methyldipropylsulfonium iodide | 38131-85-0

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: methyldipropylsulfonium iodide
• 英文别名: Methyl-dipropyl-sulfonium; Jodid；methyl(dipropyl)sulfanium;iodide
• CAS: 38131-85-0
• 化学式: C₇H₁₇S*I
• 分子量: 260.182
• InChiKey: RYLOUDHTNMHVLO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.94
• 重原子数：
  9.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  银二氰胺 、 methyldipropylsulfonium iodide 以 水 为溶剂， 以12.35 g的产率得到methyldipropylsulfonium dicyanamide
  参考文献：
  名称：

  Trialkylsulfonium dicyanamides - a new family of ionic liquids with very low viscosities

  摘要：

  三烷基磺铵二氰胺在低至 -20 °C 时表现出令人惊讶的低粘度，因此在低温下作为分离过程和电解质应用的液体材料非常有趣。

  DOI：

  10.1039/b510736a
• 作为产物：
  描述：

  二丙硫醚 、 碘甲烷 以 丙酮 为溶剂， 生成 methyldipropylsulfonium iodide
  参考文献：
  名称：

  Trialkylsulfonium dicyanamides - a new family of ionic liquids with very low viscosities

  摘要：

  三烷基磺铵二氰胺在低至 -20 °C 时表现出令人惊讶的低粘度，因此在低温下作为分离过程和电解质应用的液体材料非常有趣。

  DOI：

  10.1039/b510736a

文献信息

• Molten and Solid Trialkylsulfonium Iodides and Their Polyiodides as Electrolytes in Dye-Sensitized Nanocrystalline Solar Cells
  作者：Heléne Paulsson、Anders Hagfeldt、Lars Kloo

  DOI：10.1021/jp036859v

  日期：2003.12.1

  Potential new electrolytes for dye-sensitized nanocrystalline solar cells (DNSCs) of Gratzel type based on trialkylsulfonium iodides have been investigated. Room temperature molten salts of (Et2MeS)I, (Bu2MeS)I, and (Bu2EtS)I, with iodine in low concentrations, revealed good conducting abilities. DNSCs using iodine-doped (Bu2MeS)l as electrolyte achieved an overall light-to-electricity conversion efficiency of 3.7% in simulated AM 1.5 solar light at a light intensity of 0.1 Sun. The effects from varying the temperature during the IN measurements were studied, as well as the effects of 4-tert-butylpyridine treatment of the electrodes.
• Laparoscopic Telescope with Alpha Port and Aesop to View Open Surgical Procedures
  作者：K. Mitchell Russell、Timothy J. Broderick、Eric J. DeMaria、Shanu N. Kothari、Ronald C. Merrell

  DOI：10.1089/109264201750539727

  日期：2001.8

  Laparoscopy has advanced surgery by allowing the surgeon to operate within a patient's abdominal and pelvic cavity with minimal trauma and scarring. The coupling of a video camera to the laparoscopic telescope has had the secondary effect of allowing others to view the surgical field either on color video monitors or by watching the video feed over the Internet at a remote location. These advancements have allowed better teaching and mentoring of operations. Open procedures can benefit from this technology as well but have suffered in the past from inadequate methods to depict the open surgical field. We used the Alpha Port and Aesop robot to position a sterile laparoscopic telescope near the surgical field to view open cholecystectomies performed on five pigs and to send the video feed over the Internet to remote physicians. Viewing the video on the monitor, the surgeons performed the operation in a comfortable ergonomic upright position. Both the surgeons and the remote physicians found the quality of the video to be excellent, and the remote physicians felt comfortable learning and mentoring surgical procedures using this technique.
• Selker; Kemp, Industrial and Engineering Chemistry, 1944, vol. 36, p. 19
  作者：Selker、Kemp

  DOI：——

  日期：——