2,2,2-Trifluoroethyl 4-(2-methylprop-2-enoyloxymethyl)benzoate | 1293408-13-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2,2-Trifluoroethyl 4-(2-methylprop-2-enoyloxymethyl)benzoate
• CAS: 1293408-13-5
• 化学式: C₁₄H₁₃F₃O₄
• 分子量: 302.25
• InChiKey: OITMDGJNBIKLNA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-氯甲基苯甲酰氯 在 potassium carbonate 、 三乙胺 作用下， 以 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 反应 4.0h， 生成 2,2,2-Trifluoroethyl 4-(2-methylprop-2-enoyloxymethyl)benzoate
  参考文献：
  名称：

  Fluorinated compound, fluorinated polymer and fluorinated copolymer

  摘要：

  提供具有最多6个碳原子的RF基团的氟化合物，从而可以生产具有高耐久性的抗水/油性的氟化聚合物，并且环境负荷较小，通过聚合这种氟化合物可以获得具有高耐久性的抗水/油性和环境负荷较小的氟化聚合物和氟化共聚物。以下是用下式（I）表示的氟化合物及其聚合物：CH2═C(M)COO(CH2)nPhCOO(CH2)mCrF2r+1  (I)（在式（I）中，M是氢原子，甲基基团或卤素原子，n为0至2的整数，Ph为苯基团，m为1至4的整数，r为1至6的整数）。

  公开号：

  US08471056B2

文献信息

• FLUORINE-CONTAINING COMPOUND, FLUORINE-CONTAINING POLYMER AND FLUORINE-CONTAINING COPOLYMER
  申请人：Asahi Glass Company, Limited

  公开号：EP2497788B1

  公开（公告）日：2014-09-24
• FLUORINATED COMPOUND, FLUORINATED POLYMER AND FLUORINATED COPOLYMER
  申请人：HOSHINO Taiki

  公开号：US20120184695A1

  公开（公告）日：2012-07-19

  To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer and a fluorinated copolymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COO(CH 2 ) n PhCOO(CH 2 ) m CF 2r+1 (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).
• US8471056B2
  申请人：——

  公开号：US8471056B2

  公开（公告）日：2013-06-25
• US8748549B2
  申请人：——

  公开号：US8748549B2

  公开（公告）日：2014-06-10
• Fluorinated compound, fluorinated polymer and fluorinated copolymer
  申请人：Hoshino Taiki

  公开号：US08471056B2

  公开（公告）日：2013-06-25

  To provide a fluorinated compound having an RF group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer and a fluorinated copolymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH2═C(M)COO(CH2)nPhCOO(CH2)mCrF2r+1  (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).

  提供具有最多6个碳原子的RF基团的氟化合物，从而可以生产具有高耐久性的抗水/油性的氟化聚合物，并且环境负荷较小，通过聚合这种氟化合物可以获得具有高耐久性的抗水/油性和环境负荷较小的氟化聚合物和氟化共聚物。以下是用下式（I）表示的氟化合物及其聚合物：CH2═C(M)COO(CH2)nPhCOO(CH2)mCrF2r+1  (I)（在式（I）中，M是氢原子，甲基基团或卤素原子，n为0至2的整数，Ph为苯基团，m为1至4的整数，r为1至6的整数）。