Methyl hexadec-4-ynoate | 89199-84-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Methyl hexadec-4-ynoate
• 英文别名: methyl hexadec-4-ynoate
• CAS: 89199-84-8
• 化学式: C₁₇H₃₀O₂
• 分子量: 266.4
• InChiKey: NLVUNDNCKIBPRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• [EN] METHOD FOR THE PREPARATION OF A COATING<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN REVÊTEMENT
  申请人：ECOLE POLYTECHNIQUE FED DE LAUSANNE (EPFL) EPFL-TTO

  公开号：WO2016174266A2

  公开（公告）日：2016-11-03

  The invention relates to a method for the preparation of a coating comprising at least one coating layer on a substrate, the method comprising the steps of a. providing monomers of the type R- (N)x-(L)m- (C=C)n-(L')o- (N')y-R', wherein R is a head moiety, R' is a tail moiety, (C≡C)n is an oligoyne moiety, L and L' are linker moieties, N and N' independently are branched or unbranched optionally substituted C1-C25 alkyl moieties optionally containing 1 to 5 heteroatoms, x, m, o, and y are independently 0 or 1, n is 4 to 12, and wherein the head moiety allows for an interaction with the surface of the substrate; b. bringing the monomers into contact with the substrate wherein the interaction of the head moieties of the monomers with the surface of the substrate induces at least a part of the monomers to align in a defined manner thereby forming a film on the surface and bringing the oligoyne moieties of the monomers into close contact with each other; c. inducing a reaction between oligoyne moieties by providing an external stimulus so as to at least partially cross-link the aligned monomers, thereby forming a coating layer on the substrate. The invention further relates to a coating obtainable according to the method of the invention, the use of a coating obtainable according to the method of the invention, a substrate comprising a coating obtainable according to the invention and the use of solid substrate. The invention further relates to a method for the synthesis of the monomers according to the invention.