4-(4-morpholinophenyl)naphthalene-1,2-dione | 1260217-83-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 4-(4-morpholinophenyl)naphthalene-1,2-dione
• CAS: 1260217-83-1
• 化学式: C₂₀H₁₇NO₃
• 分子量: 319.36
• InChiKey: UHTBVCNEDHWHGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.72
• 重原子数：
  24.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  46.61
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  4-(4-morpholinophenyl)naphthalene-1,2-dione 在 盐酸羟胺 作用下， 以 乙醇 为溶剂， 反应 1.0h， 以90%的产率得到2-(hydroxyimino)-4-(4-morpholinophenyl)naphthalen-1(2H)-one
  参考文献：
  名称：

  Synthesis of Green Colored Photochromic 6′-Arylamino Spiro [2H]Naphth[1,2-b]oxazines

  摘要：

  The published route to a series of 6'-arylamino substituted photochromic spirooxazines has been investigated with improvements made to perform the synthesis in satisfactory yield. The route has been exemplified with several novel derivatives prepared (including hydroxyl functionalised). Additionally, a one-pot procedure for the conversion of suitably functionalized 1,2-naphthoquinones into the photochromic compounds is reported.

  DOI：

  10.1080/00397910903457423
• 作为产物：
  描述：

  4-苯基吗啉 、 sodium 1,2-naphthoquinone-4-sulfonate 以 甲醇 、 水 为溶剂， 反应 18.0h， 以45%的产率得到4-(4-morpholinophenyl)naphthalene-1,2-dione
  参考文献：
  名称：

  Synthesis of Green Colored Photochromic 6′-Arylamino Spiro [2H]Naphth[1,2-b]oxazines

  摘要：

  The published route to a series of 6'-arylamino substituted photochromic spirooxazines has been investigated with improvements made to perform the synthesis in satisfactory yield. The route has been exemplified with several novel derivatives prepared (including hydroxyl functionalised). Additionally, a one-pot procedure for the conversion of suitably functionalized 1,2-naphthoquinones into the photochromic compounds is reported.

  DOI：

  10.1080/00397910903457423