂料，该涂料涂在基材上后形成具有亲水和疏水复合结构的涂层，其中包含疏水聚合物和亲水聚合物。该防冻涂层的涂抹方法包括：将亲水性聚合物和疏水性聚合物溶解在溶剂中形成均匀溶液，将溶液涂抹在基材上形成薄膜，干燥固化后形成具有亲水和超疏水复合结构的防冻涂层，该结构包括超疏水表层和亲水内层。水滴很容易滚落，沉积在表面的灰尘和杂质也很容易清除。防冻效果理想。
• FILM-FORMING COMPOSITION INCLUDING FLUORINE-CONTAINING SURFACTANT
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP3106921A1

  公开（公告）日：2016-12-21

  There is provided a film with reduced formation of an edge reservoir at a periphery of a film in which the edge reservoir causes an unnecessary residue that cannot be removed by an etching process, and a method for forming the film. A film forming composition for use in a lithography process, the film forming composition comprising a surfactant containing a polymer and an oligomer having a C3-5 perfluoroalkyl partial structure. The perfluoroalkyl partial structure preferably has a carbon number of 4. The perfluoroalkyl partial structure may further include an alkyl partial structure, and the polymer and the oligomer are preferably a (meth)acrylate polymer and a (meth)acrylate oligomer, respectively. The surfactant is contained in an amount of 0.0001% by mass to 1.5% by mass based on the total solid content of the film forming composition. The film forming composition further comprises a coating film resin, and the coating film resin is a novolac resin, a condensation epoxy resin, a (meth)acylic resin, a polyether-based resin, or a silicon-containing resin, etc. The formed film can be used as a resist underlayer film or a resist overlayer film.

  本发明提供了一种可减少在薄膜外围形成边缘储层的薄膜，在这种薄膜中，边缘储层会造成无法通过蚀刻工艺去除的不必要残留物，本发明还提供了一种用于形成该薄膜的方法。一种用于光刻工艺的成膜组合物，该成膜组合物包含一种表面活性剂，其中含有一种聚合物和一种具有 C3-5 全氟烷基部分结构的低聚物。全氟烷基部分结构的碳原子数最好为 4。全氟烷基部分结构可进一步包括烷基部分结构，聚合物和低聚物最好分别为（甲基）丙烯酸酯聚合物和（甲基）丙烯酸酯低聚物。根据成膜组合物的总固体含量，表面活性剂的含量为 0.0001%（质量百分比）至 1.5%（质量百分比）。成膜组合物还包括涂膜树脂，涂膜树脂为酚醛树脂、缩合环氧树脂、（甲基）酰基树脂、聚醚基树脂或含硅树脂等。形成的薄膜可用作抗蚀剂底层薄膜或抗蚀剂覆盖层薄膜。
• SUPERAMPHIPHOBIC SURFACES BY ATMOSPHERIC PLASMA POLYMERIZATION
  申请人：Centre de Recherche Public Henri Tudor

  公开号：EP2809453A1

  公开（公告）日：2014-12-10
• ANTI-FROST COATING AND THE APPLICATION METHOD THEREOF
  申请人：He Min

  公开号：US20100316806A1

  公开（公告）日：2010-12-16

  The present invention provides an anti-frost coating, which forms a coat having a hydrophilic and hydrophobic composite structure after being applied on a substrate, and contains a hydrophobic polymer and a hydrophilic polymer. The application method of the anti-frost coating comprises: dissolving the hydrophilic polymer and the hydrophobic polymer in a solvent to form a homogeneous solution, coating the solution on a substrate to form a film, drying and curing to form an anti-frost coat with a hydrophilic and super-hydrophobic composite structure including a super-hydrophobic surface layer and a hydrophilic inner layer. Water drips can roll off easily and the dust and impurities deposited on the surface can be easily removed. The anti-frost effect is desirable.