| 78615-03-9

• CAS: 78615-03-9
• 化学式: C₂₀H₂₈I₃Ru₂
• 分子量: 851.296
• InChiKey: KCNDFFHJRSMNAH-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(p-Me-C6H4-CH(CH3)2)2Ru2Cl2(μ-Cl)(μ-H)] 、 氢碘酸 以 四氢呋喃 、 水 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of dinuclear arene ruthenium complexes: reactions of the hydrido complex [( p -Me-C 6 H 4 -Pr i ) 2 Ru 2 Cl 2 (μ-Cl)(μ-H)] with NaX and HX (X=F, Cl, Br, I)

  摘要：

  The dinuclear hydride complex [(p-Me-C6H4-Pr')(2)Ru2Cl2(mu-Cl)(mu-H)] (1) reacts with the sodium halides NaX in methanol to give the halogen analogues [(p-Me-C6H4-Pr')(2)Ru2X2(mu-X)(mu-H)] (2: X = F, 3: X = Br, 4: X = I). With HX, complex 1 reacts to give the tetrahalo complexes [(p-Me-C6H4-Pr')(2)Ru2X2(mu-X)(2)] (5: X = Cl, 6: X = Br, 7: X = I); in the case of X = I, a large excess of HI leads to the formation of the cationic complex [(p-Me-C6H4-Pr')(2)Ru-2(mu-I)(3)](+) (8). The X-ray structure analysis of 1 shows a dinuclear Ru-2 backbone with two terminal chloro ligands being irans with respect to each other as the two p-cymene ligands, the two bridging ligands lie in a plane perpendicular to the plane defined by the terminal chloro ligands and the ruthenium atoms. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00155-8