[Cu(N-benzyliminodiacetate)(74-azaindole)(H2O)] | 1211475-49-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Cu(N-benzyliminodiacetate)(74-azaindole)(H2O)]
• CAS: 1211475-49-8
• 化学式: C₁₈H₁₉CuN₃O₅
• 分子量: 420.912
• InChiKey: UIIVQBJXYQYRRH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(N-benzyliminodiacetate)(74-azaindole)(H2O)] 生成 二氧化碳 、 水 、 copper(II) oxide
  参考文献：
  名称：

  Restricting the versatile metal-binding behaviour of adenine by using deaza-purine ligands in mixed-ligand copper(II) complexes

  摘要：

  In order to deepen Our understanding of the versatile behaviour of adenine (Hade) as ligand, we have synthesized four novel ternary copper(H) complexes having two deazaadenine ligands, namely 4-azabenzimidazole (H4abim) or 7-azaindole (H7azain) as N1,N6-dideazaadenine or N1,N6,N7-trideazaadenine, respectively. The related Compounds were studied by thermal, spectral and single crystal X-ray diffraction methods. In [Cu(NBzIDA)(H4abim)](n) (1) the recognition between H4abim and the (N-benzyliminodiacetate)-copper(II) chelate only displays the formation of the Cu-N7(purine-like) bond. in contrast to Hade behaviour in [Cu(NBzIDA-like)(Hade)(H2O)]center dot H2O (Cu-N3(Hade) bond reinforced by N9-H center dot center dot center dot O(IDA-like) interaction). In [Cu(EIDA)(H7azain)(H2O)] (2, EIDA=N-ethyliminodiacetate ligand), [Cu(NBzIDA)(H7azain)(H2O)] (3) and [Cu(mu(2)-SO4)(H7azain)(2)(H2O)2](n) (4), H7azain binds Cu(II) centre by the Cu-N3(purine-like) bond. reinforced by a N9-H center dot center dot center dot O(IDA-like or sulfate) intra-molecular interligand interaction. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.054
• 作为产物：
  描述：

  7-氮杂吲哚 、 malachite 、 N-苄基亚胺二乙酸 以 水 为溶剂， 生成 [Cu(N-benzyliminodiacetate)(74-azaindole)(H2O)]
  参考文献：
  名称：

  Restricting the versatile metal-binding behaviour of adenine by using deaza-purine ligands in mixed-ligand copper(II) complexes

  摘要：

  In order to deepen Our understanding of the versatile behaviour of adenine (Hade) as ligand, we have synthesized four novel ternary copper(H) complexes having two deazaadenine ligands, namely 4-azabenzimidazole (H4abim) or 7-azaindole (H7azain) as N1,N6-dideazaadenine or N1,N6,N7-trideazaadenine, respectively. The related Compounds were studied by thermal, spectral and single crystal X-ray diffraction methods. In [Cu(NBzIDA)(H4abim)](n) (1) the recognition between H4abim and the (N-benzyliminodiacetate)-copper(II) chelate only displays the formation of the Cu-N7(purine-like) bond. in contrast to Hade behaviour in [Cu(NBzIDA-like)(Hade)(H2O)]center dot H2O (Cu-N3(Hade) bond reinforced by N9-H center dot center dot center dot O(IDA-like) interaction). In [Cu(EIDA)(H7azain)(H2O)] (2, EIDA=N-ethyliminodiacetate ligand), [Cu(NBzIDA)(H7azain)(H2O)] (3) and [Cu(mu(2)-SO4)(H7azain)(2)(H2O)2](n) (4), H7azain binds Cu(II) centre by the Cu-N3(purine-like) bond. reinforced by a N9-H center dot center dot center dot O(IDA-like or sulfate) intra-molecular interligand interaction. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.054