arabidopside D | 852369-56-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: arabidopside D
• 英文别名: Arabidopside D；[(2S)-2-[8-[4-oxo-5-[(Z)-pent-2-enyl]cyclopent-2-en-1-yl]octanoyloxy]-3-[(2R,3R,4S,5R,6R)-3,4,5-trihydroxy-6-[[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxymethyl]oxan-2-yl]oxypropyl] 8-[4-oxo-5-[(Z)-pent-2-enyl]cyclopent-2-en-1-yl]octanoate
• CAS: 852369-56-3
• 化学式: C₅₁H₈₀O₁₇
• 分子量: 965.186
• InChiKey: JFTWMYLCKKDOGZ-KINXKZRZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  68
• 可旋转键数：
  34
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  265
• 氢给体数：
  7
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  arabidopside D 在 sodium methylate 作用下， 以 甲醇 为溶剂， 反应 1.0h， 生成 (2r)-glyceryl 6-O-(alpha-d-galactopyranosyl)-beta-d-galactopyranoside
  参考文献：
  名称：

  Oxylipins Arabidopsides C and D from Arabidopsis thaliana

  摘要：

  Two new oxylipins, arabidopsides C (1) and D (2), were isolated from the aerial parts of Arabidopsis thaliana, and the structures of 1 and 2 were elucidated using spectroscopic data, primarily NMR and MS, and chemical means. Arabidopsides C (1) and D (2) are rare digalactosyl diacylglycerides containing 12-oxophytodienoic acid and/or dinor-oxophytodienoic acid. Arabidopside D (2) and arabidopsides A (3) and B (4), which were also isolated from this plant, exhibited inhibitory effects on the growth of the root of cress (Lepidium sativum) seedlings at 5 x 10(-5) mol/L.

  DOI：

  10.1021/np0495938

文献信息

• Oxylipins Arabidopsides C and D from <i>Arabidopsis </i><i>t</i><i>haliana</i>
  作者：Yosuke Hisamatsu、Nobuharu Goto、Mitsuhiro Sekiguchi、Koji Hasegawa、Hideyuki Shigemori

  DOI：10.1021/np0495938

  日期：2005.4.1

  Two new oxylipins, arabidopsides C (1) and D (2), were isolated from the aerial parts of Arabidopsis thaliana, and the structures of 1 and 2 were elucidated using spectroscopic data, primarily NMR and MS, and chemical means. Arabidopsides C (1) and D (2) are rare digalactosyl diacylglycerides containing 12-oxophytodienoic acid and/or dinor-oxophytodienoic acid. Arabidopside D (2) and arabidopsides A (3) and B (4), which were also isolated from this plant, exhibited inhibitory effects on the growth of the root of cress (Lepidium sativum) seedlings at 5 x 10(-5) mol/L.