Methyl-2,6-di-O-acetyl-3,6-didesoxy-3,6-imino-N-methoxycarbonyl-α-D-glucopyranosid | 34299-77-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: Methyl-2,6-di-O-acetyl-3,6-didesoxy-3,6-imino-N-methoxycarbonyl-α-D-glucopyranosid
• 英文别名: methyl O²,O⁴-diacetyl-3,6-methoxycarbonylazanediyl-α-D-3,6-dideoxy-glucopyranoside；(1R)-4exo,8syn-diacetoxy-3exo-methoxy-2-oxa-6-aza-bicyclo[3.2.1]octane-6-carboxylic acid methyl ester
• CAS: 34299-77-9
• 化学式: C₁₃H₁₉NO₈
• 分子量: 317.296
• InChiKey: UCRJYCAXZANPPI-ROHXPCBUSA-N

反应信息

• 作为产物：
  描述：

  methyl O²,O⁴-diacetyl-6-bromo-3-methoxycarbonylamino-α-D-3,6-dideoxy-glucopyranoside 在 吡啶 、 silver fluoride 作用下， 生成 Methyl-2,6-di-O-acetyl-3,6-didesoxy-3,6-imino-N-methoxycarbonyl-α-D-glucopyranosid
  参考文献：
  名称：

  Studies on Aminosugars. XXVIII. Synthesis of β-L-Idopyranosides through the Corresponding 5-Enopyranosides

  摘要：

  Methyl 6-deoxy-β-l-idopyranoside (7), methyl 2-amino-2,6-dideoxy-β-l-idopyranoside (13) and methyl 3-amino-3,6-dideoxy-β-l-idopyranoside (28) have been prepared through the corresponding suitably protected 5-enopyranoside precursors in good yields.

  DOI：

  10.1246/bcsj.44.2529