[Co(2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid(-1H))₂(H₂O)₂] | 1400998-33-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Co(2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid(-1H))₂(H₂O)₂]
• 英文别名: [Co(H₂MOPhIDC)₂(H₂O)₂]
• CAS: 1400998-33-5；1416789-63-3
• 化学式: C₂₄H₂₀CoN₄O₁₂
• 分子量: 615.436
• InChiKey: LLFPRKBAEHWGKR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Co(2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid(-1H))₂(H₂O)₂] 、 氧气 以 neat (no solvent) 为溶剂， 生成 cobalt(III) oxide
  参考文献：
  名称：

  Two Novel Supramolecular Complexes Built by 2-propyl or 2-p-methoxyphenyl Imidazole Dicarboxylate Ligands

  摘要：

  Two complexes, [Cu(H2PIDC)2(H2O)] (H3PIDC = 2-propyl- 1H-imidazole-4,5-dicarboxylic acid) (1) and [Co(H2MOPhIDC)2 (H2O)2] (H3MOPhIDC = 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid) (2), have been hydro(solvo)thermally synthesized and characterized by IR spectroscopy, elemental analysis, PXRD, and single-crystal X-ray diffraction. Both two complexes show three-dimensional supramolecular structures supported by intermolecular H-bonds. The thermal properties of the two complexes have been investigated as well.

  DOI：

  10.1080/15533174.2012.740714
• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid 在 三乙胺 作用下， 以 水 为溶剂， 反应 72.0h， 以43%的产率得到[Co(2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid(-1H))₂(H₂O)₂]
  参考文献：
  名称：

  Two Novel Supramolecular Complexes Built by 2-propyl or 2-p-methoxyphenyl Imidazole Dicarboxylate Ligands

  摘要：

  Two complexes, [Cu(H2PIDC)2(H2O)] (H3PIDC = 2-propyl- 1H-imidazole-4,5-dicarboxylic acid) (1) and [Co(H2MOPhIDC)2 (H2O)2] (H3MOPhIDC = 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid) (2), have been hydro(solvo)thermally synthesized and characterized by IR spectroscopy, elemental analysis, PXRD, and single-crystal X-ray diffraction. Both two complexes show three-dimensional supramolecular structures supported by intermolecular H-bonds. The thermal properties of the two complexes have been investigated as well.

  DOI：

  10.1080/15533174.2012.740714